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六氯乙烷

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库存信息

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货号 (SKU) 包装规格 是否现货 价格 数量
H110387-100g
100g 现货 Stock Image
H110387-500g
500g 现货 Stock Image

基本描述

别名 六氯乙烷 | 六氯化碳,过氯乙烷,六氯化三碳,全氯乙烷
英文别名 1,1,1,2,2,2-Hexachloroethane | 1,1,1,2,2,2-Hexachloro-ethane | InChI=1/C2Cl6/c3-1(4,5)2(6,7) | STL199166 | AKOS009158985 | Distopin | HEXACHLOROETHANE | 1,1,1,2,2,2-hexakis(chloranyl)ethane | EPA Pesticide Chemical Code 045201 | Ethane hexachloride | Falk
规格或纯度 试剂级
英文名称 Hexachloroethane
运输条件 常规运输
产品介绍

有类似樟脑香味,不易燃。溶于乙醇、乙醚、苯、氯仿和油类;不溶于水。有樟脑气味,易升华,在空气中易挥发。

Effect of hydrogen peroxide concentrations on the degradation of hexachloroethane in the absence and the presence of tetrachloroethene by Fenton′s reagent has been investigated

Hexachloroethane was used as catalyst in preparation of chlorosilanes from hydrosilanes. It was used to investigate the transformation of hexachloroethane in natural waters. It was used as reagent during polycondensation reaction of p-aminobenzoic acid.

Effect of hydrogen peroxide concentrations on the degradation of hexachloroethane in the absence and the presence of tetrachloroethene by Fenton′s reagent has been investigated

Hexachloroethane was used as catalyst in preparation of chlorosilanes from hydrosilanes. It was used to investigate the transformation of hexachloroethane in natural waters. It was used as reagent during polycondensation reaction of p-aminobenzoic acid.

关联靶点(人)

KCNH2 Tclin HERG (29587 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID

关联靶点(其它种属)

Aspergillus nidulans (364 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Mus musculus (284745 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Rattus norvegicus (775804 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
lef Anthrax lethal factor (7585 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Nfe2l2 Nuclear factor erythroid 2-related factor 2 (214 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID
Rorc Nuclear receptor ROR-gamma (89407 活性数据)
活性类型 Relation Activity value Units Action Type 期刊 PubMed Id doi Assay Aladdin ID

作用机制

作用机制 Action Type target ID Target Name Target Type Target Organism Binding Site Name 参考文献

名称和识别符

PubChem SID 488180023
EC号 200-666-4
分子类型 小分子
IIUPAC Name 1,1,1,2,2,2-hexachloroethane
INCHI 1S/C2Cl6/c3-1(4,5)2(6,7)8
InChi Key VHHHONWQHHHLTI-UHFFFAOYSA-N
Smiles C(C(Cl)(Cl)Cl)(Cl)(Cl)Cl
Isomeric SMILES C(C(Cl)(Cl)Cl)(Cl)(Cl)Cl
UN Number 2811
Packing Group I
分子量 236.74
Beilstein号 1740341
Reaxy-Rn 1740341
Reaxys-RN link address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1740341&ln=

化学和物理性质

溶解性 Insoluble in water.
密度 2.091
沸点 186°C
熔点 185°C
分子量 236.700 g/mol
XLogP3 4.100
氢键供体数Hydrogen Bond Donor Count 0
氢键受体数Hydrogen Bond Acceptor Count 0
可旋转键计数Rotatable Bond Count 0
精确质量Exact Mass 235.81 Da
单同位素质量Monoisotopic Mass 233.813 Da
拓扑极表面积Topological Polar Surface Area 0.000 Ų
重原子数Heavy Atom Count 8
形式电荷Formal Charge 0
复杂度Complexity 61.500
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 1

安全和危险性(GHS)

一般危化品 一般危化品
象形图 GHS07,   GHS08,   GHS09
信号词 危险
危险声明

H315: 引起皮肤刺激

H319: 引起严重眼睛刺激

H335: 可能引起呼吸道刺激

H350: 可能导致癌症

H351: 怀疑引起遗传缺陷

H400: 对水生生物有剧毒

H410: 对水生生物有剧毒并具有长期持续影响

H411: 对水生生物有毒并具有长期持续影响

预防措施声明

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P264: 处理后要彻底洗手。

P271: 仅在室外或通风良好的地方使用。

P273: 避免释放到环境中。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P321: 特殊处理(请参阅此标签上的...)。

P391: 收集溢出物

P302+P352: 如皮肤沾染:用水充分清洗。

P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。

P305+P351+P338: 如进入眼睛:用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出,取出隐形眼镜。继续冲洗。

P362+P364: 脱掉沾污的衣服,清洗后方可重新使用。

P405: 密闭存放

P403+P233: 存放在通风良好的地方。保持容器密闭。

P501: 将内容物/容器处理到。。。

P203: 使用前,获取、阅读并遵守所有安全说明。

P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。

P318: 如果暴露或担心,请就医。

P337+P317: 如果眼睛刺激持续:寻求医疗帮助。

P332+P317: 如果出现皮肤刺激:请寻求医疗帮助。

P319: 如果你感到不适,请寻求医疗帮助。

WGK Germany 3
RTECS KI4025000
Class 6.1
Merck Index 4679
个人防护装备 Eyeshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges

质检证书(CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):
输入批号以搜索分析图谱:

通过匹配包装上的批号来查找并下载产品的 COA,每批产品都进行了严格的验证,您可放心使用!

