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邻苯二甲酸酐

11篇引用文献 COA COA
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货号 (SKU) 包装规格 是否现货 价格 数量
P116466-100g
 100g 现货 Stock Image
P116466-500g
 500g 现货 Stock Image
P116466-2.5kg
 2.5kg 现货 Stock Image
P116466-5kg
 5kg 现货 Stock Image
P116466-12×500g
 12×500g 现货 Stock Image
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砜类合成试剂 (3) 羧酸酐 (133) 非杂环砌块 (8221)
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基本描述

别名 邻苯二甲酸酐 | 苯酐
英文别名 CHEBI:36605 | PHTHALIC ANHYDRIDE | Wiltrol P | 1,3-DIOXOPHTHALANE | Anidride ftalica | pthalic anhydride | RCRA waste number U190 | STL194302 | HSDB 4012 | Phthalic anhydride treated gelatin | Phthalic anhydride, ACS reagent, >=99% | 2-Benzofuran-1,3-dion
规格或纯度 优级试剂, ≥99%
英文名称 o-Phthalic anhydride
储存温度 充氩
运输条件 常规运输
产品介绍

能升华，易溶于热水，成为苯二甲酸，能溶于醇，能溶于冷水，难溶于二硫化碳和醚。 标定碱的标准溶液，从仲醇、叔醇中分离伯醇。根据形成衍生物的溶点不同，检别伯胺和芳香族烃。除去苯中噻吩。邻苯二甲酸酐可用作制备 N-取代的邻苯二甲酰亚胺、聚（异噻吩）和甲基（S）-2-邻苯二甲酰亚氨基-4-甲基硫代丁酸酯的反应物。

Product Describtion:

Phthalic anhydride is an industrially important chemical. It can be prepared from o-xylene or naphthalene. It is widely used for the industrial preparation of plasticizers for PVC (polyvinyl chloride).Phthalic anhydride can be synthesized via oxidation of o-xylene, in the presence of V2O5/TiO2 monolithic catalyst supported by aluminium honeycomb.
纯度 ≥99%

关联靶点（人）

AR Tclin Androgen Receptor (11781 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
PPARG Tclin Peroxisome proliferator-activated receptor gamma (15191 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
CXCL8 Tchem Interleukin-8 (642 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
ALOX15 Tchem Arachidonate 15-lipoxygenase (7108 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
COLO 205 (50209 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
COLO 320 (353 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
MRC5 (9203 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Lymphoblastoid cell (5959 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
TDP1 Tchem Tyrosyl-DNA phosphodiesterase 1 (345557 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID

关联靶点（其它种属）

Abcb1b P-glycoprotein 1 (174 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Botrytis cinerea (4183 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Rorc Nuclear receptor ROR-gamma (89407 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Nr1i2 Nuclear receptor subfamily 1 group I member 2 (14 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID

作用机制

作用机制 Action Type target ID Target Name Target Type Target Organism Binding Site Name 参考文献

名称和识别符

PubChem SID 488180164
EC号 201-607-5
分子类型 小分子
IIUPAC Name 2-benzofuran-1,3-dione
INCHI 1S/C8H4O3/c9-7-5-3-1-2-4-6(5)8(10)11-7/h1-4H
InChi Key LGRFSURHDFAFJT-UHFFFAOYSA-N
Smiles C1=CC=C2C(=C1)C(=O)OC2=O
Isomeric SMILES C1=CC=C2C(=C1)C(=O)OC2=O
UN Number 2214
Packing Group III
分子量 148.12
Beilstein号 118515
Reaxy-Rn 118515
Reaxys-RN link address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=118515&ln=

化学和物理性质

溶解性 Soluble in water, carbon disulfide, ethanol, acetone and benzene. Slightly soluble in ethyl ether
密度 1.53
敏感性 对湿度敏感
闪点(℉) 305.6 °F
闪点(℃) 152 °C
沸点 295°C
熔点 130.8°C
分子量 148.110 g/mol
XLogP3 1.300
氢键供体数Hydrogen Bond Donor Count 0
氢键受体数Hydrogen Bond Acceptor Count 3
可旋转键计数Rotatable Bond Count 0
精确质量Exact Mass 148.016 Da
单同位素质量Monoisotopic Mass 148.016 Da
拓扑极表面积Topological Polar Surface Area 43.400 Ų
重原子数Heavy Atom Count 11
形式电荷Formal Charge 0
复杂度Complexity 187.000
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 1

