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四丁基碘化铵

59篇引用文献 COA COA
    级别和纯度:
  • ≥99%
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货号 (SKU) 包装规格 是否现货 价格 数量
T103714-5g
 5g 现货 Stock Image
T103714-25g
 25g 现货 Stock Image
T103714-100g
 100g 现货 Stock Image
T103714-500g
 500g 现货 Stock Image
T103714-2.5kg
 2.5kg 现货 Stock Image
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相转移催化剂 (106) 聚合物/高分子试剂 (683)
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基本描述

别名 碘化四丁基铵
英文别名 TBAI | FT-0649550 | STR02456 | tetrabutylamonium iodide | C16H36IN | tetra butyl ammonium iodide | Tetra-n-butylammoniumjodid [Czech] | EINECS 206-220-5 | T0057 | terabutylammonium iodide | tetra-n-butylamrnonium iodide | D70426 | J-018250 | tetrabutyl am
规格或纯度 ≥99%
英文名称 Tetrabutylammonium iodide
储存温度 充氩
运输条件 常规运输
产品介绍

易吸湿。溶于水和乙醇，微溶于氯仿。有刺激性。水中溶解度<5%。 离子对色谱试剂，相转移催化剂，极谱分析试剂。有机合成。 Tetrabutylammonium iodide (TBAI) has been used as a catalyst in the following reactions: · Synthesis of O-benzyl-N-Boc-L-tyrosine benzyl ester from N-Boc-L-tyrosine. · Conversion of 8-fluoro-1-aminonaphthalene into 1-(8-fluoro-naphthalen-1-yl)piperazine hydrochloride. · Synthesis of 1-(2,4-dichlorophenyl)-5-(4-(4-iodobut-1-ynyl)phenyl)-4-methyl-N-(piperidin-1-yl)-1H-pyrazole-3-carboxamide from 4-(4-(1-(2,4-dichlorophenyl)-4-methyl-3-(piperidin-1-ylcarbamoyl)-1H-pyrazol-5-yl)phenyl)but-3-yn-1-yl methanesulfonate. Other reactions where TBAI can be used as a catalyst: · TBAI-tert-butyl hydroperoxide system can catalyze the conversion of α-methyl styrene derivatives into allylic sulfones by reacting with sulfonylhydrazides under metal-free conditions. · Palladium(0)-catalyzed cross-coupling between benzylic zinc bromides and aryl or alkenyl triflates. · Three-component coupling of amines, carbon dioxide, and halides to form ca

Tetrabutylammonium iodide (TBAI) has been used as a catalyst in the following reactions: · Synthesis of O-benzyl-N-Boc-L-tyrosine benzyl ester from N-Boc-L-tyrosine. · Conversion of 8-fluoro-1-aminonaphthalene into 1-(8-fluoro-naphthalen-1-yl)piperazine hydrochloride. · Synthesis of 1-(2,4-dichlorophenyl)-5-(4-(4-iodobut-1-ynyl)phenyl)-4-methyl-N-(piperidin-1-yl)-1H-pyrazole-3-carboxamide from 4-(4-(1-(2,4-dichlorophenyl)-4-methyl-3-(piperidin-1-ylcarbamoyl)-1H-pyrazol-5-yl)phenyl)but-3-yn-1-yl methanesulfonate. Other reactions where TBAI can be used as a catalyst: · TBAI-tert-butyl hydroperoxide system can catalyze the conversion of α-methyl styrene derivatives into allylic sulfones by reacting with sulfonylhydrazides under metal-free conditions. · Palladium(0)-catalyzed cross-coupling between benzylic zinc bromides and aryl or alkenyl triflates. · Three-component coupling of amines, carbon dioxide, and halides to form carbamates in the presence of cesium carbonate.
纯度 ≥99%

关联靶点（其它种属）

Staphylococcus epidermidis (22802 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Escherichia coli (133304 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID

作用机制

作用机制 Action Type target ID Target Name Target Type Target Organism Binding Site Name 参考文献

名称和识别符

PubChem SID 504754170
EC号 206-220-5
分子类型 小分子
IIUPAC Name tetrabutylazanium;iodide
INCHI 1S/C16H36N.HI/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;/h5-16H2,1-4H3;1H/q+1;/p-1
InChi Key DPKBAXPHAYBPRL-UHFFFAOYSA-M
Smiles CCCC[N+](CCCC)(CCCC)CCCC.[I-]
Isomeric SMILES CCCC[N+](CCCC)(CCCC)CCCC.[I-]
PubChem CID 67553
分子量 369.37
Beilstein号 3916152
Reaxy-Rn 3916152

