视黄醇乙酸酯

1篇引用文献

COA

级别和纯度:

来自合成

crystalline solid or supercooled liquid

CAS编号: 127-47-9
分子式: C₂₂H₃₂O₂
分子量: 328.49
Beilstein号: 1915439
EC号: 204-844-2
PubChem编号: 638034

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货号 (SKU)	包装规格	是否现货
R431692-1g	1g	现货
R431692-5g	5g	现货
R431692-25g	25g	现货
R431692-100g	100g	现货

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基本描述

别名	醋酸维生素 A, 维生素 A 醋酸酯
英文别名	DTXSID6021240 \| Vitamin A acetate 10 microg/mL in Acetonitrile \| Myvax (VAN) \| NCGC00090756-09 \| Tox21_201423 \| trans-Retinyl acetate \| VitaminAacetate \| BDBM50442911 \| RETINYL ACETATE [USP-RS] \| NCGC00090756-02 \| NCGC00090756-06 \| trans-Vitamin A acetate
规格或纯度	来自合成, crystalline solid or supercooled liquid
英文名称	Retinyl acetate
生化机理	视黄醛、视黄醇和视黄酸是维生素 A 的醛、醇和酸形式。由于脂肪链中的不饱和键，维 a 酸的几何异构体较多。维 A 酸也以维 A 酸酯的形式存在，如丙酸维 A 酸、醋酸维 A 酸和维 A 棕榈酸酯。视黄醇酯提供维生素 A 库，可根据需要转化为视黄醇和其他维 A 酸。醋酸视黄醇具有广泛的生物学用途。
储存温度	-20°C储存
运输条件	超低温冰袋运输
产品介绍	维生素A通常以视黄酯形式的存在于食物中，而视黄酯是维生素A的前体来源。视黄醇乙酸酯是黄色晶体，不溶于水。它溶于乙醇和油。应用视黄醇乙酸酯已被用于：研究其对小鼠耳蜗发育的影响作为定量测定蛋黄中抗氧化剂的内标物成分作为测定血清视黄醇浓度的内标物 Vitamin A usually occurs in food as retinyl esters, which are the pre-formed sources of vitamin A. Retinyl acetate exists as yellow crystals and is insoluble in water. It is soluble in ethanol and oils. Application Retinyl acetate has been used: to study its effects on cochlear development in mice as a component of an internal standard to quantify antioxidants in yolk as an internal standard to determine serum retinol concentration

关联靶点（人）

ESR1 Tclin Estrogen receptor alpha (17718 活性数据)

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活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

VDR Tclin Vitamin D receptor (26531 活性数据)

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活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

RXRA Tclin Retinoid X receptor alpha (3637 活性数据)

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活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

ALDH1A1 Tchem Aldehyde dehydrogenase 1A1 (77053 活性数据)

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活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

NR1H4 Tclin Bile acid receptor FXR (6228 活性数据)

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CYP3A4 Tclin Cytochrome P450 3A4 (53859 活性数据)

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Lymphoblastoid cell (5959 活性数据)

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HSD17B10 Tchem Endoplasmic reticulum-associated amyloid beta-peptide-binding protein (20669 活性数据)

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活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

EHMT2 Tchem Histone-lysine N-methyltransferase, H3 lysine-9 specific 3 (93046 活性数据)

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TDP1 Tchem Tyrosyl-DNA phosphodiesterase 1 (345557 活性数据)

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活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

HPGD Tchem 15-hydroxyprostaglandin dehydrogenase [NAD+] (24926 活性数据)

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活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

SLCO1B1 Tchem Solute carrier organic anion transporter family member 1B1 (2672 活性数据)

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SLCO1B3 Tchem Solute carrier organic anion transporter family member 1B3 (2517 活性数据)

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RGS4 Tchem Regulator of G-protein signaling 4 (13867 活性数据)

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关联靶点（其它种属）

Cruzipain (33337 活性数据)

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Hdac6 Histone deacetylase 6 (222 活性数据)

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活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

rep Replicase polyprotein 1ab (378 活性数据)

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Mapt Microtubule-associated protein tau (6 活性数据)

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Nfe2l2 Nuclear factor erythroid 2-related factor 2 (214 活性数据)

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FTL Ferritin light chain (43324 活性数据)

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Nr1i2 Nuclear receptor subfamily 1 group I member 2 (14 活性数据)

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活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

SARS-CoV-2 (38078 活性数据)

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活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

作用机制

作用机制	Action Type	target ID	Target Name	Target Type	Target Organism	Binding Site Name	参考文献

名称和识别符

EC号	204-844-2
分子类型	小分子
IIUPAC Name	[(2E,4E,6E,8E)-3,7-dimethyl-9-(2,6,6-trimethylcyclohexen-1-yl)nona-2,4,6,8-tetraenyl] acetate
INCHI	1S/C22H32O2/c1-17(9-7-10-18(2)14-16-24-20(4)23)12-13-21-19(3)11-8-15-22(21,5)6/h7,9-10,12-14H,8,11,15-16H2,1-6H3/b10-7+,13-12+,17-9+,18-14+
InChi Key	QGNJRVVDBSJHIZ-QHLGVNSISA-N
Smiles	CC1=C(C(CCC1)(C)C)C=CC(=CC=CC(=CCOC(=O)C)C)C
Isomeric SMILES	CC1=C(C(CCC1)(C)C)/C=C/C(=C/C=C/C(=C/COC(=O)C)/C)/C
分子量	328.49
Beilstein号	1915439
Reaxy-Rn	1915438
Reaxys-RN link address	https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1915438&ln=