找到9个结果

批号(Lot Number) 证书类型 货号
H2513574 分析证书 H110387
H2513758 分析证书 H110387
A2309402 分析证书 H110387
K22301108 分析证书 H110387
K22301109 分析证书 H110387
D2319433 分析证书 H110387
E2522022 分析证书 H110387
B2224237 分析证书 H110387
B2225006 分析证书 H110387

此产品的引用文献

引用文献

1. P S Holmes.  (1999-11-02)  Pneumomediastinum associated with inhalation of white smoke..  Military medicine,  164  ((10)): (751-752).  [PMID:10544633]
2.  (2000-05-11)  Hexachloroethane..  IARC monographs on the evaluation of carcinogenic risks to humans,  73  (295-306).  [PMID:10804959]
3. M E Walsh,P Kyritsis,N A Eady,H A Hill,L L Wong.  (2000-09-06)  Catalytic reductive dehalogenation of hexachloroethane by molecular variants of cytochrome P450cam (CYP101)..  European journal of biochemistry,  267  ((18)): (5815-5820).  [PMID:10971594]
4. E V Patterson,C J Cramer,D G Truhlar.  (2001-07-18)  Reductive dechlorination of hexachloroethane in the environment: mechanistic studies via computational electrochemistry..  Journal of the American Chemical Society,  123  ((9)): (2025-2031).  [PMID:11456825]
5. Gerard Cornelissen,Joris Haftka,John Parsons,Orjan Gustafsson.  (2005-06-15)  Sorption to black carbon of organic compounds with varying polarity and planarity..  Environmental science & technology,  39  ((10)): (3688-3694).  [PMID:15952373]
6. Qiang Yin,Yong Ye,Guo Tang,Yu-Fen Zhao.  (2005-08-23)  Studies on the structure behavior of triphenyldichlorophosphorane in different solvents..  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,  63  ((1)): (192-195).  [PMID:16112605]
7. Ching-Hui Loh,Yaw-Wen Chang,Saou-Hsing Liou,Jun-Hei Chang,Hong-I Chen.  (2006-05-06)  Case report: hexachloroethane smoke inhalation: a rare cause of severe hepatic injuries..  Environmental health perspectives,  114  ((5)): (763-765).  [PMID:16675434]
8. Thomas B Hofstetter,Christopher M Reddy,Linnea J Heraty,Michael Berg,Neil C Sturchio.  (2007-08-19)  Carbon and chlorine isotope effects during abiotic reductive dechlorination of polychlorinated ethanes..  Environmental science & technology,  41  ((13)): (4662-4668).  [PMID:17695912]
9. Ilaria Massarelli,Marcello Imbriani,Alessio Coi,Marilena Saraceno,Niccolò Carli,Anna Maria Bianucci.  (2009-03-11)  Development of QSAR models for predicting hepatocarcinogenic toxicity of chemicals..  European journal of medicinal chemistry,  44  ((9)): (3658-3664).  [PMID:19272677]
10. Olha Furman,Derek F Laine,Alexander Blumenfeld,Amy L Teel,Kenichi Shimizu,I Francis Cheng,Richard I Watts.  (2009-04-09)  Enhanced reactivity of superoxide in water-solid matrices..  Environmental science & technology,  43  ((5)): (1528-1533).  [PMID:19350930]
11. Veerachai Pongkittiphan,Emmanuel A Theodorakis,Warinthorn Chavasiri.  (2010-04-03)  Hexachloroethane: a highly efficient reagent for the synthesis of chlorosilanes from hydrosilanes..  Tetrahedron letters,  50  ((36)): (5080-5082).  [PMID:20360997]
12. Cheng-Hsiu Chou,Tung-Wei Kao,Saou-Hsing Liou,Hong-I Chen,Hsiu-Ying Ku,Hui-Jung Chuang,Ching-Hui Loh.  (2010-04-14)  Hematological abnormalities of acute exposure to hexachloroethane smoke inhalation..  Inhalation toxicology,  22  ((6)): (486-492).  [PMID:20384461]
13. Kai Chen,John C Mackie,Eric M Kennedy,Bogdan Z Dlugogorski.  (2010-12-03)  Air pollutants formed in thermal decomposition of folpet fungicide under oxidative conditions..  Environmental science & technology,  45  ((2)): (554-560).  [PMID:21121660]
14.  (2011-08-20)  Hexachloroethane..  Report on carcinogens : carcinogen profiles,  12  (227-229).  [PMID:21852846]
15. Bofan Yu,Yonghui Song,Lu Han,Huibin Yu,Yang Liu,Hongliang Liu.  (2014-07-07)  Optimizations of packed sorbent and inlet temperature for large volume-direct aqueous injection-gas chromatography to determine high boiling volatile organic compounds in water..  Journal of chromatography. A,  1356  (221-229).  [PMID:24997514]
