Basic Description

Synonyms	Bis(triphenylphosphine)palladium(II) dichloride, ChemDose(TM) tablets, Loading: 1mumol per tablet \| PDCL2(PPH3)2 \| 6,6'-((1E,1'E)-(4-Methyl-1,3-phenylene)bis(diazene-2,1-diyl))bis(4-methylbenzene-1,3-diamine) \| Dichlorobis(triphenylphosphine)palladium(II)
Specifications & Purity	≥98%
Storage Temp	Store at 2-8°C,Protected from light,Argon charged
Shipped In	Wet ice This product requires cold chain shipping. Ground and other economy services are not available.
Product Description	Application Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction.Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported.It is employed as catalyst for the Heck reaction medium. Bis(triphenylphosphine)palladium(II) dichloride is an organometallic complex. It is an efficient cross-coupling catalyst for C-C coupling reaction, such as Negishi coupling, Suzuki coupling, Sonogashira coupling and Heck coupling reaction.Detection of bis(triphenylphosphine)palladium(II) dichloride by electrospray ionization quadrupole ion trap mass spectrometry using different imidazolium salts as the charge carrier has been reported.It is employed as catalyst for the Heck reaction medium. Palladium-catalyzed coupling of iodo-α-β-unsaturated esters to afford tetrasubstituted olefins Product class M-P, Homogeneous Catalysts, Monodentate Ligands, Phosphorus Ligands - Achiral Reaction type Cross Coupling Reactions with Arenes, Carbonylation, Mizoroki Heck Coupling Reaction, Sonogashira-Hagihara Coupling Reaction, Stille Reaction, Cyclization, Oxidation, Reduction Chemical properties Chemical formula C36H30Cl2P2Pd Empirical formula [Pd(PPh3)2Cl2] Molecular weight 701.91 Metal Pd Theoretical metal content 15 Physical state powder Color yellow Applications & references Synthesis of the pyrazolopyridinone-based p38 mitogen-activated protein kinase inhibitor including a Suzuki coupling reaction. p38 MAP kinases are intercellular serine/threonine kinases which certainly regulate the production and action of several pro-inflammatory mediators. They are also involved in disease states such as rheumatoid arthritis, Crohn’s diseases and psoriasis. Reference: Org. Proc. Res. Dev. 2011, 15, 31. (DOI: 10.1021/op100205s) Mild and effective direct palladium catalyzed C-H alkynylation of electron-rich heterocycles. Synthesis of spiro-indane-oxindoles with a tandem Heck / C-H functionalization. Reference: Angew. Chem. Int. Ed. 2008, 47, 4711. (DOI: 10.1002/anie.200800549) Palladium catalyzed intermolecular decarboxylative coupling in the presence of reactive C-H groups. Reference: J. Org. Chem. 2010, 75, 1550. (DOI: 10.1021/jo9022793) High yielding Palladium catalyzed C-H arylation of electron-enriched heteroarenes with aryl bromides. Reference: J. Org. Chem. 2010, 75, 6998. (DOI: 10.1021/jo101433g)

Taxonomic Classification

Taxonomy Tree

Kingdom Organic compounds
- Superclass Benzenoids
  - Class Benzene and substituted derivatives
    - Subclass Phenylphosphines and derivatives

Kingdom	Organic compounds
Superclass	Benzenoids
Class	Benzene and substituted derivatives
Subclass	Phenylphosphines and derivatives
Intermediate Tree Nodes	Not available
Direct Parent	Phenylphosphines and derivatives
Alternative Parents	Organic phosphines and derivatives Organic transition metal salts Organic metal halides Organopnictogen compounds Organic chloride salts Hydrocarbon derivatives
Molecular Framework	Not available
Substituents	Triphenylphosphine - Phenylphosphine - Phosphine - Organic metal halide - Organic transition metal salt - Organopnictogen compound - Hydrocarbon derivative - Organic chloride salt - Organic salt - Organophosphorus compound - Aromatic homomonocyclic compound
Description	This compound belongs to the class of organic compounds known as phenylphosphines and derivatives. These are compounds containing a phenylphosphine, which consists of phosphine substituent bound to a phenyl group.
External Descriptors	Not available
1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61. DOI: 10.1186/s13321-016-0174-y

