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Tag OxidizingAgents
Articles by tag "OxidizingAgents"
- Chromium Trioxide (CrO3) Chromium trioxide serves as a potent oxidizing agent, exhibiting insolubility in a majority of organic solvents and a propensity to detonate when in contact with organic compounds and solvents. When dissolved in water, it undergoes transformation into chromic acid and anhydrides, which ...
- Tetrabromomethane, CBr4 A facile synthesis of aryl carboxylic acids from aryl ketones by aerobic photooxidation using the inexpensive and easily handled CBr4 as catalyst is applicable to inert compounds under usual photo-irradiation conditions, and appears very attractive for the expansion of the Norrish Type I reaction.
- Cerium Ammonium Nitrate, CAN Cerium (IV) ammonium nitrate ((NH4)2Ce(NO3)6) is a one-electron oxidizing agent that is used for oxidative addition reactions of electrophilic radicals to alkenes, enabling intermolecular and intramolecular carbon-carbon and carbon-heteroatom bond formation. CAN also oxidizes secondary alcohols ...
- Chloramine-B, N-chlorobenzenesulfonamide sodium salt The use of chloramine-B as the oxidant and KI or NaBr as the halogen source enables a direct oxidative halogenation of terminal alkynes to provide synthetically valuable 1-iodoalkynes and 1-bromoalkynes in very good yields under mild reaction conditions.
- Chloramine-T, N-chloro tosylamide sodium salt Chloramine-T is a source of electrophilic chlorine. In water, chloramine-T is decomposed to yield hypochlorite, which acts as a disinfectant, and the sulfonamide moiety, which inhibits bacterial grow due to the similarity with para-aminobenzoic acid (a bacterial metabolite). Chloramine-T can ...
- Chloranil, Tetrachloro-1,4-benzoquinone Chloranil, and the parent benzoquinone, are relatively mild oxidants (dehydrogenation reagents).
- Benzoyl Peroxide (BPO) Benzoyl peroxide is a chemical compound with structural formula (C6H5−C(=O)O−)2, often abbreviated as (BzO)2. In terms of its structure, the molecule can be described as two benzoyl (C6H5−C(=O)−, Bz) groups connected by a peroxide (−O−O−). It is a white granular solid with a faint ...
- Sodium Hypochlorite (NaOCl) Sodium hypochlorite is an inexpensive, strong oxidizing agent, that is used as disinfectant and bleaching agent. It is unstable as a solid, but solutions of up to 40% are commercially available that contain NaOH and NaCl as byproducts of the preparation:
- N-Bromosaccharin N-Bromosaccharin
- N-Bromosuccinimide (NBS) N-Bromosuccinimide (NBS) is a brominating and oxidizing agent that is used as source for bromine in radical reactions (for example: allylic brominations) and various electrophilic additions. The NBS bromination of substrates such as alcohols and amines, followed by elimination of HBr in the ...