16.  (2004-08-26)  Hexachloroethane..  Report on carcinogens : carcinogen profiles,  10  (135-137).  [PMID:15326659]
17. Ludwig Weissflog,Gert Krueger,Nikolai Elansky,Erich Putz,Christian A Lange,Lida Lisitzina,Andrea Pfennigsdorff,Karsten Kotte.  (2006-05-06)  The phytotoxic effect of C(1)/C(2)-halocarbons and trichloroacetic acid on the steppe plant Artemisia lerchiana..  Chemosphere,  65  ((6)): (975-980).  [PMID:16674990]
18. Ching-Hui Loh,Saou-Hsing Liou,Yaw-Wen Chang,Hong-I Chen,Wann-Cherng Perng,Hsiu-Ying Ku,Yeong-Hwang Chen.  (2008-04-18)  Hepatic injuries of hexachloroethane smoke inhalation: the first analytical epidemiological study..  Toxicology,  247  ((2-3)): (119-122).  [PMID:18417266]
19. Fernando Gil,Antonio Pla,Antonio F Hernández,Juan M Mercado,Fernando Méndez.  (2008-06-28)  A fatal case following exposure to zinc chloride and hexachloroethane from a smoke bomb in a fire simulation at a school..  Clinical toxicology (Philadelphia, Pa.),  46  ((6)): (563-565).  [PMID:18584371]
20. K R Schmidt,A Tiehm.  (2008-10-01)  Natural attenuation of chloroethenes: identification of sequential reductive/oxidative biodegradation by microcosm studies..  Water science and technology : a journal of the International Association on Water Pollution Research,  58  ((5)): (1137-1145).  [PMID:18824815]
21. Xiaoxia Lu,John T Wilson,Donald H Kampbell.  (2009-01-06)  Comparison of an assay for Dehalococcoides DNA and a microcosm study in predicting reductive dechlorination of chlorinated ethenes in the field..  Environmental pollution (Barking, Essex : 1987),  157  ((3)): (809-815).  [PMID:19121882]
22. E H Jho,N Singhal,S Turner.  (2010-09-08)  Fenton degradation of tetrachloroethene and hexachloroethane in Fe(II) catalyzed systems..  Journal of hazardous materials,  184  ((1-3)): (234-240).  [PMID:20817400]
23.  (2004-01-01)  Hexachloroethane..  Report on carcinogens : carcinogen profiles,  11  (III140-III141).  [PMID:21089887]
24. Changcheng Wei, Jinzhe Li, Zhongmin Liu.  (2023)  Selective Synthesis of Butadiene from γ-Valerolactone over ZSM-35 Zeolite.  ACS Sustainable Chemistry & Engineering,  11  (38): (14103–14111).  [10.1021/acssuschemeng.3c03592]
25. Changcheng Wei, Wenna Zhang, Kuo Yang, Xiu Bai, Shutao Xu, Jinzhe Li, Zhongmin Liu.  (2023)  An efficient way to use CO2 as chemical feedstock by coupling with alkanes.  CHINESE JOURNAL OF CATALYSIS,  47  (138).  [10.1016/S1872-2067(23)64416-X]
26. Yanqing Xue, Qitang Hao, Xinlei Li, Han Zhang, Peiqing Wang, Chengze Yin, Bo Li, Xinliang Wang.  (2022)  Acquiring Mg-Ag microalloying TiB2/Al-4.5Cu composite simultaneously with ultrahigh strength and ductility via optimized salt-metal reaction and multistage heat treatment.  MATERIALS & DESIGN,  223  (111252).  [10.1016/j.matdes.2022.111252]
27. Yanqing Xue, Bo Li, Xinliang Wang, Xinlei Li, Han Zhang, Qitang Hao.  (2021)  Effect of Mg on the microstructure evolution and mechanical properties of 5%TiB2/Al−4.5%Cu composites.  Materials Today Communications,  28  (102625).  [10.1016/j.mtcomm.2021.102625]
28. Na Liu, Qing Hu, Chao Wang, Lizhi Tong, Chih-Huang Weng, Longzhen Ding.  (2021)  Hexachloroethane dechlorination in sulfide-containing aqueous solutions catalyzed by nitrogen-doped carbon materials.  ENVIRONMENTAL POLLUTION,  281  (116915).  [PMID:33799207] [10.1016/j.envpol.2021.116915]
29. Siyang Tang, Zhen Liu, Xiaowei Yan, Ning Li, Ruihua Cheng, Xuelian He, Boping Liu.  (2014)  Kinetic studies on the pyrrole–Cr-based Chevron-Phillips ethylene trimerization catalyst system.  APPLIED CATALYSIS A-GENERAL,  481  (39).  [10.1016/j.apcata.2014.04.006]

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