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| 货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
|---|---|---|---|---|
| S119490-1g |
1g |
现货 ![]() |
| |
| S119490-5g |
5g |
现货 ![]() |
|
| 别名 | 三氟甲磺酸银 |
|---|---|
| 英文别名 | Methanesulfonic acid, 1,1,1-trifluoro-, silver(1+) salt (1:1) | N-propan-2-ylcyclohexanamine | Silver trifluoromethanesulfonate, purum, >=98.0% (Ag) | Silver(I) trifluoromethanesulfonate | DTXSID5062716 | Silver trifluoromethanesulfonate, >=99% | silver(1 |
| 规格或纯度 | ≥99.98% metals basis |
| 英文名称 | Silver trifluoromethanesulfonate |
| 储存温度 | 充氩 |
| 运输条件 | 常规运输 |
| 产品介绍 |
溶于水。由仲磷酸盐和硫代磷酸盐生成烯烃.使用该试剂,伯烷基卤化物对醇的醚化可以在温和条件下实现。 用于由氯铑络合物生成阳离子铑催化剂,以用于乙炔的氢化亚膦酸化。还用作通过醛的氢化硅烷化来制备硅醚的催化剂。 |
| 纯度 | ≥99.98% metals basis |
| PubChem SID | 504755040 |
|---|---|
| EC号 | 220-882-2 |
| IIUPAC Name | silver;trifluoromethanesulfonate |
| INCHI | 1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1 |
| InChi Key | QRUBYZBWAOOHSV-UHFFFAOYSA-M |
| Smiles | C(F)(F)(F)S(=O)(=O)[O-].[Ag+] |
| Isomeric SMILES | C(F)(F)(F)S(=O)(=O)[O-].[Ag+] |
| PubChem CID | 76223 |
| 分子量 | 256.94 |
| Beilstein号 | 3598402 |
| Reaxy-Rn | 3598402 |
| 溶解性 | Soluble in water and also in most organic solvents. |
|---|---|
| 密度 | 1.876 |
| 敏感性 | 对光线和空气和湿度敏感 |
| 熔点 | 356°C |
| 分子量 | 256.940 g/mol |
| XLogP3 | |
| 氢键供体数Hydrogen Bond Donor Count | 0 |
| 氢键受体数Hydrogen Bond Acceptor Count | 6 |
| 可旋转键计数Rotatable Bond Count | 0 |
| 精确质量Exact Mass | 255.857 Da |
| 单同位素质量Monoisotopic Mass | 255.857 Da |
| 拓扑极表面积Topological Polar Surface Area | 65.600 Ų |
| 重原子数Heavy Atom Count | 9 |
| 形式电荷Formal Charge | 0 |
| 复杂度Complexity | 145.000 |
| 同位素原子数Isotope Atom Count | 0 |
| 定义的原子立体中心计数Defined Atom Stereocenter Count | 0 |
| 未定义的原子立体中心计数Undefined Atom Stereocenter Count | 0 |
| 定义的键立体中心计数Defined Bond Stereocenter Count | 0 |
| 未定义的键立体中心计数Undefined Bond Stereocenter Count | 0 |
| 所有立体化学键的总数The total count of all stereochemical bonds | 0 |
| 共价键合单元计数Covalently-Bonded Unit Count | 2 |
| 象形图 | GHS07 |
|---|---|
| 信号词 | 警告 |
| 危险声明 |
H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 |
| 预防措施声明 |
P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P264: 处理后要彻底洗手。 P271: 仅在室外或通风良好的地方使用。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理(请参阅此标签上的...)。 P302+P352: 如皮肤沾染:用水充分清洗。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。 P362+P364: 脱掉沾污的衣服,清洗后方可重新使用。 P405: 密闭存放 P403+P233: 存放在通风良好的地方。保持容器密闭。 P501: 将内容物/容器处理到。。。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P337+P317: 如果眼睛刺激持续:寻求医疗帮助。 P332+P317: 如果出现皮肤刺激:请寻求医疗帮助。 P319: 如果你感到不适,请寻求医疗帮助。 |
| WGK Germany | 3 |
| 个人防护装备 | dust mask type N95 (US),Eyeshields,Gloves |
| 1. Dennis M Whitfield. (2012-04-25) Plausible Transition States for glycosylation reactions.. Carbohydrate research, 356 (180-190). [PMID:22525097] |
| 2. Sandro Keller,Carolyn Vargas,Huaying Zhao,Grzegorz Piszczek,Chad A Brautigam,Peter Schuck. (2012-04-26) High-precision isothermal titration calorimetry with automated peak-shape analysis.. Analytical chemistry, 84 ((11)): (5066-5073). [PMID:22530732] |
