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三羟甲基丙烷 三(3-巯基丙酸酯)

28篇引用文献 COA COA
    级别和纯度:
  • ≥85%(GC)
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货号 (SKU) 包装规格 是否现货 价格 数量
T162389-25g
 25g 现货 Stock Image
T162389-100g
 100g 现货 Stock Image
T162389-500g
 500g 现货 Stock Image
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二硫醇单体 (13) 聚合物/高分子试剂 (683)
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基本描述

别名 1,1,1-三(3-巯基丙酰氧基甲基)丙烷
英文别名 trimethylolpropanetris(3-mercaptopropionate) | Q27274969 | LY-364947;4-[3-(2-Pyridinyl)-1H-pyrazol-4-yl]-quinoline;[3-(Pyridin-2-yl)-4-(4-quinonyl)]-1H-pyrazole | 1,1,1-Tris(3-mercaptopropionyloxymethyl)propane | DTXCID6024919 | PROPANOIC ACID, 3-MERCAPTO
规格或纯度 ≥85%(GC)
英文名称 Trimethylolpropane Tris(3-mercaptopropionate)
应用 三羟甲基丙烷三（3-巯基丙酸酯）可用于以下研究： · 通过交联菊粉衍生物制备水凝胶。 · 多孔杂化整体材料的构建。 · 作为通过光引发聚合制备新型硫醇烯基聚合物荧光传感器的单体
运输条件 常规运输
产品介绍

据研究报道，三羟甲基丙烷三（3-巯基丙酸酯）是一种多硫醇交联剂三羟甲基丙烷三（3-巯基丙酸酯）可用于以下研究： · 通过交联菊粉衍生物制备水凝胶。 · 多孔杂化整体材料的构建。 · 作为通过光引发聚合制备新型硫醇烯基聚合物荧光传感器的单体

Trimethylolpropane tris(3-mercaptopropionate) is reported as a multi-thiol crosslinking reagent.
Uaually used in the following studies:Preparation of hydrogels, via crosslinking inulin derivatives,Construction of porous hybrid monolithic materials,As monomer for the preparation of a new thiol-ene based polymeric fluorescence sensor, via photo initiated polymerization.
纯度 ≥85%(GC)

名称和识别符

PubChem SID 488187571
分子类型 小分子
IIUPAC Name 2,2-bis(3-sulfanylpropanoyloxymethyl)butyl 3-sulfanylpropanoate
INCHI 1S/C15H26O6S3/c1-2-15(9-19-12(16)3-6-22,10-20-13(17)4-7-23)11-21-14(18)5-8-24/h22-24H,2-11H2,1H3
InChi Key IMQFZQVZKBIPCQ-UHFFFAOYSA-N
Smiles CCC(COC(=O)CCS)(COC(=O)CCS)COC(=O)CCS
Isomeric SMILES CCC(COC(=O)CCS)(COC(=O)CCS)COC(=O)CCS
PubChem CID 118379
分子量 398.55

化学和物理性质

密度 1.21
折光率 n20/D 1.518
闪点(℃) 96 °C
沸点 220 °C/0.3 mmHg
分子量 398.600 g/mol
XLogP3 1.600
氢键供体数Hydrogen Bond Donor Count 3
氢键受体数Hydrogen Bond Acceptor Count 9
可旋转键计数Rotatable Bond Count 16
精确质量Exact Mass 398.089 Da
单同位素质量Monoisotopic Mass 398.089 Da
拓扑极表面积Topological Polar Surface Area 81.900 Ų
重原子数Heavy Atom Count 24
形式电荷Formal Charge 0
复杂度Complexity 348.000
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 1

安全和危险性（GHS）

象形图 GHS07
信号词 警告
危险声明

H315: 引起皮肤刺激

H319: 引起严重眼睛刺激

H335: 可能引起呼吸道刺激
预防措施声明

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P264: 处理后要彻底洗手。

P271: 仅在室外或通风良好的地方使用。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P321: 特殊处理（请参阅此标签上的...）。

