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甲醇中扑灭津溶液标准物质

    级别和纯度:
  • 1000μg/ml in Methanol
有货

库存信息

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货号 (SKU) 包装规格 是否现货 价格 数量
P265663-1.2ml
1.2ml 现货 Stock Image
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代谢物 (8911)

基本描述

英文别名 propazine | 139-40-2 | Gesamil | Prozinex | Milogard | Plantulin | Primatol P | Propazin | Propasin | Milo-pro | 2-Chloro-4,6-bis(isopropylamino)-s-triazine | Propazine (herbicide) | 2,4-Bis(isopropylamino)-6-chloro-1,3,5-triazine | Geigy 30,028 | 6-Chloro-N,N'-bis(1-methylethyl)-1,
规格或纯度 1000μg/ml in Methanol
英文名称 Propazine Solution in Methanol
储存温度 2-8°C储存,避光
运输条件 冰袋运输
产品介绍

本标准物质主要用于测量仪器校准,分析方法评价和质量控制,以及食品,卫生,环境和农业等领域相应成分含量测定与残留检测,也可用于量值溯源或作为标准储备溶液,通过逐级稀释配制成各种工作用标准溶液等。


样品制备


本标准物质采用纯度准确定值的扑灭津纯品为原料,以HPLC级甲醇为溶剂,采用重量-容量法准确配制而成。

扑灭津,英文名称: Propazine,CAS: 139-40-2


溯源性及定值方法


本标准物质以配制值作为标准值,采用HPLC-MS对本批次标准物质和质量控制对照样品进行比对,核验配制值。通过使用满足计量学特性要求的制备方法,测量方法和计量器具,保证标准物质的量值溯源性。


特性量值及不确定度


编号名称标准值(μg/mL)不确定度(%)(k=2)
P265663甲醇中扑灭津10003

           

标准值的不确定度主要由原料纯度,称量,定容以及均匀性,稳定性等不确定度分量合成。


均匀性检验及稳定性考察


依据JJF1343-2012[标准物质定值的通用原则及统计学原理],对分装后的样品进行随机抽样,对溶液浓度进行均匀性检验,稳定性考察。结果表明,本标准物质均匀性,稳定性良好。

本标准物质量值自定值日期起,有效期为24个月, 研制单位将继续跟踪监测该标准物质的稳定性,有效期内如发现量值变化,将及时通知用户。


包装、运输和贮存、使用及注意事项


1.包装: 本标准物质采用硼硅酸盐玻璃安瓿瓶包装,约1.2mL/支,移取或稀释时请以移液管量取为准。

2.运输和贮存: 冰袋运输,运输时应避免挤压,碰撞;冷藏和避光条件下贮存。

3.使用: 启封前于室温(20±3℃)平衡,并充分摇匀。安瓿瓶一经打开,应立即使用,不可再次熔封后作为标准物质使用。

This standard substance is mainly used for measuring instrument calibration, analysis method evaluation and quality control, as well as the content determination and residue detection of corresponding components in the fields of food, hygiene, environment and agriculture. It can also be used for value traceability or as a standard stock solution. Dilute and prepare various standard solutions for work.


Sample Preparation


This standard substance is made of pure pumaijin with accurate purity as raw material, HPLC grade methanol as solvent, and accurate preparation by weight-volume method.

Propazine, English name: Propazine, CAS: 139-40-2


Traceability and valuation method


This standard material takes the prepared value as the standard value, and uses HPLC-MS to compare the batch of standard materials and quality control control samples to verify the prepared value. Through the use of preparation methods, measurement methods and measuring instruments that meet the requirements of metrological characteristics, the traceability of the value of the reference material is guaranteed.


Characteristic value and uncertainty


NumberNameStandard value(μg/mL)Uncertainty(%)(k=2)
P265663Propazine Solution in Methanol10003


The uncertainty of the standard value is mainly composed of raw material purity, weighing, constant volume, uniformity, stability and other uncertainty components.


Uniformity inspection and stability inspection


According to JJF1343-2012 [General Principles and Statistical Principles for Determining Standard Material Values], the samples after subpackage are randomly sampled, the solution concentration is tested for uniformity and stability. The results show that the standard material has good uniformity and stability.

The quality value of this standard material is valid for 24 months from the date of setting the value. The development unit will continue to track and monitor the stability of the standard material. If the value changes within the validity period, the user will be notified in time.


Packaging, transportation and storage, use and precautions


1. Packaging: This standard substance is packaged in borosilicate glass ampoule, about 1.2mL/piece, please refer to the pipette volume when pipetting or diluting.

2. Transportation and storage: ice bag transportation, avoid squeezing and collision during transportation; store under refrigerated and dark conditions.

3. Use: Equilibrate at room temperature (20±3℃) before unpacking and shake well. Once the ampoule is opened, it should be used immediately. It cannot be used as a standard substance after being sealed again.

