基本描述

英文别名	Samarium powder (99.9% REO) 325 mesh \| Samarium foil, 0.62mm (0.024in) thick \| Samarium, foil, not light tested, 50x50mm, thickness 0.025mm, as rolled, 99% \| KZUNJOHGWZRPMI-UHFFFAOYSA-N \| Samarium - Sm @ 1000 microg/mL in 5% HNO3 \| CHEBI:33374 \| Samarium
规格或纯度	≥99% trace rare earth metals basis, −10 mesh
英文名称	Samarium
产品介绍	应用通过联合使用氯化钐和氯化钛(IV) 还原芳基磺酰氯和芳基亚磺酸盐，制备二芳基二硫化物。 Application Arylsulfonyl chlorides and arylsulfinates are reduced by a combination of samarium and titanium(IV) chloride to make diaryl disulfides.
纯度	≥99% trace rare earth metals basis

名称和识别符

EC号	231-128-7
IIUPAC Name	samarium
INCHI	1S/Sm
InChi Key	KZUNJOHGWZRPMI-UHFFFAOYSA-N
Smiles	[Sm]
Isomeric SMILES	[Sm]
PubChem CID	23951
UN Number	3132
Packing Group	III
分子量	150.36

化学和物理性质

密度	7.47g/mLat 25°C (lit.)
沸点	1778°C
熔点	1072°C
分子量	150.400 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	0
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	151.92 Da
单同位素质量Monoisotopic Mass	151.92 Da
拓扑极表面积Topological Polar Surface Area	0.000 Å²
重原子数Heavy Atom Count	1
形式电荷Formal Charge	0
复杂度Complexity	0.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

象形图	GHS02
信号词	警告
危险声明	H228: 易燃固体 H261: 与水接触释放出易燃气体
预防措施声明	P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P240: 地面/粘结容器和接收设备 P241: 使用防爆的[电气/通风/照明/.../]设备。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P231+P232: 在惰性气体中操作。防潮。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P402+P404: 存放于干燥处。存放于密闭的容器中。 P501: 将内容物/容器处理到。。。
WGK Germany	3
Class	4.3