化学和物理性质

折光率	1.547-1.555
熔点	57-58 °C
分子量	328.500 g/mol
XLogP3	6.300
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	2
可旋转键计数Rotatable Bond Count	7
精确质量Exact Mass	328.24 Da
单同位素质量Monoisotopic Mass	328.24 Da
拓扑极表面积Topological Polar Surface Area	26.300 Å²
重原子数Heavy Atom Count	24
形式电荷Formal Charge	0
复杂度Complexity	595.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	4
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	4
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

象形图	GHS07, GHS08
信号词	危险
危险声明	H315: 引起皮肤刺激 H360: 可能损害生育力或未出生的孩子 H361: 怀疑破坏生育力或未出生的孩子 H413: 可能对水生生物造成长期的有害影响
预防措施声明	P264: 处理后要彻底洗手。 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理（请参阅此标签上的...）。 P302+P352: 如皮肤沾染：用水充分清洗。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P203: 使用前，获取、阅读并遵守所有安全说明。 P318: 如果暴露或担心，请就医。 P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。
WGK Germany	2
RTECS	VH6825000
个人防护装备	Eyeshields,full-face respirator (US),Gloves,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

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批号(Lot Number)	证书类型	货号
A2410345	分析证书	R431692
A2410347	分析证书	R431692
A2410349	分析证书	R431692
A2410351	分析证书	R431692
A2410344	分析证书	R431692
A2410346	分析证书	R431692
A2410348	分析证书	R431692
A2410350	分析证书	R431692
J2511177	分析证书	R431692
A2403056	分析证书	R431692

技术文档和文章

9-顺式视黄酸

Categories: 技术文章

探索主题:

抗癌维生素抗氧化

9-cis-Retinoic Acid

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Anti-cancer Vitamins Antioxidant Reduction

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引用文献

1. Roxana A Radu,Jane Hu,Jennifer Peng,Dean Bok,Nathan L Mata,Gabriel H Travis. (2008-05-14) Retinal pigment epithelium-retinal G protein receptor-opsin mediates light-dependent translocation of all-trans-retinyl esters for synthesis of visual chromophore in retinal pigment epithelial cells.. The Journal of biological chemistry, 283 ((28)): (19730-19738). [PMID:18474598]
2. Peter Coward,Marion Conn,Jie Tang,Fei Xiong,Anthony Menjares,Jeff D Reagan. (2008-10-28) Application of an allosteric model to describe the interactions among retinol binding protein 4, transthyretin, and small molecule retinol binding protein 4 ligands.. Analytical biochemistry, 384 ((2)): (312-320). [PMID:18952041]
3. M M Delgado-Zamarreño,M Bustamante-Rangel,M García-Jiménez,A Sánchez-Pérez,R Carabias-Martínez. (2008-10-31) Off-line coupling of pressurized liquid extraction and LC/ED for the determination of retinyl acetate and tocopherols in infant formulas.. Talanta, 70 ((5)): (1094-1099). [PMID:18970886]
4. Anne L Escaron,Michael H Green,Sherry A Tanumihardjo. (2008-12-02) Plasma turnover of 3,4-didehydroretinol (vitamin A2) increases in vitamin A-deficient rats fed low versus high dietary fat.. Journal of lipid research, 50 ((4)): (694-703). [PMID:19043141]
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20. Hui-Jeong Jang,Sang-Hwal Yoon,Hee-Kyung Ryu,Jung-Hun Kim,Chong-Long Wang,Jae-Yean Kim,Deok-Kun Oh,Seon-Won Kim. (2011-08-02) Retinoid production using metabolically engineered Escherichia coli with a two-phase culture system.. Microbial cell factories, 10 (59-59). [PMID:21801353]
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22. Pilar Viñas,María Bravo-Bravo,Ignacio López-García,Manuel Hernández-Córdoba. (2013-01-08) Quantification of β-carotene, retinol, retinyl acetate and retinyl palmitate in enriched fruit juices using dispersive liquid-liquid microextraction coupled to liquid chromatography with fluorescence detection and atmospheric pressure chemical ionization-mass spectrometry.. Journal of chromatography. A, 1275 (1-8). [PMID:23290361]
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29. Kara A Bresnahan,Christopher R Davis,Sherry A Tanumihardjo. (2014-04-09) Relative vitamin A values of 9-cis- and 13-cis-β-carotene do not differ when fed at physiological levels during vitamin A depletion in Mongolian gerbils (Meriones unguiculatus).. The British journal of nutrition, 112 ((2)): (162-169). [PMID:24709067]
30. Napaporn Riabroy,Sherry A Tanumihardjo. (2014-06-20) Oral doses of α-retinyl ester track chylomicron uptake and distribution of vitamin A in a male piglet model for newborn infants.. The Journal of nutrition, 144 ((8)): (1188-1195). [PMID:24944285]
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溶液计算器

摩尔浓度计算器

计算溶液所需的质量、体积或浓度。

质量

浓度

体积

分子量

g/mol

稀释计算器

计算配制储备溶液所需的稀释度。

浓度1（C1）

体积 1 (V1)

浓度 2 (C2)

体积 2 (V2)

复溶计算器

复溶计算器允许您快速计算试剂的体积，以复溶小瓶。只需输入试剂的质量和目标浓度，计算器将确定其余部分。

体积（添加到小瓶中）

质量（小瓶）

所需的复溶浓度