P302+P352: 如皮肤沾染：用水充分清洗。

P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。

P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。

P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。

P405: 密闭存放

P403+P233: 存放在通风良好的地方。保持容器密闭。

P501: 将内容物/容器处理到。。。

P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。

P337+P317: 如果眼睛刺激持续：寻求医疗帮助。

P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。

P319: 如果你感到不适，请寻求医疗帮助。

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L2102677 分析证书 T162389
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C2304034 分析证书 T162389
C2304045 分析证书 T162389
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引用文献

1. Xiaochun Liu, Jianyu Wu, Jianxin Wu, Zhiyi Huang, Wei Shen, Xingshan Yin, Yingjuan Sun, Xiaofeng Lin, Wenjing Lin, Guobin Yi.  (2023)  Tough, self-healing, and recyclable cross-linked polyurethane elastomers via synergistic effect of dual dynamic covalent bonds.  JOURNAL OF APPLIED POLYMER SCIENCE,  141  (5): (e54876).  [10.1002/app.54876]
2. Hang Shen, Siyi Li, Huagui Zhang.  (2023)  Transparent and Thermally Stable Urushiol Films by Fast Thiol–ene Curing.  ACS Applied Polymer Materials,  5  (9): (7022–7034).  [10.1021/acsapm.3c01070]
3. Jiahao Du, Huan Wang, Zhiyi Huang, Xiaochun Liu, Xinshan Yin, Jianxin Wu, Wenjing Lin, Xiaofeng Lin, Guobin Yi.  (2023)  Construction and mechanism study of lignin-based polyurethane with high strength and high self-healing properties.  INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES,  248  (125925).  [PMID:37499717] [10.1016/j.ijbiomac.2023.125925]
4. Yixiang Chen, Xueli Fu, Yu Jiang, Wanqi Feng, Dan Yu, Wei Wang.  (2023)  Highly sensitive and durable MXene/SBS nanofiber-based multifunctional sensors via thiol-ene click chemistry.  CHEMICAL ENGINEERING JOURNAL,  467  (143408).  [10.1016/j.cej.2023.143408]
5. Jingyuan Hu, Haoyang Feng, Yangke Rong, Shuaipeng Wang, Dandan Jin, Qing Chen, Jinyue Dai, Xiaoqing Liu.  (2023)  Recyclable bio-based epoxy resins containing hybrid cross-linking networks.  POLYMERS FOR ADVANCED TECHNOLOGIES,  34  (5): (1599-1607).  [10.1002/pat.5994]
6. Jing Dou, Shuo Han, Saisai Lin, Zhifu Qi, Feipeng Huang, Xiangdong Feng, Zhikan Yao, Jing Wang, Lin Zhang.  (2023)  Tailoring the selectivity of quasi-PIMs nanofiltration membrane via molecular flexibility of acyl chloride monomers for desalination from dye effluents.  JOURNAL OF MEMBRANE SCIENCE,  671  (121382).  [10.1016/j.memsci.2023.121382]
7. Lei Shi, Wanhui Wang, Chunjuan Wang, Yang Zhou, Yuezhan Feng, Tiekun Jia, Fang Wang, Zhiyu Min, Ji Hu, Zhigang Xue.  (2023)  In situ formed cross-linked polymer networks as dual-functional layers for high-stable lithium metal batteries.  Journal of Energy Chemistry,  79  (253).  [10.1016/j.jechem.2022.12.007]
8. Zijun Gao, Yang You, Qin Chen, Michael North, Haibo Xie.  (2023)  Vanillin-derived α,ω-diene monomer for thermosets preparation via thiol–ene click polymerization.  GREEN CHEMISTRY,  25  (1): (172-182).  [10.1039/D2GC02901D]
