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Chiralyst Ru914 - 99.95% metals basis, high purity , CAS No.916197-27-8

COA

Grade & Purity:

≥99.95% metals basis

Cas Number: 916197-27-8
Molecular Weight: 913.99
PubChem CID: 138115063

In stock

Item Number

C294419

Grouped product items
SKU	Size	Availability	Price	Qty
C294419-1g	1g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$687.90

Discover Chiralyst Ru914 by Aladdin Scientific in 99.95% metals basis for only $687.90. Available - in Ligands at Aladdin Scientific. Tags: .

Basic Description

Synonyms	849238-54-6 \| 916197-27-8 \| Ruthenium, bis(acetato- \| EO, \| EO')[[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[bis(3,5-dimethylphenyl)phosphine- \| EP]]-, (OC-6-22) \| Ruthenium, bis(acetato- \| EO, \| EO')[1,1'-[(1R)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(3
Specifications & Purity	≥99.95% metals basis
Legal Information	Product of Umicore
Storage Temp	Room temperature
Shipped In	Normal
Product Description	Product class M-P, Homogeneous Catalysts, M-O, Acetate Ligands, Phosphorus Ligands - Chiral Reaction type Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation Chemical properties Chemical formula C50H54O6P2Ru Empirical formula Ru[(R)-Xyl-MeO-BIPHEP](OAc)2 Molecular weight 913.99 Metal Ru Theoretical metal content 11 Physical state powder Color brown Metal purity 99.95 Applications & references Asymmetric hydrogenation of (Z)-methyl 3-amino-4-methoxy butenoate. Reference: Org. Proc. Res. Dev. 2011, 15, 353 (DOI: 10.1021/op034181b) Synthesis of (S)-fluoromethyldihydro-furan-2-one for the manufacture of pyrido[2,1-α]isoquinoline derivatives which are useful for treatment or prophylaxis of diseases. Reference: WO2006 125728

Names and Identifiers

IUPAC Name	[2-[2-bis(3,5-dimethylphenyl)phosphaniumyl-6-methoxyphenyl]-3-methoxyphenyl]-bis(3,5-dimethylphenyl)phosphanium;ruthenium(2+);diacetate
INCHI	InChI=1S/C46H48O2P2.2C2H4O2.Ru/c1-29-17-30(2)22-37(21-29)49(38-23-31(3)18-32(4)24-38)43-15-11-13-41(47-9)45(43)46-42(48-10)14-12-16-44(46)50(39-25-33(5)19-34(6)26-39)40-27-35(7)20-36(8)28-40;21-2(3)4;/h11-28H,1-10H3;21H3,(H,3,4);/q;;;+2
InChIKey	OSAVHRNXJVTRTO-UHFFFAOYSA-N
Smiles	CC1=CC(=CC(=C1)[PH+](C2=CC=CC(=C2C3=C(C=CC=C3[PH+](C4=CC(=CC(=C4)C)C)C5=CC(=CC(=C5)C)C)OC)OC)C6=CC(=CC(=C6)C)C)C.CC(=O)[O-].CC(=O)[O-].[Ru+2]
Isomeric SMILES	CC1=CC(=CC(=C1)[PH+](C2=CC=CC(=C2C3=C(C=CC=C3[PH+](C4=CC(=CC(=C4)C)C)C5=CC(=CC(=C5)C)C)OC)OC)C6=CC(=CC(=C6)C)C)C.CC(=O)[O-].CC(=O)[O-].[Ru+2]
PubChem CID	138115063
Molecular Weight	913.99

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