Names and Identifiers

IUPAC Name	dichloropalladium;triphenylphosphane
INCHI	InChI=1S/2C18H15P.2ClH.Pd/c21-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h21-15H;2*1H;/q;;;;+2/p-2
InChIKey	YNHIGQDRGKUECZ-UHFFFAOYSA-L
Smiles	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Pd]Cl
Isomeric SMILES	C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.Cl[Pd]Cl
WGK Germany	3
PubChem CID	6102075
Molecular Weight	701.9
Beilstein	4935975
Reaxy-Rn	13172189

Certificates（CoA,COO,BSE/TSE and Analysis Chart)

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Analytical Chart:

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23 results found

Lot Number	Certificate Type	Date	Item
E2509156	Certificate of Analysis	Apr 23, 2025	D196276
E2509155	Certificate of Analysis	Apr 23, 2025	D196276
E2509157	Certificate of Analysis	Apr 23, 2025	D196276
B2512069	Certificate of Analysis	Feb 17, 2025	D196276
D2518272	Certificate of Analysis	Jul 13, 2024	D196276
D2518273	Certificate of Analysis	Jul 13, 2024	D196276
F2421249	Certificate of Analysis	May 31, 2024	D196276
F2421250	Certificate of Analysis	May 31, 2024	D196276
D2518274	Certificate of Analysis	Mar 22, 2024	D196276
A2425013	Certificate of Analysis	Nov 28, 2023	D196276
A2426029	Certificate of Analysis	Nov 28, 2023	D196276
K2317117	Certificate of Analysis	Nov 28, 2023	D196276
E2414014	Certificate of Analysis	Nov 28, 2023	D196276
J2311043	Certificate of Analysis	Sep 04, 2023	D196276
H2328062	Certificate of Analysis	Sep 04, 2023	D196276
B2317765	Certificate of Analysis	Dec 12, 2022	D196276
B2317717	Certificate of Analysis	Dec 12, 2022	D196276
C2320411	Certificate of Analysis	Jun 30, 2022	D196276
F2301030	Certificate of Analysis	Jun 30, 2022	D196276
J2221145	Certificate of Analysis	Jun 30, 2022	D196276
J2221146	Certificate of Analysis	Jun 30, 2022	D196276
C2222024	Certificate of Analysis	May 14, 2021	D196276
G2211043	Certificate of Analysis	Mar 04, 2021	D196276

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Chemical and Physical Properties

Solubility	Insoluble in water. Soluble in benzene, and toluene.
Sensitivity	Moisture & Air & light & Heat sensitive
Melt Point(°C)	297-298°C
Molecular Weight	701.900 g/mol
XLogP3
Hydrogen Bond Donor Count	0
Hydrogen Bond Acceptor Count	0
Rotatable Bond Count	6
Exact Mass	700.023 Da
Monoisotopic Mass	700.023 Da
Topological Polar Surface Area	0.000 Å²
Heavy Atom Count	41
Formal Charge	0
Complexity	204.000
Isotope Atom Count	0
Defined Atom Stereocenter Count	0
Undefined Atom Stereocenter Count	0
Defined Bond Stereocenter Count	0
Undefined Bond Stereocenter Count	0
The total count of all stereochemical bonds	0
Covalently-Bonded Unit Count	3

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SKU	Size	Availability	Price
D196276-1g	1g	3	$59.90
D196276-5g	5g	1	$199.90
D196276-25g	25g	1	$713.90

Bis(triphenylphosphine)palladium(II) dichloride - ≥98%, high purity , CAS No.13965-03-2