化学和物理性质

溶解性 Soluble in water and methanol. Insoluble in benzene.
密度 1.2
敏感性 对湿度和光线敏感
熔点 145-148°C
分子量 369.370 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count 0
氢键受体数Hydrogen Bond Acceptor Count 1
可旋转键计数Rotatable Bond Count 12
精确质量Exact Mass 369.189 Da
单同位素质量Monoisotopic Mass 369.189 Da
拓扑极表面积Topological Polar Surface Area 0.000 Ų
重原子数Heavy Atom Count 18
形式电荷Formal Charge 0
复杂度Complexity 116.000
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 2

安全和危险性（GHS）

象形图 GHS05,   GHS07
信号词 危险
危险声明

H302: 吞食有害

H315: 引起皮肤刺激

H318: 造成严重的眼睛损伤

H319: 引起严重眼睛刺激

H335: 可能引起呼吸道刺激
预防措施声明

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P264: 处理后要彻底洗手。

P270: 使用本产品时，请勿进食、饮水或吸烟。

P271: 仅在室外或通风良好的地方使用。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P321: 特殊处理（请参阅此标签上的...）。

P330: 漱口

P302+P352: 如皮肤沾染：用水充分清洗。

P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。

P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。

P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。

P405: 密闭存放

P403+P233: 存放在通风良好的地方。保持容器密闭。

P501: 将内容物/容器处理到。。。

P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。

P301+P317: 如果被吞咽：请寻求医疗帮助。

P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。

P317: 寻求紧急医疗救助。

P337+P317: 如果眼睛刺激持续：寻求医疗帮助。

P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。

P319: 如果你感到不适，请寻求医疗帮助。
WGK Germany 3
RTECS BS5450000
个人防护装备 dust mask type N95 (US),Eyeshields,Gloves

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找到21个结果

批号(Lot Number) 证书类型 货号
A2411078 分析证书 T103714
D2510031 分析证书 T103714
K2407215 分析证书 T103714
L2118215 分析证书 T103714
L2118216 分析证书 T103714
L2118231 分析证书 T103714
K2117471 分析证书 T103714
F2103354 分析证书 T103714
F2103355 分析证书 T103714
F2103356 分析证书 T103714
B23111212 分析证书 T103714
B23111213 分析证书 T103714
B23111214 分析证书 T103714
B23111219 分析证书 T103714
B23111221 分析证书 T103714
C2429030 分析证书 T103714
C2429080 分析证书 T103714
H2514024 分析证书 T103714
L2426179 分析证书 T103714
A2125133 分析证书 T103714
A2125130 分析证书 T103714

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引用文献

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11. Kosei Sugahara,Toshihiro Kimura,Keigo Kamata,Kazuya Yamaguchi,Noritaka Mizuno.  (2012-07-14)  A highly negatively charged γ-Keggin germanodecatungstate efficient for Knoevenagel condensation..  Chemical communications (Cambridge, England),  48  ((67)): (8422-8424).  [PMID:22790486]
12. Muhammet Uyanik,Tatsuya Mutsuga,Kazuaki Ishihara.  (2012-07-20)  IBS-catalyzed regioselective oxidation of phenols to 1,2-quinones with Oxone®..  Molecules (Basel, Switzerland),  17  ((7)): (8604-8616).  [PMID:22810194]
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14. Matt Petrowsky,Allison Fleshman,Mohd Ismail,Daniel T Glatzhofer,Dharshani N Bopege,Roger Frech.  (2012-07-31)  Molecular and system parameters governing mass and charge transport in polar liquids and electrolytes..  The journal of physical chemistry. B,  116  ((33)): (10098-10105).  [PMID:22838847]
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40. Amir Said, Guanyun Zhang, Caiyun Liu, Dexin Wang, Huihui Niu, Yanshu Liu, Guanjie Chen, Chen-Ho Tung, Yifeng Wang.  (2023)  A butterfly-like lead-doped titanium-oxide compound with high performance in photocatalytic cycloaddition of CO2 to epoxide.  DALTON TRANSACTIONS,  52  (8): (2392-2403).  [PMID:36723215] [10.1039/D2DT03990G]
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