| 货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
|---|---|---|---|---|
| T106149-500ml |
500ml |
现货  |
|
| 英文别名 | trimethoxyphosphane | TRIMETHYL PHOSPHITE | HSDB 1007 | Methyl phosphite | EC 204-471-5 | Trimethylphosphit | AKOS000121918 | WLN: 1OPO1 & O1 | CHEBI:183313 | Methyl phosphite ((MeO)3P) | Trimethyl ester of phosphorous acid | Fosforyn trojmetylowy [Czech] |
|---|---|
| 规格或纯度 | 化学纯（CP）, ≥95% |
| 英文名称 | Trimethyl phosphite |
| 储存温度 | 室温 |
| 运输条件 | 常规运输 |
| 纯度 | ≥95% |
| 密度 | 1.052 |
|---|---|
| 折光率 | 1.4095 |
| 闪点(℉) | 82.4 °F |
| 闪点(℃) | 28℃ |
| 沸点 | 112°C |
| 熔点 | -78°C |
| 分子量 | 124.080 g/mol |
| XLogP3 | 0.100 |
| 氢键供体数Hydrogen Bond Donor Count | 0 |
| 氢键受体数Hydrogen Bond Acceptor Count | 3 |
| 可旋转键计数Rotatable Bond Count | 3 |
| 精确质量Exact Mass | 124.029 Da |
| 单同位素质量Monoisotopic Mass | 124.029 Da |
| 拓扑极表面积Topological Polar Surface Area | 27.700 Ų |
| 重原子数Heavy Atom Count | 7 |
| 形式电荷Formal Charge | 0 |
| 复杂度Complexity | 31.700 |
| 同位素原子数Isotope Atom Count | 0 |
| 定义的原子立体中心计数Defined Atom Stereocenter Count | 0 |
| 未定义的原子立体中心计数Undefined Atom Stereocenter Count | 0 |
| 定义的键立体中心计数Defined Bond Stereocenter Count | 0 |
| 未定义的键立体中心计数Undefined Bond Stereocenter Count | 0 |
| 所有立体化学键的总数The total count of all stereochemical bonds | 0 |
| 共价键合单元计数Covalently-Bonded Unit Count | 1 |
| 一般危化品 | 一般危化品 |
|---|---|
| 象形图 | GHS02, GHS07, GHS08 |
| 信号词 | 警告 |
| 危险声明 |
H226: 易燃液体和蒸气 H302: 吞食有害 H313: 接触皮肤可能有害 H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H335: 可能引起呼吸道刺激 H373: 通过长时间或反复暴露对器官造成损害 |
| 预防措施声明 |
P201: 使用前获取特殊说明 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P233: 保持容器密闭。 P240: 地面/粘结容器和接收设备 P241: 使用防爆的[电气/通风/照明/.../]设备。 P242: 仅使用无火花的工具。 P243: 采取防静电措施 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P264: 处理后要彻底洗手。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P271: 仅在室外或通风良好的地方使用。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P312: 打电话给毒物中心或医生。。。如果你觉得不舒服 P330: 漱口 P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P332+P313: 如发生皮肤刺激：求医/就诊。 P337+P313: 如仍觉眼刺激：求医/就诊。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P403+P233: 存放在通风良好的地方。保持容器密闭。 P403+P235: 存放在通风良好的地方。保持低温。 P501: 将内容物/容器处理到。。。 P301+P312+P330: 如误吞咽：如感觉不适，呼叫急救中心/医生。漱口 P301+P317: 如果被吞咽：请寻求医疗帮助。 P319: 如果你感到不适，请寻求医疗帮助。 |
| WGK Germany | 1 |
| RTECS | TH1400000 |
| Class | 3 |
| 个人防护装备 | Eyeshields， Faceshields， full-face respirator (US)， Gloves， multi-purpose combination respirator cartridge (US)， type ABEK (EN14387) respirator filter |
| 1. M A Mehlman,P H Craig,M A Gallo. (1984-01-01) Teratological evaluation of trimethyl phosphite in the rat.. Toxicology and applied pharmacology, 72 ((1)): (119-123). [PMID:6710478] |
| 2. Bangwei Ding,Wesley G Bentrude. (2003-03-13) Trimethyl phosphite as a trap for alkoxy radicals formed from the ring opening of oxiranylcarbinyl radicals. Conversion to alkenes. Mechanistic applications to the study of C-C versus C-O ring cleavage.. Journal of the American Chemical Society, 125 ((11)): (3248-3259). [PMID:12630880] |
| 3. Tian-lin Zhang,Zai-feng Li,Zhen Jia,Jun-hong Wang. (2005-03-15) [Studies on the reactions of unsaturated chloride polyether polyol with trimethyl phosphite by FTIR].. Guang pu xue yu guang pu fen xi = Guang pu, 24 ((11)): (1334-1337). [PMID:15762469] |
| 4. D Vaughan Griffiths,Mohamad J Al-Jeboori,Yuen-Ki Cheong,Philip Duncanson,Jayne E Harris,Michael C Salt,Helen V Taylor. (2008-01-26) Electron-rich heteroaroylphosphonates and their reaction with trimethyl phosphite.. Organic & biomolecular chemistry, 6 ((3)): (577-585). [PMID:18219430] |
| 5. Arjen VanDoorn,Mario Kallenbach,Alejandro A Borquez,Ian T Baldwin,Gustavo Bonaventure. (2010-08-11) Rapid modification of the insect elicitor N-linolenoyl-glutamate via a lipoxygenase-mediated mechanism on Nicotiana attenuata leaves.. BMC plant biology, 10 (164-164). [PMID:20696061] |
| 6. Shinichi Yamabe,Noriko Tsuchida,Shoko Yamazaki. (2010-10-15) Correlation between the rate order and the number of molecules in the reaction of trimethyl phosphite with water in acetonitrile solvent.. The journal of physical chemistry. A, 114 ((43)): (11699-11707). [PMID:20942499] |
| 7. N Ramanathan,Bishnu Prasad Kar,K Sundararajan,K S Viswanathan. (2012-11-21) Matrix isolation infrared and DFT study of the trimethyl phosphite-hydrogen chloride interaction: hydrogen bonding versus nucleophilic substitution.. The journal of physical chemistry. A, 116 ((49)): (12014-12023). [PMID:23163609] |
| 8. D H Barton,C O Bardin,D Doller. (1994-04-01) The functionalisation of saturated hydrocarbons--XXX. Model studies on the mechanism of some oxygenases.. Bioorganic & medicinal chemistry, 2 ((4)): (259-266). [PMID:7922137] |
| 9. J C Lin,Y F Chen,C Y Chen. (1999-08-24) Surface characterization and platelet adhesion studies of plasma polymerized phosphite and its copolymers with dimethylsulfate.. Biomaterials, 20 ((16)): (1439-1447). [PMID:10458557] |
| 10. Ruilian Chen, Dengchong Feng, Guojian Chen, Xudong Chen, Wei Hong. (2021) Re-Printable Chiral Photonic Paper with Invisible Patterns and Tunable Wettability. ADVANCED FUNCTIONAL MATERIALS, 31 (16): (2009916). [10.1002/adfm.202009916] |
| 11. Wenwen Guo, Yuyu Zhao, Xin Wang, Wei Cai, Junling Wang, Lei Song, Yuan Hu. (2020) Multifunctional epoxy composites with highly flame retardant and effective electromagnetic interference shielding performances. COMPOSITES PART B-ENGINEERING, 192 (107990). [10.1016/j.compositesb.2020.107990] |
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