| 3. Dennis M Whitfield. (2012-05-01) Complications of modeling glycosylation reactions: can the anomeric conformation of a donor determine the glycopyranosyl oxacarbenium ring conformation?. Carbohydrate research, 356 (191-195). [PMID:22542073] |
| 4. Shiqiang Yan,Ning Ding,Wei Zhang,Peng Wang,Yingxia Li,Ming Li. (2012-05-09) An efficient and recyclable catalyst for the cleavage of tert-butyldiphenylsilyl ethers.. Carbohydrate research, 354 (6-20). [PMID:22565030] |
| 5. Danqing Zheng,Shaoyu Li,Jie Wu. (2012-05-24) An unexpected silver triflate catalyzed reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate.. Organic letters, 14 ((11)): (2655-2657). [PMID:22616758] |
| 6. Yu Liu,Michael P Doyle. (2012-06-27) Michael addition/pericyclization/rearrangement--a multicomponent strategy for the synthesis of substituted resorcinols.. Organic & biomolecular chemistry, 10 ((31)): (6388-6394). [PMID:22733346] |
| 7. Luka S Kovacevic,Christopher Idziak,Augustinas Markevicius,Callum Scullion,Michael J Corr,Alan R Kennedy,Tell Tuttle,John A Murphy. (2012-07-19) Superelectrophilic amidine dications: dealkylation by triflate anion.. Angewandte Chemie (International ed. in English), 51 ((34)): (8516-8519). [PMID:22807275] |
| 8. Dominika Bratkowska,Núria Fontanals,Sylwia Ronka,Andrzej W Trochimczuk,Francesc Borrull,Rosa M Marcé. (2012-08-07) Comparison of different imidazolium supported ionic liquid polymeric phases with strong anion-exchange character for the extraction of acidic pharmaceuticals from complex environmental samples.. Journal of separation science, 35 ((15)): (1953-1958). [PMID:22865758] |
| 9. Yusuke Imazaki,Eiji Shirakawa,Ryota Ueno,Tamio Hayashi. (2012-08-25) Ruthenium-catalyzed transformation of aryl and alkenyl triflates to halides.. Journal of the American Chemical Society, 134 ((36)): (14760-14763). [PMID:22916734] |
| 10. Akio Saito,Nao Hyodo,Yuji Hanzawa. (2012-09-15) Synthesis of highly substituted oxazoles through iodine(III)-mediated reactions of ketones with nitriles.. Molecules (Basel, Switzerland), 17 ((9)): (11046-11055). [PMID:22976468] |
| 11. Atsushi Kinbara,Takehiro Yamagishi,Naoko Hanzawa,Etsuko Kawashima,Hiroaki Miyaoka. (2012-09-26) Synthesis of phenol derivatives from cyclohex-2-enones bearing an alkyne through Lewis acid-catalyzed enolization and intramolecular Alder-Rickert reaction.. The Journal of organic chemistry, 77 ((20)): (8999-9005). [PMID:23003109] |
| 12. Yu Hsien Lin,Bhaswati Ghosh,Kwok-Kong Tony Mong. (2012-10-02) In situ formation of β-glycosyl imidinium triflate from participating thioglycosyl donors: elaboration to disarmed-armed iterative glycosylation.. Chemical communications (Cambridge, England), 48 ((88)): (10910-10912). [PMID:23023321] |
| 13. Yan-ping Zhu,Feng-cheng Jia,Mei-cai Liu,Liu-ming Wu,Qun Cai,Yang Gao,An-xin Wu. (2012-10-13) I2-CF3SO3H synergistic promoted sp3 C-H bond diarylation of aromatic ketones.. Organic letters, 14 ((20)): (5378-5381). [PMID:23057842] |