9. Yun Hu, Jing Zhou, Yufeng Ma, Yu Bei, Feilong Hu, Zhimin Kou, Yonghong Zhou, Puyou Jia.  (2022)  Branched plasticizers derived from eugenol via green polymerization for low/non-migration and externally/internally plasticized polyvinyl chloride materials.  Arabian Journal of Chemistry,  15  (104331).  [10.1016/j.arabjc.2022.104331]
10. Wenwen Guo, Fuwei Liang, Shun Chen, Kejing Yu, Jie Sun, Zengyuan Pang, Bin Fei.  (2022)  Magnolol-derived thiol-ene photo-polymerized membranes with intrinsic anti-flammability and high transparency.  COMPOSITES PART B-ENGINEERING,  242  (110074).  [10.1016/j.compositesb.2022.110074]
11. Puyou Jia, Yuxuan Shi, Fei Song, Yu Bei, Caoxing Huang, Meng Zhang, Lihong Hu, Yonghong Zhou.  (2022)  Bio-based and degradable vitrimer-graphene/graphene oxide composites with self-healing ability stimulated by heat, electricity and microwave as temperature and fire warning sensors.  COMPOSITES SCIENCE AND TECHNOLOGY,  227  (109573).  [10.1016/j.compscitech.2022.109573]
12. Yinlei Lin, Xinyan Song, Chenjing Zhu, Jianhui Huang, Xiaoxu Bai, Haichen Zhang, Kun Wang, Huawen Hu, Guangji Li.  (2022)  Moisture-triggered self-healing of a polyurethane coating based on isocyanate–oxazolidine-loaded microcapsules synthesized via thiol-ene photopolymerization without CO2 release.  PROGRESS IN ORGANIC COATINGS,  163  (106687).  [10.1016/j.porgcoat.2021.106687]
13. Miaozhou Ji, Zhenggong Wang, Yuzhang Zhu, Linglong Shan, Yang Lu, Yuping Zhang, Yatao Zhang, Jian Jin.  (2022)  Thin-film composite nanofiltration membrane with unprecedented stability in strong acid for highly selective dye/NaCl separation.  JOURNAL OF MEMBRANE SCIENCE,  645  (120189).  [10.1016/j.memsci.2021.120189]
14. Ying Li, Chao Liu, Wenying Zhou, Zhenzhong Hou, Qin Shi, Changdan Gong, Yi Wu.  (2021)  Microscopic ordered structure compactness and intrinsic thermal conductivity improvement of dispersed liquid crystal films of flexible epoxy-thiol polymers.  Materials Today Communications,  29  (102792).  [10.1016/j.mtcomm.2021.102792]
15. Xue Ying, Li Chunmei, Liu Jin, Tan Jiaojun, Yin Hangyu, Yao Laifeng, Zhang Qiuyu.  (2021)  Microcapsule-type stabilizers with adjustable wettability and their application in Pickering emulsion.  JOURNAL OF MATERIALS SCIENCE,  56  (31): (17527-17541).  [10.1007/s10853-021-06367-2]
16. Zhongqun Zhou, Yanning Zeng, Caili Yu, Quanyang Li, Faai Zhang.  (2021)  Intrinsically self-healing and stretchy poly(urethane-urea) elastomer based on dynamic urea bonds and thiol-ene click reaction.  MATERIALS CHEMISTRY AND PHYSICS,  267  (124642).  [10.1016/j.matchemphys.2021.124642]
17. Huang Dijun, Ren Yongxia, Yang Ruoning, He Zhiguo, Yao Youwei.  (2021)  Preparation and characterization of a novel ultraviolet/thermal dual-curing thiol-ene/polyurethane acrylate coating.  Journal of Coatings Technology and Research,  18  (4): (1109-1116).  [10.1007/s11998-021-00464-2]
18. Yuqi Liu, Mingyue Wei, Xingyu Jiang, Mingwei Ren, Lianying Liu, Bianying Wen, Wantai Yang.  (2020)  Anomalously Shaped Functional Particles Prepared by Thiol-Isocyanate Off-Stoichiometric Click Dispersion Polymerization.  LANGMUIR,  36  (47): (14417–14424).  [PMID:33198464] [10.1021/acs.langmuir.0c02798]