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此产品的引用文献

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引用文献

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2. A N Serafini. (2000-07-18) Samarium Sm-153 lexidronam for the palliation of bone pain associated with metastases.. Cancer, 88 ((12 Suppl)): (2934-2939). [PMID:10898337]
3. A N Serafini. (2001-07-18) Systemic metabolic radiotherapy with samarium-153 EDTMP for the treatment of painful bone metastasis.. The quarterly journal of nuclear medicine : official publication of the Italian Association of Nuclear Medicine (AIMN) [and] the International Association of Radiopharmacology (IAR), 45 ((1)): (91-99). [PMID:11456381]
4. Masakazu Sono. (2003-08-23) [6-endo-trig mode cyclization to a hydrindanone using samarium (II) iodide].. Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 123 ((8)): (653-663). [PMID:12931661]
5. David J Edmonds,Derek Johnston,David J Procter. (2004-07-15) Samarium(II)-iodide-mediated cyclizations in natural product synthesis.. Chemical reviews, 104 ((7)): (3371-3404). [PMID:15250745]
6. Jose M Concellón,Humberto Rodríguez-Solla. (2004-12-14) Beta-elimination reactions by using samarium diiodide.. Chemical Society reviews, 33 ((9)): (599-609). [PMID:15592625]
7. Pete Anderson. (2006-07-25) Samarium for osteoblastic bone metastases and osteosarcoma.. Expert opinion on pharmacotherapy, 7 ((11)): (1475-1486). [PMID:16859431]
8. Pete Anderson,Rodolfo Nuñez. (2007-11-21) Samarium lexidronam (153Sm-EDTMP): skeletal radiation for osteoblastic bone metastases and osteosarcoma.. Expert review of anticancer therapy, 7 ((11)): (1517-1527). [PMID:18020921]
9. K C Nicolaou,Shelby P Ellery,Jason S Chen. (2009-08-29) Samarium diiodide mediated reactions in total synthesis.. Angewandte Chemie (International ed. in English), 48 ((39)): (7140-7165). [PMID:19714695]
10. José M Concellón,Humberto Rodríguez-Solla,Carmen Concellón,Vicente del Amo. (2010-08-05) Stereospecific and highly stereoselective cyclopropanation reactions promoted by samarium.. Chemical Society reviews, 39 ((11)): (4103-4113). [PMID:20683534]
11. Christine Beemelmanns,Hans-Ulrich Reissig. (2011-01-19) Samarium diiodide induced ketyl-(het)arene cyclisations towards novel N-heterocycles.. Chemical Society reviews, 40 ((5)): (2199-2210). [PMID:21243132]
12. Michal Szostak,Malcolm Spain,Dixit Parmar,David J Procter. (2011-09-01) Selective reductive transformations using samarium diiodide-water.. Chemical communications (Cambridge, England), 48 ((3)): (330-346). [PMID:21879049]
13. Brice Sautier,David J Procter. (2012-08-09) Recent advances in the chemistry of SmI(2)-H(2)O.. Chimia, 66 ((6)): (399-403). [PMID:22871283]
14. Weiwei Huan,Chao Cheng,Yuxiang Yang,Hongming Yuan,Yongxia Li. (2012-08-22) A study on the magnetic and photoluminescence properties of Eu(n+) and Sm3+ doped Fe3O4 nanoparticles.. Journal of nanoscience and nanotechnology, 12 ((6)): (4621-4634). [PMID:22905509]
15. Kristina Simon,Johannes Wefer,Elisabeth Schöttner,Thomas Lindel. (2012-09-27) Enantioselective total synthesis of the diterpene (+)-cubitene.. Angewandte Chemie (International ed. in English), 51 ((43)): (10889-10892). [PMID:23011985]
16. Ana M Gutiérrez,José J Cerón,Blas A Marsilla,María D Parra,Silvia Martinez-Subiela. (2012-10-02) Dual-label time-resolved fluoroimmunoassay for simultaneous quantification of haptoglobin and C-reactive protein in meat juice from pigs.. Canadian journal of veterinary research = Revue canadienne de recherche veterinaire, 76 ((2)): (136-142). [PMID:23024456]
17. Chintada Nageswara Rao,Shmaryahu Hoz. (2012-10-03) Synergism and inhibition in the combination of visible light and HMPA in SmI2 reductions.. The Journal of organic chemistry, 77 ((20)): (9199-9204). [PMID:23025345]
18. Wei Xu,Ben Niu,Lai Feng,Zujin Shi,Yongfu Lian. (2012-10-04) Access to an unexplored chiral C82 \u2005cage by encaging a divalent metal: structural elucidation and electrochemical studies of Sm@C2(5)-C82.. Chemistry (Weinheim an der Bergstrasse, Germany), 18 ((45)): (14246-14249). [PMID:23033122]