| 14. Dahan Eom,Sangjune Park,Youngchul Park,Taekyu Ryu,Phil Ho Lee. (2012-10-26) Synthesis of indenes via Brønsted acid catalyzed cyclization of diaryl- and alkyl aryl-1,3-dienes.. Organic letters, 14 ((21)): (5392-5395). [PMID:23094690] |
| 15. Yasuyuki Muto,Yuta Murai,Yasuko Sakihama,Yasuyuki Hashidoko,Makoto Hashimoto. (2012-11-08) Effective Friedel-Crafts acylation of biotin acid chloride in trifluoromethanesulfonic acid.. Bioscience, biotechnology, and biochemistry, 76 ((11)): (2162-2164). [PMID:23132579] |
| 16. Fergus R Knight,Rebecca A M Randall,Lucy Wakefield,Alexandra M Z Slawin,J Derek Woollins. (2012-11-10) Investigating silver coordination to mixed chalcogen ligands.. Molecules (Basel, Switzerland), 17 ((11)): (13307-13329). [PMID:23138535] |
| 17. Su-Xia Xu,Lu Hao,Tao Wang,Zong-Cang Ding,Zhuang-Ping Zhan. (2012-11-29) Chemoselective synthesis of substituted pyrazoles through AgOTf-catalyzed cascade propargylic substitution-cyclization-aromatization.. Organic & biomolecular chemistry, 11 ((2)): (294-298). [PMID:23188378] |
| 18. B V Subba Reddy,M Ramana Reddy,Y Gopal Rao,J S Yadav,B Sridhar. (2013-01-18) Cu(OTf)2-catalyzed synthesis of 2,3-disubstituted indoles and 2,4,5-trisubstituted pyrroles from α-diazoketones.. Organic letters, 15 ((3)): (464-467). [PMID:23323540] |
| 19. Krystyna Poreba,Joanna Wietrzyk. (2013-01-30) The synthesis of 3,5,6,7-tetrasubstituted isoxazolo[4,5-b]pyridines and an evaluation of their in vitro antiproliferative activity.. Advances in clinical and experimental medicine : official organ Wroclaw Medical University, 21 ((5)): (563-571). [PMID:23356192] |
| 20. Jeong Hyeon Park,Chan Yi Park,Hyun Seung Song,Yun Suk Huh,Geon Hee Kim,Chan Pil Park. (2013-02-05) Green diacetoxylation of alkenes in a microchemical system.. Organic letters, 15 ((4)): (752-755). [PMID:23373522] |
| 21. Fumiya Urabe,Shunsuke Nagashima,Keisuke Takahashi,Jun Ishihara,Susumi Hatakeyama. (2013-04-13) Total synthesis of (-)-cinatrin C1 based on an In(OTf)3-catalyzed Conia-Ene reaction.. The Journal of organic chemistry, 78 ((8)): (3847-3857). [PMID:23578072] |
| 22. Lihui Zhu,Zhi-Guo Xi,Jian Lv,Sanzhong Luo. (2013-08-21) In(III)/PhCO2H binary acid catalyzed tandem [2 + 2] cycloaddition and Nazarov reaction between alkynes and acetals.. Organic letters, 15 ((17)): (4496-4499). [PMID:23947688] |
| 23. Hua-Dong Xu,Zhi-Hong Jia,Ke Xu,Hao Zhou,Mei-Hua Shen. (2014-12-17) One-pot protocol to functionalized benzopyrrolizidine catalyzed successively by Rh2(OAc)4 and Cu(OTf)2: a transition metal-Lewis acid catalysis relay.. Organic letters, 17 ((1)): (66-69). [PMID:25496025] |
| 24. Baocheng Zhou,Wenxing Chen. (2015-05-15) A Mild Catalytic Oxidation System: FePcOTf/H2O2 Applied for Cyclohexene Dihydroxylation.. Molecules (Basel, Switzerland), 20 ((5)): (8429-8439). [PMID:25970042] |
| 25. Tongfa Liu,Dongcheon Kim,Hongwei Han,Abd Rashid bin Mohd Yusoff,Jin Jang. (2015-06-02) Fine-tuning optical and electronic properties of graphene oxide for highly efficient perovskite solar cells.. Nanoscale, 7 ((24)): (10708-10718). [PMID:26030146] |
