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1,4-二叠氮双环[2.2.2]辛烷, K v2.1通道阻断剂;K v3.4通道阻断剂

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货号 (SKU) 包装规格 是否现货 价格 数量
T105635-25g
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T105635-50g
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T105635-100g
 100g 现货 Stock Image
T105635-250g
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T105635-500g
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T105635-1kg
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T105635-5kg
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Analytical Chromatography Products (187) Kv2.1 Channel blocker (4) Kv3.4 Channel blocker (2)
main product photo

基本描述

别名 三乙烯二胺
英文别名 1,4-diazabicyclo(2,2,2)octane | 1,4-DIAZABICYCLO-(2,2,2)-OCTANE | EN300-18991 | 1,4-Diazabicyclo[2.2.2]octane | 1,4-diaza-bicyclo[2.2.2]octane | 1,4-DIAZABICYCLO-[2.2.2]OCTANE | 1,4-diazabicyclo-[2.2.2]-octane | 1,4-diazabicyclo[2.2.2]-octane | 1,4-Diazab
规格或纯度 Moligand™, ≥98%
英文名称 Triethylene diamine
应用 1,4-二氮杂双环[2.2.2]辛烷（DABCO）可以通过在亲偶极物存在下使伯硝基化合物脱水，以合成异恶唑衍生物。DABCO可用于制备以下物质： · DABCO双（过水合物） · DABCO一水合物 · DABCO六水合物
储存温度 充氩
运输条件 常规运输
作用类型 通道阻滞剂
作用机制 K v2.1通道阻断剂;K v3.4通道阻断剂
产品介绍

1,4-二氮杂双环[2.2.2]辛烷（DABCO，三亚乙基二胺），一种笼状叔二胺，通常用作化学合成中的有机碱。它也可以用作络合配体和催化剂。其气相电子吸收光谱、振动光谱、多光子电离（MPI）和双光子荧光激发（TPFE）光谱已被记录和分析。通过对固态DABCO进行质子磁共振（PMR）研究，以对其线宽、二次矩和自旋晶格弛豫时间进行了确定。1,4-二氮杂双环[2.2.2]辛烷（DABCO）可以通过在亲偶极物存在下使伯硝基化合物脱水，以合成异恶唑衍生物。DABCO可用于制备以下物质： · DABCO双（过水合物） · DABCO一水合物 · DABCO六水合物

An anti-fade reagent that scavenges free-radicals produced by the excitation of fluorochromes. Added to the mounting medium in fluorescence microscopy to retard photobleaching of fluorescein and other fluorescent dyes.
An anti-fade reagent shown to scavenge free-radicals due to flurochrome excitation.
纯度 ≥98%

关联靶点（人）

KCNB1 Tclin 钾电压门控通道亚家族 B 成员 1(Potassium voltage-gated channel subfamily B member 1) (1 活性数据)
活性类型 活性值-log(M) 作用机制 期刊 参考文献(PubMed IDs)
KCNC4 Tclin 钾电压门控通道亚家族C成员4(Potassium voltage-gated channel subfamily C member 4) (1 活性数据)
活性类型 活性值-log(M) 作用机制 期刊 参考文献(PubMed IDs)

名称和识别符

PubChem SID 504751806
EC号 205-999-9
分子类型 未知
IIUPAC Name 1,4-diazabicyclo[2.2.2]octane
INCHI 1S/C6H12N2/c1-2-8-5-3-7(1)4-6-8/h1-6H2
InChi Key IMNIMPAHZVJRPE-UHFFFAOYSA-N
Smiles C1CN2CCN1CC2
Isomeric SMILES C1CN2CCN1CC2
PubChem CID 9237
UN Number 1325
分子量 112.17
Beilstein号 103618
Reaxy-Rn 103618

化学和物理性质

溶解性 Soluble in water (460 mg/ml);Soluble in acetone, benzene, ethanol and methyl ethyl ketone.
密度 1.02
敏感性 易吸潮
折光率 1.4634
闪点(℉) 143.6 °F
闪点(℃) 62 °C
沸点 174°C
熔点 156-159°C
分子量 112.170 g/mol
XLogP3 -0.200
氢键供体数Hydrogen Bond Donor Count 0
氢键受体数Hydrogen Bond Acceptor Count 2
可旋转键计数Rotatable Bond Count 0
精确质量Exact Mass 112.1 Da
单同位素质量Monoisotopic Mass 112.1 Da
拓扑极表面积Topological Polar Surface Area 6.500 Ų
重原子数Heavy Atom Count 8
形式电荷Formal Charge 0
复杂度Complexity 61.500
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 1

安全和危险性（GHS）

象形图 GHS02,   GHS05,   GHS07
信号词 危险
危险声明

H228: 易燃固体

H302: 吞食有害

H315: 引起皮肤刺激

H318: 造成严重的眼睛损伤

H319: 引起严重眼睛刺激

H335: 可能引起呼吸道刺激

H412: 对水生生物有害并具有长期持续影响
预防措施声明

P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。

P240: 地面/粘结容器和接收设备

P241: 使用防爆的[电气/通风/照明/.../]设备。

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P264: 处理后要彻底洗手。

P270: 使用本产品时，请勿进食、饮水或吸烟。

P271: 仅在室外或通风良好的地方使用。

P273: 避免释放到环境中。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P321: 特殊处理（请参阅此标签上的...）。

P330: 漱口

P302+P352: 如皮肤沾染：用水充分清洗。

P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。

P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。

P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。

P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。

P405: 密闭存放

P403+P233: 存放在通风良好的地方。保持容器密闭。

P501: 将内容物/容器处理到。。。

P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。

P301+P317: 如果被吞咽：请寻求医疗帮助。

P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。

P317: 寻求紧急医疗救助。

P337+P317: 如果眼睛刺激持续：寻求医疗帮助。

P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。

P319: 如果你感到不适，请寻求医疗帮助。
WGK Germany 1
RTECS HM0354200
Merck Index 9669
个人防护装备 Eyeshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges

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引用文献

1. Gordon E, Cohen JL, Engel R, Abbott GW.  (2006)  1,4-Diazabicyclo[2.2.2]octane derivatives: a novel class of voltage-gated potassium channel blockers..  Mol Pharmacol,  69  (3): (718-26).  [PMID:16317109]
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3. Frauke Beilstein,Martin R Higgs,Nigel D Stow.  (2009-06-26)  Mutational analysis of the herpes simplex virus type 1 DNA packaging protein UL33..  Journal of virology,  83  ((17)): (8938-8945).  [PMID:19553324]
4. Mun Y Jung,Dong S Choi,Ki H Park,Bosoon Lee,David B Min.  (2011-05-04)  Luminescence spectroscopic observation of singlet oxygen formation in extra virgin olive oil as affected by irradiation light wavelengths, 1,4-diazabicyclo[2.2.2]octane, irradiation time, and oxygen bubbling..  Journal of food science,  76  ((1)): (C59-C63).  [PMID:21535654]
5. Michael Giese,Markus Albrecht,Christoph Bannwarth,Gerhard Raabe,Arto Valkonen,Kari Rissanen.  (2011-06-29)  From attraction to repulsion: anion-π interactions between bromide and fluorinated phenyl groups..  Chemical communications (Cambridge, England),  47  ((30)): (8542-8544).  [PMID:21709909]
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