19. Ying Xue, Chunmei Li, Jin Liu, Jiaojun Tan, Zhengzhou Su, Yumin Yang, Guoxian Zhang, Qiuyu Zhang.  (2020)  Fabrication and characterization of hierarchical microcapsules with multi-storage cells for repeatable self-healing.  COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS,  603  (125201).  [10.1016/j.colsurfa.2020.125201]
20. Liu Pin, Qi Chenze, Gao Yong.  (2019)  CTAB-assisted fabrication of well-shaped PDA-based colloidosomes.  COLLOID AND POLYMER SCIENCE,  297  (10): (1301-1311).  [10.1007/s00396-019-04547-w]
21. Cheng Chuanjie, Zhang Xu, Chen Xinghe, Li Jin, Huang Qinghua, Hu Zhongyu, Tu Yuanming.  (2016)  Self-healing polymers based on eugenol via combination of thiol-ene and thiol oxidation reactions.  JOURNAL OF POLYMER RESEARCH,  23  (6): (1-12).  [10.1007/s10965-016-1001-x]
22. Chunmei Li, Jiaojun Tan, Junwei Gu, Lei Qiao, Baoliang Zhang, Qiuyu Zhang.  (2016)  Rapid and efficient synthesis of isocyanate microcapsules via thiol-ene photopolymerization in Pickering emulsion and its application in self-healing coating.  COMPOSITES SCIENCE AND TECHNOLOGY,  123  (250).  [10.1016/j.compscitech.2016.01.001]
23. Beitao Liu, Jiahui Li, Cijian Zhang, Yibo Wang, Xigao Jian, Zhihuan Weng.  (2024)  “Polymer to polymer” recycling and body-temperature triggered shape memory of a carvone-based epoxy thermoset system achieved using a thiol-Michael covalent adaptable network.  Journal of Materials Chemistry A,  [10.1039/D4TA03378G]
24. Fengying Yi, Zeyu Li, Qingzhong Guo, Faliang Luo, Jiangyu Wu, Pu Hu, Zhihong Liu.  (2025)  In situ preparation of nonflammable phosphorus-containing gel polymer electrolyte for lithium metal battery with enhanced interfacial stability and safety.  CHEMICAL ENGINEERING JOURNAL,  506  (160011).  [10.1016/j.cej.2025.160011]
25. Yanyun Li, Tiancheng Wang, Junying Zhang, Jue Cheng, Qingsong Lian.  (2025)  Multi-mode triggered bio-based epoxy resin/lauric acid/graphene paper flexible phase change materials with high enthalpy value, multi-functionality, and personal thermal management ability.  COMPOSITES PART A-APPLIED SCIENCE AND MANUFACTURING,  (108849).  [10.1016/j.compositesa.2025.108849]
26. Ge Zhao, Kangning Wu, Zhuolin Zhang, Dongxu An, Xu Zhang, Li Ran, Fusheng Zhou, Jianying Li.  (2024)  Novel recyclable epoxy resin with releasable residual stress and synergistically enhanced dielectric properties and healing ability.  POLYMER,  311  (127569).  [10.1016/j.polymer.2024.127569]
27. Yu Li, Hao-Xin Niu, Ze-Tao Xiao, Tian-Mo Yang, Hao-Ran Jiang, Wei Wang, Yuan Hu, Xin Wang.  (2025)  Sustainably sourced covalent adaptable networks derived from eugenol for flame retardant, transparent and self-healing coating applications.  PROGRESS IN ORGANIC COATINGS,  200  (109072).  [10.1016/j.porgcoat.2025.109072]
28. Haihui Liu, Guoting Li, Jingguang Zhang, Ziheng Sang, Ze Chen, Qiang Xu, Shuai Wang, Xingxiang Zhang.  (2024)  Synthesis and properties of temperature-responsive shape memory polyurethane with secondary crosslinked network structure based on LPO.  POLYMER,  311  (127559).  [10.1016/j.polymer.2024.127559]

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