关联靶点(人)

THRB Tclin Thyroid hormone receptor beta-1 (7926 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
GAA Tclin Lysosomal alpha-glucosidase (35701 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
GLP1R Tclin Glucagon-like peptide 1 receptor (111429 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
POLK Tbio DNA polymerase kappa (8653 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
APEX1 Tchem DNA-(apurinic or apyrimidinic site) lyase (38016 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
TDP1 Tchem Tyrosyl-DNA phosphodiesterase 1 (345557 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
SLCO1B1 Tchem Solute carrier organic anion transporter family member 1B1 (2672 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID

关联靶点(其它种属)

FTL Ferritin light chain (43324 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID

作用机制

作用机制 Action Type target ID Target Name Target Type Target Organism Binding Site Name 参考文献

名称和识别符

EC号 205-359-9
分子类型 小分子
IIUPAC Name 6-chloro-2-N,4-N-di(propan-2-yl)-1,3,5-triazine-2,4-diamine
INCHI 1S/C9H16ClN5/c1-5(2)11-8-13-7(10)14-9(15-8)12-6(3)4/h5-6H,1-4H3,(H2,11,12,13,14,15)
InChi Key WJNRPILHGGKWCK-UHFFFAOYSA-N
Smiles CC(C)NC1=NC(=NC(=N1)Cl)NC(C)C
Isomeric SMILES CC(C)NC1=NC(=NC(=N1)Cl)NC(C)C
分子量 229.71
Beilstein号 747081
Reaxy-Rn 747081
Reaxys-RN link address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=747081&ln=

化学和物理性质

闪点(℃) 11°C
分子量 229.710 g/mol
XLogP3 2.900
氢键供体数Hydrogen Bond Donor Count 2
氢键受体数Hydrogen Bond Acceptor Count 5
可旋转键计数Rotatable Bond Count 4
精确质量Exact Mass 229.109 Da
单同位素质量Monoisotopic Mass 229.109 Da
拓扑极表面积Topological Polar Surface Area 62.700 Ų
重原子数Heavy Atom Count 15
形式电荷Formal Charge 0
复杂度Complexity 169.000
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 1

安全和危险性(GHS)

象形图 GHS08,   GHS09
信号词 警告
危险声明

H351: 怀疑引起遗传缺陷

H400: 对水生生物有剧毒

H410: 对水生生物有剧毒并具有长期持续影响

预防措施声明

P273: 避免释放到环境中。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P391: 收集溢出物

P405: 密闭存放

P501: 将内容物/容器处理到。。。

P203: 使用前,获取、阅读并遵守所有安全说明。

P318: 如果暴露或担心,请就医。

WGK Germany 3
RTECS XY5300000
个人防护装备 dust mask type N95 (US), Eyeshields, Gloves

质检证书(CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):
输入批号以搜索分析图谱:

此产品的引用文献

引用文献

1. Du Pengfei, Song Jiamu, Zou Xinya, Han Zhenlong, Li Jiayan, Chen Baoshan, He Xipu.  (2023)  Highly sensitive fluorescent probe for mesotrione based on nitrogen and sulfur co-doped graphene quantum dots.  JOURNAL OF NANOPARTICLE RESEARCH,  25  (12): (1-12).  [10.1007/s11051-023-05894-0]
2. Chun Wang, Qianqian Wang, Jintao Yu, Xinmeng Wang, Lijuan Wang, Bin Zhao, Lin Hao, Weihua Liu, Zhi Wang, Hao Chen, Qiuhua Wu.  (2023)  Converting waste expanded polystyrene into higher-value-added hyper-crosslinked porous polymer for rapid and high-efficient adsorption of aflatoxins.  Journal of Cleaner Production,  408  (137102).  [10.1016/j.jclepro.2023.137102]
3. Yumei Yan, Zhili Liu, Wenfeng Zhou, Haixiang Gao, Runhua Lu.  (2023)  Construction of multiple modes using gold nanoparticles as probes for the rapid detection of fenpyroximate.  Analytical Methods,  15  (13): (1713-1721).  [PMID:36938594] [10.1039/D3AY00139C]
4. Wei Zhong, Jin Zou, Qi Yu, Yansha Gao, Fengli Qu, Shuwu Liu, Hui Zhou, Limin Lu.  (2023)  Ultrasensitive indirect electrochemical sensing of thiabendazole in fruit and water by the anodic stripping voltammetry of Cu2+ with hierarchical Ti3C2Tx-TiO2 for signal amplification.  FOOD CHEMISTRY,  402  (134379).  [PMID:36179525] [10.1016/j.foodchem.2022.134379]
5. Qianqian Wang, Ranxiao Tang, Mingming Xu, Junmin Wang, Shuofeng Li, Weihua Liu, Lin Hao, Shuaihua Zhang, Junhong Zhou, Chun Wang, Qiuhua Wu, Zhi Wang.  (2022)  Sustainable synthesis of hydroxyl-functional porous organic framework as novel adsorbent for effective removal of organic micropollutants from water.  JOURNAL OF ENVIRONMENTAL MANAGEMENT,  321  (115952).  [PMID:35985270] [10.1016/j.jenvman.2022.115952]
6. Jilong Li, Fengze Wu, Yupu Zhang, Ji Feng, Xiujuan Wang, Yi Yang, Zhibing Wang, Hanqi Zhang.  (2023)  Application of supramolecular solvent based on the surface-active ionic liquid in dispersive liquid–liquid microextraction of triazine herbicides in tea samples.  FOOD CHEMISTRY,  399  (133901).  [PMID:36001927] [10.1016/j.foodchem.2022.133901]
7. Feng Ji, Zhao Zhe, Li Jilong, Shan Zhenhua, Yang Yi, Wang Zhibing, Zhang Hanqi.  (2022)  Vortex-assisted dispersive liquid–liquid microextraction based on the solidification of sedimentary deep eutectic solvents for the determination of triazine and phenylurea herbicides in milk samples.  Analytical Methods,  14  (4): (460-468).  [PMID:35023520] [10.1039/D1AY01788H]
8. Qianqian Wang, Weihua Liu, Lin Hao, Chun Wang, Qiuhua Wu, Zhi Wang.  (2020)  Fabrication of magnetic porous organic framework for effective enrichment and assay of nitroimidazoles in chicken meat.  FOOD CHEMISTRY,  332  (127427).  [PMID:32619936] [10.1016/j.foodchem.2020.127427]
9. Wang Qianqian, Li Gaigai, Wang Chun, Wu Qiuhua, Wang Zhi.  (2020)  Layered porous organic frameworks as a novel adsorbent for the solid phase extraction of chlorophenols prior to their determination by HPLC-DAD.  MICROCHIMICA ACTA,  187  (4): (1-11).  [PMID:32152748] [10.1007/s00604-020-4195-x]
10. Wenqiang Jing, Yanying Zhou, Jiaqin Wang, Miao Ni, Wentao Bi, David Da Yong Chen.  (2019)  Dispersive Magnetic Solid-Phase Extraction Coupled to Direct Analysis in Real Time Mass Spectrometry for High-Throughput Analysis of Trace Environmental Contaminants.  ANALYTICAL CHEMISTRY,  91  (17): (11240–11246).  [PMID:31373488] [10.1021/acs.analchem.9b02197]
11. Zan Li, Jun Jia, Mingwei Wang, Hua Zhang, Hongyuan Yan, Fengxia Qiao.  (2017)  Bifunctionalized ordered mesoporous organosilica synthesized in deep eutectic solvent for extraction of triazine herbicides from watermelon.  JOURNAL OF CHROMATOGRAPHY A,  1529  (50).  [PMID:29132822] [10.1016/j.chroma.2017.10.074]
12. Qingxiang Zhou, Zhi Fang.  (2015)  Use of TiO2 nanotube arrays as the adsorbents for preconcentration of triazine herbicides in environmental water samples prior to determination using high performance liquid chromatography.  Analytical Methods,  (7): (3277-3282).  [10.1039/C4AY03012E]
13. Guijiao Zhao, Chenhuan Wang, Min Kang, Lin Hao, Weihua Liu, Zhi Wang, Xiaodong Shi, Qiuhua Wu.  (2024)  Construction of magnetic azo-linked porous polymer for highly-efficient enrichment and separation of phenolic endocrine disruptors from environmental water and fish.  FOOD CHEMISTRY,  445  (138698).  [PMID:38350198] [10.1016/j.foodchem.2024.138698]
14. Yang Xu, Jingyi Bao, Yuhan Ning, Weiping Wang, Ai-jun Wang, Jiu-ju Feng.  (2024)  Porous poly(bismaleimide-co-divinylbenzene) microspheres as dispersive solid-phase extraction adsorbent coupled to high-performance liquid chromatography for the determination of triazine herbicide residues in vegetable samples.  JOURNAL OF SEPARATION SCIENCE,  47  (5): (2300746).  [PMID:38471966] [10.1002/jssc.202300746]
15. Linna Guo, Qianqian Wang, Qiuhua Wu, Chun Wang, Baojiang Chen.  (2025)  β-Cyclodextrin based magnetic hyper-crosslinked polymer: A recyclable adsorbent for effective preconcentration of triazine herbicides in complex sample matrices.  FOOD CHEMISTRY,  463  (141219).  [PMID:39276543] [10.1016/j.foodchem.2024.141219]

溶液计算器