安全和危险性（GHS）

一般危化品 一般危化品
象形图 GHS05,   GHS07,   GHS08
信号词 危险
危险声明

H302: 吞食有害

H315: 引起皮肤刺激

H317: 可能引起皮肤过敏反应

H318: 造成严重的眼睛损伤

H334: 吸入可能引起过敏或哮喘病症状或呼吸困难

H335: 可能引起呼吸道刺激

H402: 对水生生物有害
预防措施声明

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P264: 处理后要彻底洗手。

P270: 使用本产品时，请勿进食、饮水或吸烟。

P271: 仅在室外或通风良好的地方使用。

P272: 被污染的工作服不允许离开工作场所

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P284: 如果通风不良，请佩戴呼吸防护装置。

P321: 特殊处理（请参阅此标签上的...）。

P330: 漱口

P302+P352: 如皮肤沾染：用水充分清洗。

P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。

P333+P313: 如发生皮肤刺激或皮疹：求医/就诊。

P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。

P405: 密闭存放

P403+P233: 存放在通风良好的地方。保持容器密闭。

P501: 将内容物/容器处理到。。。

P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。

P301+P317: 如果被吞咽：请寻求医疗帮助。

P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。

P317: 寻求紧急医疗救助。

P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。

P319: 如果你感到不适，请寻求医疗帮助。

P342+P316: 如果出现呼吸道症状：立即寻求急救。
WGK Germany 1
RTECS TI3150000
Class 8
Merck Index 7372
个人防护装备 dust mask type N95 (US),Eyeshields,Faceshields,Gloves

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G2515467 分析证书 P116466
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引用文献

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8. Chuan-Fu Liu,Run-Cang Sun,Ai-Ping Zhang,Men-Hua Qin,Jun-Li Ren,Xin-Ai Wang.  (2007-02-27)  Preparation and characterization of phthalated cellulose derivatives in room-temperature ionic liquid without catalysts..  Journal of agricultural and food chemistry,  55  ((6)): (2399-2406).  [PMID:17319683]
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12. Kwan Soo Kim,Dinanath Baburao Fulse,Ju Yuel Baek,Bo-Young Lee,Heung Bae Jeon.  (2008-06-06)  Stereoselective direct glycosylation with anomeric hydroxy sugars by activation with phthalic anhydride and trifluoromethanesulfonic anhydride involving glycosyl phthalate intermediates..  Journal of the American Chemical Society,  130  ((26)): (8537-8547).  [PMID:18528988]
13. A Micó-Tormos,E F Simó-Alfonso,G Ramis-Ramos.  (2008-07-25)  Determination of fatty alcohol ethoxylates by derivatization with phthalic anhydride followed by liquid chromatography with UV-vis detection..  Journal of chromatography. A,  1203  ((1)): (47-53).  [PMID:18649884]
14. Yuichi Kajita,Takuya Kurahashi,Seijiro Matsubara.  (2008-12-04)  Nickel-catalyzed decarbonylative addition of anhydrides to alkynes..  Journal of the American Chemical Society,  130  ((51)): (17226-17227).  [PMID:19049285]
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20. Ana-Maria Oprea,Raluca Petronela Dumitriu,Cătălina Cheaburu,Cornelia Vasile.  (2011-01-18)  In vitro evaluation of ketoprofen controlled release from various formulations..  Revista medico-chirurgicala a Societatii de Medici si Naturalisti din Iasi,  114  ((3)): (829-835).  [PMID:21235124]
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23. Diana Guzman-Villanueva,Ibrahim M El-Sherbiny,Alexander V Vlassov,Dea Herrera-Ruiz,Hugh D C Smyth.  (2014-07-27)  Enhanced cellular uptake and gene silencing activity of siRNA molecules mediated by chitosan-derivative nanocomplexes..  International journal of pharmaceutics,  473  ((1-2)): (579-590).  [PMID:25063077]
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36. Xing Ruimin, Yang Haitang, Li Shengnan, Yang Jinghe, Zhao Xiaoyu, Wang Qinglong, Liu Shanhu, Liu Xiuhua.  (2017)  A sensitive and reliable rutin electrochemical sensor based on palladium phthalocyanine-MWCNTs-Nafion nanocomposite.  JOURNAL OF SOLID STATE ELECTROCHEMISTRY,  21  (5): (1219-1228).  [10.1007/s10008-016-3447-5]
37. Zhaoyu Cao, Minming Wu, Yunfei Zhao, Lisha Dai, Rong Zeng, Mei Tu, Jianhao Zhao.  (2016)  Bioinspired double-positively charged phosphodicholine-chitosan and zwitterionic phosphorylcholine-chitosan conjugates: The associated water structure, biocompatibility and antibacterial action.  REACTIVE & FUNCTIONAL POLYMERS,  103  (1).  [10.1016/j.reactfunctpolym.2016.03.018]
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