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亚磷酸三苯酯

    级别和纯度:
  • ≥98%
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货号 (SKU) 包装规格 是否现货 价格 数量
T104038-100g
100g 现货 Stock Image
T104038-500g
500g 现货 Stock Image
T104038-2.5kg
2.5kg 现货 Stock Image
T104038-10kg
10kg 现货 Stock Image

基本描述

别名 三苯基氧化膦 | 亚磷酸三苯基酯 | 三苯基亚磷酸盐 | 三苯氧膦
英文别名 Trifenylfosfit [Czech] | Tris(phenoxy)phosphine | DTXSID0026252 | EINECS 202-908-4 | NSC-62219 | Mellite 310 | AI3-07866 | Trifenoxyfosfin | DTXCID306252 | Triphenyl Phosphite (TPPi) | Weston TPP | ADK Stab TPP | NCIOpen2_007800 | JP 360 | Trifenoxyfosfin
规格或纯度 ≥98%
英文名称 Triphenyl phosphite
应用 螯合剂,广泛用于各种PVC制品中,能使制品保持其透明度并能抑制颜色的变化,同时它可增加主稳定剂的抗氧性和光、热稳定性。另外,本品还用于PE、PP、ABS、SBS等制品中,并可作农药中间体。合成醇酸树脂和聚酯和聚酯树脂的原料。
储存温度 充氩
运输条件 常规运输
产品介绍

对湿敏感,遇潮气水解生成游离酚。能与醇、醚、苯和丙酮和等有机溶剂混溶,不溶于水。对紫外线有吸收作用,有刺激性 螯合剂,广泛用于各种PVC制品中,能使制品保持其透明度并能抑制颜色的变化,同时它可增加主稳定剂的抗氧性和光、热稳定性。另外,本品还用于PE、PP、ABS、SBS等制品中,并可作农药中间体。合成醇酸树脂和聚酯和聚酯树脂的原料。

Used to convert alcohols to alkyl halides, as a peptide coupling agent, and, in combination with ozone, as a low-temperature source of singlet oxygen, and ligand for metal-catalyzed reactions.


application:

Triphenyl phosphite can be used:

As a source of phosphorus and as a ligand for the synthesis of transition metal phosphide nanoparticles via heating-up process.

To convert alcohols to alkyl halides.

As a peptide coupling agent.

As a low-temperature source of singlet oxygen after forming an adduct with ozone.

To synthesize bromotriphenoxyphosphonium bromide, a brominating agent, by reacting with bromine.

纯度 ≥98%

关联靶点(人)

AR Tclin Androgen Receptor (11781 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
THRB Tclin Thyroid hormone receptor beta-1 (7926 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID

关联靶点(其它种属)

Nfe2l2 Nuclear factor erythroid 2-related factor 2 (214 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID

作用机制

作用机制 Action Type target ID Target Name Target Type Target Organism Binding Site Name 参考文献

名称和识别符

PubChem SID 504751386
分子类型 小分子
IIUPAC Name triphenyl phosphite
INCHI 1S/C18H15O3P/c1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h1-15H
InChi Key HVLLSGMXQDNUAL-UHFFFAOYSA-N
Smiles C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3
Isomeric SMILES C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3
UN Number 3077
Packing Group III
分子量 310.28
Beilstein号 1079456
Reaxy-Rn 1079456

化学和物理性质

溶解性 Insoluble in water
密度 1.184
敏感性 对湿度敏感 ,对空气敏感
凝固点 20 °C
折光率 1.59
闪点(℉) 410 °F
闪点(℃) 206℃
沸点 360°C
熔点 22-24°C
分子量 310.300 g/mol
XLogP3 5.500
氢键供体数Hydrogen Bond Donor Count 0
氢键受体数Hydrogen Bond Acceptor Count 3
可旋转键计数Rotatable Bond Count 6
精确质量Exact Mass 310.076 Da
单同位素质量Monoisotopic Mass 310.076 Da
拓扑极表面积Topological Polar Surface Area 27.700 Ų
重原子数Heavy Atom Count 22
形式电荷Formal Charge 0
复杂度Complexity 247.000
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 1

安全和危险性(GHS)