19. Alicia K Morgans,Matthew R Smith. (2012-10-23) Bone-targeted agents: preventing skeletal complications in prostate cancer.. The Urologic clinics of North America, 39 ((4)): (533-546). [PMID:23084529]
20. I Pal,A Agarwal,S Sanghi,M P Aggarwal. (2012-10-27) Investigation of spectroscopic properties, structure and luminescence spectra of Sm3+ doped zinc bismuth silicate glasses.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 101 (74-81). [PMID:23099163]
21. M Saif,H Hafez,A I Nabeel. (2012-11-06) Photo-induced self-cleaning and sterilizing activity of Sm3+ doped ZnO nanomaterials.. Chemosphere, 90 ((2)): (840-847). [PMID:23123120]
22. M Majumder,K Ghoshray,C Mazumdar,A Poddar,A Ghoshray,D Berardan,N Dragoe. (2012-12-05) Evidence of a structural phase transition in superconducting SmFeAsO(1-x)F(x) from 19F NMR.. Journal of physics. Condensed matter : an Institute of Physics journal, 25 ((2)): (025701-025701). [PMID:23207111]
23. Benjamin Voß,Jörg Nordmann,Andreas Uhl,Rajesh Komban,Markus Haase. (2012-12-14) Effect of the crystal structure of small precursor particles on the growth of β-NaREF4 (RE = Sm, Eu, Gd, Tb) nanocrystals.. Nanoscale, 5 ((2)): (806-812). [PMID:23235555]
24. C Guzmán-Afonso,C González-Silgo,M E Torres,E Matesanz,A Mujica. (2012-12-15) Structural anomalies related to changes in the conduction mechanisms of α-Sm2(MoO4)3.. Journal of physics. Condensed matter : an Institute of Physics journal, 25 ((3)): (035902-035902). [PMID:23238241]
25. Sd Zulfiqar Ali Ahamed,C Madhukar Reddy,B Deva Prasad Raju. (2012-12-25) Spectroscopic and laser properties of Sm³⁺ ions doped lithium fluoroborate glasses for efficient visible lasers.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 103 (246-254). [PMID:23261619]
26. T Sasikala,L Rama Moorthy,A Mohan Babu. (2013-01-01) Optical and luminescent properties of Sm³+ doped tellurite glasses.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 104 (445-450). [PMID:23274475]
27. Hua Yang,Zhimin Wang,Hongxiao Jin,Bo Hong,Ziyang Liu,Christine M Beavers,Marilyn M Olmstead,Alan L Balch. (2013-01-25) Isolation and crystallographic characterization of Sm@C2v(3)-C80 through cocrystal formation with Ni(II)(octaethylporphyrin) or bis(ethylenedithio)tetrathiafulvalene.. Inorganic chemistry, 52 ((3)): (1275-1284). [PMID:23343255]
28. Mario Janjetovic,Annika M Träff,Tobias Ankner,Jenny Wettergren,Göran Hilmersson. (2013-01-30) Solvent dependent reductive defluorination of aliphatic C-F bonds employing Sm(HMDS)2.. Chemical communications (Cambridge, England), 49 ((18)): (1826-1828). [PMID:23358653]
29. M Baczyk,P Milecki,M Pisarek,P Gut,A Antczak,M Hrab. (2013-02-05) A prospective randomized trial: a comparison of the analgesic effect and toxicity of 153Sm radioisotope treatment in monotherapy and combined therapy including local external beam radiotherapy (EBRT) among metastatic castrate resistance prostate cancer (mCRPC) patients with painful bone metastases.. Neoplasma, 60 ((3)): (328-333). [PMID:23374004]
30. Yi Lu,Xijia Gu. (2013-02-08) All-fiber passively Q-switched fiber laser with a Sm-doped fiber saturable absorber.. Optics express, 21 ((2)): (1997-2002). [PMID:23389180]
31. Fu Yang,Zhiping Yang,Quanmao Yu,Yufeng Liu,Xu Li,Fachun Lu. (2013-02-09) Sm(3+)-doped Ba3Bi(PO4)3 orange reddish emitting phosphor.. Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 105 (626-631). [PMID:23391850]
32. Dhandapani V Sadasivam,Kimberly A Choquette,Robert A Flowers. (2013-02-15) Preparation and use of samarium diiodide (SmI(2)) in organic synthesis: the mechanistic role of HMPA and Ni(II) salts in the samarium Barbier reaction.. Journal of visualized experiments : JoVE, ((72)(72)): (e4323-e4323). [PMID:23407417]
33. D Mogilyansky,I Fita,A Wisniewski,V Markovich,R Puzniak,G Gorodetsky. (2013-02-21) Anomalous magnetic behavior of Sm0.8Ca0.2MnO3 nanoparticles.. Journal of nanoscience and nanotechnology, 12 ((11)): (8613-8618). [PMID:23421252]
