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(+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate - ≥98%(S,S)-Me-DUPHOS-Rh, high purity , CAS No.136705-75-4

COA

Grade & Purity:

≥98%
(S,S)-Me-DUPHOS-Rh

Cas Number: 136705-75-4
Molecular Weight: 666.52
MDL number: MFCD00269863
PubChem CID: 5702642

In stock

Item Number

B282807

Grouped product items
SKU	Size	Availability	Price
B282807-100mg	100mg	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$169.90
B282807-500mg	500mg	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$589.90
B282807-2g	2g	Available within 8-12 weeks(?) Production requires sourcing of materials. We appreciate your patience and understanding.	$2,123.90

Discover (+)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I)trifluoromethanesulfonate by Aladdin Scientific in ≥98%(S,S)-Me-DUPHOS-Rh for only $169.90. Available - in Ligands at Aladdin Scientific. Catalysts & Chiral Catalysts Tags: .

Basic Description

Synonyms	(1Z,5Z)-cycloocta-1,5-diene;(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane;rhodium;trifluoromethanesulfonate \| 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I) trifluoromethanesulfonate \| AKOS015
Specifications & Purity	≥98%, (S,S)-Me-DUPHOS-Rh
Legal Information	(S,S)-Duphos and BPE Rhodium Catalysts Kit component.
Storage Temp	Store at 2-8°C
Shipped In	Wet ice This product requires cold chain shipping. Ground and other economy services are not available.

Taxonomic Classification

Taxonomy Tree

Kingdom Organic compounds
- Superclass Organic acids and derivatives
  - Class Organic sulfonic acids and derivatives
    - Subclass Organosulfonic acids and derivatives
      - Level5 Alkanesulfonic acids and derivatives
        Level6 Alkanesulfonic acids
        Level7 Trifluoromethanesulfonates

Kingdom	Organic compounds
Superclass	Organic acids and derivatives
Class	Organic sulfonic acids and derivatives
Subclass	Organosulfonic acids and derivatives
Intermediate Tree Nodes	Alkanesulfonic acids and derivatives - Alkanesulfonic acids
Direct Parent	Trifluoromethanesulfonates
Alternative Parents	Benzene and substituted derivatives Sulfonyls Phospholanes Methanesulfonates Organosulfonic acids Trihalomethanes Organic phosphines and derivatives Cycloalkenes Phosphacyclic compounds Organic transition metal salts Organic oxides Unsaturated aliphatic hydrocarbons Hydrocarbon derivatives Organopnictogen compounds Alkyl fluorides Organofluorides Organic anions
Molecular Framework	Not available
Substituents	Trifluoromethanesulfonate - Monocyclic benzene moiety - Benzenoid - Methanesulfonate - Phospholane - Organosulfonic acid - Sulfonyl - Trihalomethane - Phosphine - Cyclic olefin - Phosphacycle - Organic transition metal salt - Organoheterocyclic compound - Cycloalkene - Unsaturated aliphatic hydrocarbon - Unsaturated hydrocarbon - Organic oxide - Organic oxygen compound - Alkyl halide - Organosulfur compound - Organophosphorus compound - Organofluoride - Organohalogen compound - Olefin - Alkyl fluoride - Organopnictogen compound - Hydrocarbon derivative - Halomethane - Organic anion - Hydrocarbon - Aromatic heteromonocyclic compound
Description	This compound belongs to the class of organic compounds known as trifluoromethanesulfonates. These are alkanesulfonic acids, that contain a sulfonate group that is substituted with a trifluoromethyl group.
External Descriptors	Not available
1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61. DOI: 10.1186/s13321-016-0174-y

Names and Identifiers

IUPAC Name	(1Z,5Z)-cycloocta-1,5-diene;(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]phenyl]-2,5-dimethylphospholane;rhodium;trifluoromethanesulfonate
INCHI	InChI=1S/C18H28P2.C8H12.CHF3O3S.Rh/c1-13-9-10-14(2)19(13)17-7-5-6-8-18(17)20-15(3)11-12-16(20)4;1-2-4-6-8-7-5-3-1;2-1(3,4)8(5,6)7;/h5-8,13-16H,9-12H2,1-4H3;1-2,7-8H,3-6H2;(H,5,6,7);/p-1/b;2-1-,8-7-;;/t13-,14-,15-,16-;;;/m0.../s1
InChIKey	HFNBCEIZBZROGX-KZOFNLLLSA-M
Smiles	CC1CCC(P1C2=CC=CC=C2P3C(CCC3C)C)C.C1CC=CCCC=C1.C(F)(F)(F)S(=O)(=O)[O-].[Rh]
Isomeric SMILES	C[C@@H]1P([C@H](CC1)C)C2=CC=CC=C2P3[C@H](CC[C@@H]3C)C.C1/C=C\CC/C=C\C1.C(S(=O)(=O)[O-])(F)(F)F.[Rh]
WGK Germany	3
PubChem CID	5702642
Molecular Weight	666.52

Certificates（CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):

Analytical Chart:

Chemical and Physical Properties

Sensitivity	air sensitive
Molecular Weight	666.500 g/mol
XLogP3
Hydrogen Bond Donor Count	0
Hydrogen Bond Acceptor Count	6
Rotatable Bond Count	2
Exact Mass	666.118 Da
Monoisotopic Mass	666.118 Da
Topological Polar Surface Area	65.600 Å²
Heavy Atom Count	37
Formal Charge	-1
Complexity	495.000
Isotope Atom Count	0
Defined Atom Stereocenter Count	4
Undefined Atom Stereocenter Count	0
Defined Bond Stereocenter Count	2
Undefined Bond Stereocenter Count	0
The total count of all stereochemical bonds	2
Covalently-Bonded Unit Count	4

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