| 26. Hanchen Wei, Caiyun Yang, Feihu Bi, Bang Li, Rui Xie, Deshui Yu, Shuzhen Fang, Zan Hua, Qingqing Wang, Guang Yang. (2023) Structure-Controllable and Mass-Produced Glycopolymersomes as a Template of the Carbohydrate@Ag Nanobiohybrid with Inherent Antibacteria and Biofilm Eradication. BIOMACROMOLECULES, [PMID:38100369] [10.1021/acs.biomac.3c01003] |
| 27. Wang Haoyu, Li Lei, Cao Xinran, Zhen Mingming, Wang Chunru, Bai Chunli. (2023) Application of mannose-modified fullerene immunomodulator selectively polarizes tumor-associated macrophages potentiating antitumor immunity. Nano Research, 16 (11): (12855-12863). [10.1007/s12274-023-6266-x] |
| 28. Jiaqi Wu, Lei Zhang, Jinxing Long, Qiang Zeng, Biaolin Yin, Xuehui Li. (2022) Synthesis and fluorescent properties of quinoxaline derived ionic liquids. Green Energy & Environment, 7 (996). [10.1016/j.gee.2020.12.018] |
| 29. Guangming Lu, Shu Tian, Jingyu Li, Yongjian Xu, Shuan Liu, Jibin Pu. (2021) Fabrication of bio-based amphiphilic hydrogel coating with excellent antifouling and mechanical properties. CHEMICAL ENGINEERING JOURNAL, 409 (128134). [10.1016/j.cej.2020.128134] |
| 30. Rui Xu, Bolong Li, Jiale Ding, Wei Li, Yunhe Zhang. (2020) Donor–acceptor conjugates-functionalized aluminum phthalocyanines: Photophysical and nonlinear optical properties. EUROPEAN POLYMER JOURNAL, 134 (109813). [10.1016/j.eurpolymj.2020.109813] |
| 31. Jiale Ding, Zengduo Cui, Ningning Dong, Bolong Li, Yunhe Zhang, Jun Wang, Zhenhua Jiang. (2020) Enhanced optical limiting properties of composite films consisting of hyperbranched phthalocyanine and polyphenylsulfone with high linear transmittance. SYNTHETIC METALS, 265 (116405). [10.1016/j.synthmet.2020.116405] |
| 32. Bolong Li, Zengduo Cui, Yuping Han, Jiale Ding, Zhenhua Jiang, Yunhe Zhang. (2020) Novel axially substituted lanthanum phthalocyanines: Synthesis, photophysical and nonlinear optical properties. DYES AND PIGMENTS, 179 (108407). [10.1016/j.dyepig.2020.108407] |
| 33. Chenhua Shu, Faying Lai, Feng Zhu, Dan Luo. (2020) Optimal extractive and reductive desulfurization process using sodium borohydride in situ generated via sodium metaborate electroreduction in ionic liquid. Chemical Engineering and Processing-Process Intensification, 150 (107869). [10.1016/j.cep.2020.107869] |
| 34. Shu Tian, Daoyi Jiang, Jibin Pu, Xiaofeng Sun, Zhanming Li, Bin Wu, Wenru Zheng, Wenqing Liu, Zhixiong Liu. (2019) A new hybrid silicone-based antifouling coating with nanocomposite hydrogel for durable antifouling properties. CHEMICAL ENGINEERING JOURNAL, 370 (1). [10.1016/j.cej.2019.03.185] |
| 35. Haonan Xu, Yuping Han, Danying Zhao, Zheng Liu, Guibin Wang, Yunhe Zhang. (2025) Novel axial fullerenol-substituted hyperbranched phthalocyanines:Synthesis, photophysical and nonlinear optical properties. DYES AND PIGMENTS, 235 (112642). [10.1016/j.dyepig.2025.112642] |
| 36. Changwei Zhang, Hua Yuan, Hong Shen, Jianzhong Ye, Chengzhang Wang. (2024) Synthesis, light-controlled antibacterial and anti-tumor activities of Ginkgo biloba leaves polyprenols-based polypyridine metal complexes. Heliyon, 10 [PMID:39229538] [10.1016/j.heliyon.2024.e35479] |