34. Yongchao Jia,Wei Lü,Ning Guo,Wenzhen Lü,Qi Zhao,Hongpeng You. (2013-02-26) Utilizing Tb3+ as an energy transfer bridge to connect Eu(2+)-Sm3+ luminescent centers: realization of efficient Sm3+ red emission under near-UV excitation.. Chemical communications (Cambridge, England), 49 ((26)): (2664-2666). [PMID:23435681]
35. Tianye Cao,Yang Yang,Yun Sun,Yongquan Wu,Yuan Gao,Wei Feng,Fuyou Li. (2013-06-26) Biodistribution of sub-10 nm PEG-modified radioactive/upconversion nanoparticles.. Biomaterials, 34 ((29)): (7127-7134). [PMID:23796579]
36. Gregory A Brennecka,Lars E Borg,Meenakshi Wadhwa. (2013-10-09) Evidence for supernova injection into the solar nebula and the decoupling of r-process nucleosynthesis.. Proceedings of the National Academy of Sciences of the United States of America, 110 ((43)): (17241-17246). [PMID:24101483]
37. Michal Szostak,Malcolm Spain,David J Procter. (2014-09-24) Selective synthesis of α,α-dideuterio alcohols by the reduction of carboxylic acids using SmI2 and D2O as deuterium source under SET conditions.. Organic letters, 16 ((19)): (5052-5055). [PMID:25247236]
38. Hiroshi Suizu,Daisuke Shigeoka,Hiroshi Aoyama,Takehiko Yoshimitsu. (2014-12-17) Total synthesis of clavilactone B: a radical cyclization-fragmentation strategy.. Organic letters, 17 ((1)): (126-129). [PMID:25513832]
39. Xiaohong Xiong,Tao Jiang,Wenhao Qi,Jun Zuo,Meiling Yang,Qiang Fei,Saijin Xiao,Aimin Yu,Zhiqiang Zhu,Huanwen Chen. (2015-10-01) Some Rare Earth Elements Analysis by Microwave Plasma Torch Coupled with the Linear Ion Trap Mass Spectrometry.. International journal of analytical chemistry, 2015 (156509-156509). [PMID:26421013]
40. Carmen Cavallo,Alberto Salleo,Daniele Gozzi,Francesco Di Pascasio,Simone Quaranta,Riccardo Panetta,Alessandro Latini. (2015-11-19) Solid Solutions of Rare Earth Cations in Mesoporous Anatase Beads and Their Performances in Dye-Sensitized Solar Cells.. Scientific reports, 5 (16785-16785). [PMID:26577287]
41. Y Kamochi,T Kudo. (2000-03-21) [Rapid reduction of a variety of organic functionalities including a new selective reduction with samarium diiodide].. Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 120 ((3)): (245-255). [PMID:10723266]
42. Masakazu Sono,Natsuko Ise,Tsutomu Shoji,Motoo Tori. (2012-09-15) Cyclizations producing hydrindanones with two methyl groups at the juncture positions mediated by samarium diiodide and electrolysis.. Molecules (Basel, Switzerland), 17 ((9)): (11079-11088). [PMID:22976471]
43. Yang Yang,Yun Sun,Tianye Cao,Juanjuan Peng,Ying Liu,Yongquan Wu,Wei Feng,Yingjian Zhang,Fuyou Li. (2012-11-03) Hydrothermal synthesis of NaLuF4:153Sm,Yb,Tm nanoparticles and their application in dual-modality upconversion luminescence and SPECT bioimaging.. Biomaterials, 34 ((3)): (774-783). [PMID:23117216]
44. Hong Zhang, Qian Du, Xin Du, Zhanglian Xu, Shaoqiang Guo, Wentao Zhou. (2023) Selective extraction of Sm from LiCl-KCl molten salt into wasteforms via liquid bismuth. SEPARATION AND PURIFICATION TECHNOLOGY, 313 (123441). [10.1016/j.seppur.2023.123441]
45. Huijun Liao, Zizhen Zhou, Sikang Zheng, Yuling Huang, Guang Han, Guoyu Wang, Zhengyong Huang, Xu Lu, Jian Li, Xiaoyuan Zhou. (2023) High-Temperature Thermoelectricity in Narrow-Gap Semiconductor SmS with Strong Electron-Hole Asymmetry. Advanced Energy Materials, 13 (12): (2203519). [10.1002/aenm.202203519]
46. Tingting Wang, Yonggui Song, Huanhua Xu, Yali Liu, Hongwei He, Mingyue Zhou, Chen Jin, Ming Yang, Zhifu Ai, Dan Su. (2022) Study on the mechanism of reducing biofilm toxicity and increasing antioxidant activity in vinegar processing phytomedicines containing pentacyclic triterpenoid saponins. JOURNAL OF ETHNOPHARMACOLOGY, 290 (115112). [PMID:35181486] [10.1016/j.jep.2022.115112]

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货号 (SKU)	包装规格	是否现货
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化学和物理性质

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溶液计算器

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