一般危化品 一般危化品
象形图 GHS07,   GHS09
信号词 警告
危险声明

H315: 引起皮肤刺激

H319: 引起严重眼睛刺激

H400: 对水生生物有剧毒

H410: 对水生生物有剧毒并具有长期持续影响

预防措施声明

P264: 处理后要彻底洗手。

P273: 避免释放到环境中。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P321: 特殊处理(请参阅此标签上的...)。

P391: 收集溢出物

P302+P352: 如皮肤沾染:用水充分清洗。

P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。

P362+P364: 脱掉沾污的衣服,清洗后方可重新使用。

P501: 将内容物/容器处理到。。。

P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。

P337+P317: 如果眼睛刺激持续:寻求医疗帮助。

P332+P317: 如果出现皮肤刺激:请寻求医疗帮助。

WGK Germany 2
RTECS TH1575000
Class 9
RIDADR UN 3077 9 / PGIII

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批号(Lot Number) 证书类型 货号
H2514087 分析证书 T104038
F2528104 分析证书 T104038
F2509084 分析证书 T104038
D2509098 分析证书 T104038
K21111070 分析证书 T104038
K21111072 分析证书 T104038
I2114004 分析证书 T104038
I2111026 分析证书 T104038
I2114005 分析证书 T104038
H2104371 分析证书 T104038
J2211197 分析证书 T104038
J2211201 分析证书 T104038
J2211202 分析证书 T104038
J2211203 分析证书 T104038
K2222362 分析证书 T104038
I2308194 分析证书 T104038
I2308196 分析证书 T104038
I2308199 分析证书 T104038
D2502105 分析证书 T104038
B2525040 分析证书 T104038
F2129391 分析证书 T104038

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此产品的引用文献

引用文献

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13. Shaokang Su, Chenfeng Guo, Li Li, Ying Xie, Song Wang, Kai Pan.  (2022)  Monodispersed nickel phosphide nanocrystals in situ grown on reduced graphene oxide matrix with excellent performance as the anode for lithium-ion batteries.  JOURNAL OF ELECTROANALYTICAL CHEMISTRY,  920  (116616).  [10.1016/j.jelechem.2022.116616]
14. Lichao Chen, Bo Wang, Haohao Ren, Yanan Wu, Defu Lyu, Yanan Ouyang, Qiyi Zhang, Yonggang Yan.  (2022)  Arg−Gly−Asp peptide functionalized poly-amino acid/ poly (p-benzamide) copolymer with enhanced mechanical properties and osteogenicity.  Biomaterials Advances,  133  (112627).  [PMID:35527153] [10.1016/j.msec.2021.112627]
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16. Xing-Zhou Lu, Chao Gu, Qi Zhang, Lei Shi, Shi-Kui Han, Guan-Ping Jin.  (2021)  Regioselective Construction of Chemically Transformed Phosphide–Metal Nanoheterostructures for Enhanced Hydrogen Evolution Catalysis.  INORGANIC CHEMISTRY,  60  (10): (7269–7275).  [PMID:33764054] [10.1021/acs.inorgchem.1c00348]
17. Yanyu Gao, Wei Zhang, Dongxu Li, Xiaoxue Lin, Xin Qiao, Haijun Niu, Wen Wang.  (2021)  Novel polyamides containing asymmetric diamine designed and synthesized towards electrochromic and resistance memory device.  SYNTHETIC METALS,  274  (116732).  [10.1016/j.synthmet.2021.116732]
18. Pan Zhaoqun, Chen Mianfeng, Zeng Keling, Kang Yingzi.  (2022)  Synthesis of Epoxy-Modified Methyl Phenyl Silicone Resins for LED Encapsulation.  Silicon,  14  (3): (1159-1167).  [10.1007/s12633-020-00868-6]
19. Canhuang Li, Siyong Wu, Yijing Qiu, Dongsheng Lu.  (2020)  Phosphorus-Containing C12H27O4P as Functional Electrolyte Additives for High-Voltage LiNi0.5Mn1.5O4/Graphite Li-Ion Batteries with Excellent Electrochemical Performance.  Advanced Materials Interfaces,  (3): (2001588).  [10.1002/admi.202001588]
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