三甲基硅咪唑（TSIM）

12篇引用文献

COA

级别和纯度:

用于GC衍生化

≥98%

CAS编号: 18156-74-6
分子式: C₆H₁₂N₂Si
分子量: 140.26
Beilstein号: 606148
EC号: 242-040-3
MDL号: MFCD00005280
PubChem编号: 28925
PubChem SID: 504753393

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货号 (SKU)	包装规格	是否现货
T118634-5ml	5ml	现货
T118634-10×1ml	10×1ml	现货
T118634-25ml	25ml	现货
T118634-100ml	100ml	现货
T118634-500ml	500ml	期货

查看相关系列

五元杂环化合物 (2065) 元素分类的化合物 (2083) 硅化合物 (543) 硅烷化试剂 (51) 衍生化试剂 (59)

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基本描述

别名	N-三甲基硅烷基咪唑
英文别名	N-Trimethylsilylimidazole N-Trimethylsilylimidazole TMSI TMS-Imidazole TMS-Imidazole
规格或纯度	用于GC衍生化, ≥98%
英文名称	1-(Trimethylsilyl)imidazole
应用	高效硅烷化试剂，特别适合用于醇、酰基咪唑类的合成，在氨基存在的条件下保护羟基基团。抗菌素中间体。
储存温度	2-8°C储存
运输条件	冰袋运输
产品介绍	高效硅烷化试剂，特别适合用于醇、酰基咪唑类的合成，在氨基存在的条件下保护羟基基团。抗菌素中间体。
纯度	≥98%

关联靶点（人）

GMNN Tbio Geminin (128009 活性数据)

点击查看靶蛋白信息： GMNN

活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

关联靶点（其它种属）

ampC Beta-lactamase AmpC (62480 活性数据)

点击查看靶蛋白信息： ampC

活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

Plasmodium falciparum (966862 活性数据)

点击查看此靶标相关信息

活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

Txnrd1 Thioredoxin reductase 1, cytoplasmic (45279 活性数据)

点击查看靶蛋白信息： Txnrd1

活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

fba Putative fructose-1,6-bisphosphate aldolase (15559 活性数据)

点击查看靶蛋白信息： fba

活性类型	Relation	Activity value	Units	Action Type	期刊	PubMed Id	doi	Assay Aladdin ID

作用机制

作用机制	Action Type	target ID	Target Name	Target Type	Target Organism	Binding Site Name	参考文献

名称和识别符

PubChem SID	504753393
EC号	242-040-3
分子类型	小分子
IIUPAC Name	imidazol-1-yl(trimethyl)silane
INCHI	1S/C6H12N2Si/c1-9(2,3)8-5-4-7-6-8/h4-6H,1-3H3
InChi Key	YKFRUJSEPGHZFJ-UHFFFAOYSA-N
Smiles	C[Si](C)(C)N1C=CN=C1
Isomeric SMILES	C[Si](C)(C)N1C=CN=C1
PubChem CID	28925
分子量	140.26
Beilstein号	606148
Reaxy-Rn	606148

化学和物理性质

密度	0.957
敏感性	对潮湿敏感，对热敏感
折光率	n20/D 1.475
闪点(℉)	42.8 °F
闪点(℃)	6 °C
沸点	93-94°C/14mmHg
熔点	-42°C
分子量	140.260 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	1
可旋转键计数Rotatable Bond Count	1
精确质量Exact Mass	140.077 Da
单同位素质量Monoisotopic Mass	140.077 Da
拓扑极表面积Topological Polar Surface Area	17.800 Å²
重原子数Heavy Atom Count	9
形式电荷Formal Charge	0
复杂度Complexity	97.700
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

象形图	GHS02, GHS07
信号词	危险
危险声明	H225: 高度易燃的液体和蒸气 H226: 易燃液体和蒸气 H302: 吞食有害 H314: 造成严重的皮肤灼伤和眼睛损伤 H315: 引起皮肤刺激 H318: 造成严重的眼睛损伤 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H360: 可能损害生育力或未出生的孩子 H360D: 可能会伤害未出生的孩子 H400: 对水生生物有剧毒 H410: 对水生生物有剧毒并具有长期持续影响 H411: 对水生生物有毒并具有长期持续影响
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WGK Germany	3
RTECS	NI8700000
个人防护装备	Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

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批号(Lot Number)	证书类型	货号
L1713113	分析证书	T118634
J2410759	分析证书	T118634
A2002113	分析证书	T118634
I2320347	分析证书	T118634
I2320348	分析证书	T118634
I2320349	分析证书	T118634
I2320467	分析证书	T118634
I2320468	分析证书	T118634
I2320469	分析证书	T118634
I2320470	分析证书	T118634
I2320471	分析证书	T118634
B2510011	分析证书	T118634
J2211524	分析证书	T118634
B2510059	分析证书	T118634
C2219171	分析证书	T118634
C2219179	分析证书	T118634
C2219514	分析证书	T118634
C2219519	分析证书	T118634
C1807103	分析证书	T118634

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引用文献

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10. Jessica Zampolli,Elena Collina,Marina Lasagni,Patrizia Di Gennaro. (2014-11-18) Biodegradation of variable-chain-length n-alkanes in Rhodococcus opacus R7 and the involvement of an alkane hydroxylase system in the metabolism.. AMB Express, 4 (73-73). [PMID:25401074]
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13. Tuula M Jyske,Jussi-Petteri Suuronen,Andrey V Pranovich,Tapio Laakso,Ugai Watanabe,Katsushi Kuroda,Hisashi Abe. (2015-06-25) Seasonal variation in formation, structure, and chemical properties of phloem in Picea abies as studied by novel microtechniques.. Planta, 242 ((3)): (613-629). [PMID:26105650]
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