基本描述

别名	2,4-戊二酮铑(III) 衍生物
英文别名	(E)-4-hydroxypent-3-en-2-one;rhodium \| Rhodium acetylacetonate \| MFCD00083144 \| Rhodium(III) 2,4-pentanedionate, Premion(R) \| AKOS025311441 \| Rh(acac)3 \| 2,4-Pentanedione rhodium(III) derivative
规格或纯度	PrimorTrace™, ≥99.99% metals basis
英文名称	Rhodium(III) acetylacetonate
运输条件	常规运输
产品介绍	Rhodium(III) acetylacetonate is a yellowcrystalline compound composed of rhodium atoms coordinated with three acetylacetonate ligands. It iswidely used in the field of catalysis, organic electronics and to prepare Rhcomplexes. It is soluble inorganic solvents. Application： Rhodium(III) acetylacetonate can be used: As a precursor to synthesize Rh nanocrystals with catalytic activities；As an efficient catalyst for the α-alkylation of ketones, β-alkylation of secondary alcohols, and the alkylation of amines with primary alcohols；To prepare highly phosphorescent complexes for organic light-emitting devices；To synthesize the Rh2P NCs supported on carbon (Rh2P/C) by a one-step solvothermal method via a direct reaction between Rh(acac)3 and tri-n-octylphosphine (TOP). The resultant electrocatalyst exhibited remarkable performance for both the hydrogen evolution reaction and the oxygen evolution reaction, surpassing the capabilities of Rh/C and Pt/C catalysts for water splitting；To prepare Single-atom Rh/N-doped carbon electrocatalyst for the oxidation of formic acid；To synthesize Pt–Rh NWs as highly efficient electrocatalysts toward ethanol oxidation reaction (EOR) for Direct ethanol fuel cells. The electrocatalyst demonstrated improved catalytic activities, primarily attributed to the presence of Rh, which enhances its ability to resist poisoning.
纯度	≥99.99% metals basis

名称和识别符

PubChem SID	504772020
EC号	238-192-5
IIUPAC Name	(E)-4-hydroxypent-3-en-2-one;rhodium
INCHI	1S/3C5H8O2.Rh/c31-4(6)3-5(2)7;/h33,6H,1-2H3;/b3*4-3+;
InChi Key	MBVAQOHBPXKYMF-MUCWUPSWSA-N
Smiles	CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Rh]
Isomeric SMILES	C/C(=C\C(=O)C)/O.C/C(=C\C(=O)C)/O.C/C(=C\C(=O)C)/O.[Rh]
PubChem CID	71306774
分子量	400.23

化学和物理性质

溶解性	Very soluble in chloroform. Soluble in alcohol. In soluble in water.
密度	0.852
熔点	263-264°C

安全和危险性（GHS）

象形图	GHS07, GHS08
信号词	警告
危险声明	H302: 吞食有害 H312: 皮肤接触有害 H315: 引起皮肤刺激 H319: 引起严重眼睛刺激 H332: 吸入有害 H335: 可能引起呼吸道刺激 H361: 怀疑破坏生育力或未出生的孩子
预防措施声明	P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P264: 处理后要彻底洗手。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P271: 仅在室外或通风良好的地方使用。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理（请参阅此标签上的...）。 P330: 漱口 P302+P352: 如皮肤沾染：用水充分清洗。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。 P405: 密闭存放 P403+P233: 存放在通风良好的地方。保持容器密闭。 P501: 将内容物/容器处理到。。。 P203: 使用前，获取、阅读并遵守所有安全说明。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P301+P317: 如果被吞咽：请寻求医疗帮助。 P318: 如果暴露或担心，请就医。 P317: 寻求紧急医疗救助。 P337+P317: 如果眼睛刺激持续：寻求医疗帮助。 P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。 P319: 如果你感到不适，请寻求医疗帮助。
WGK Germany	3
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

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批号(Lot Number)	证书类型	货号
I2517649	分析证书	R118540
H2529113	分析证书	R118540
C2510351	分析证书	R118540
C2510352	分析证书	R118540
F2513054	分析证书	R118540
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A2403377	分析证书	R118540
A2403378	分析证书	R118540
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引用文献

1. Ce Han, Bingbao Mei, Qinghua Zhang, Huimin Zhang, Pengfei Yao, Ping Song, Xue Gong, Peixin Cui, Zheng Jiang, Lin Gu, Weilin Xu. (2023) Atomic Ru coordinated by channel ammonia in V-doped tungsten bronze for highly efficient hydrogen-evolution reaction. CHINESE JOURNAL OF CATALYSIS, 51 (80). [10.1016/S1872-2067(23)64489-4]
2. Ziqiang Wang, Guanghui Yang, Pengjun Tian, Xinmiao Li, Kai Deng, Hongjie Yu, You Xu, Hongjing Wang, Liang Wang. (2023) Hydrophilic functionalization of rhodium metallene for saving-energy hydrogen production and sulfur recovery. CHEMICAL ENGINEERING JOURNAL, 473 (145147). [10.1016/j.cej.2023.145147]
3. Xiaolan Li, Yangqi Huang, Zhenyu Chen, Shuqi Hu, Jinliang Zhu, Panagiotis Tsiakaras, Pei Kang Shen. (2023) Novel PtNi nanoflowers regulated by a third element (Rh, Ru, Pd) as efficient multifunctional electrocatalysts for ORR, MOR and HER. CHEMICAL ENGINEERING JOURNAL, 454 (140131). [10.1016/j.cej.2022.140131]
4. Fan Yang, Hongbo Yu, Chunzheng Wu, Shiwei Wang, Tong Li, Hongfeng Yin. (2022) RhCu Bimetallic Nanoparticles in Hollow Carbon Spheres for Catalytic Halonitrobenzene Chemoselective Hydrogenation. ACS Applied Nano Materials, 5 (8): (11627–11635). [10.1021/acsanm.2c02358]
5. Qiqi Mao, Kai Deng, Hongjie Yu, You Xu, Ziqiang Wang, Xiaonian Li, Liang Wang, Hongjing Wang. (2022) In Situ Reconstruction of Partially Hydroxylated Porous Rh Metallene for Ethylene Glycol-Assisted Seawater Splitting. ADVANCED FUNCTIONAL MATERIALS, 32 (31): (2201081). [10.1002/adfm.202201081]
6. Yuting Chu, Bo Yan, Xia Yang, Shiwei Wang, Peng Cao, Tong Li, Hongbo Yu, Hongfeng Yin. (2021) Selective Oxidation of Methyl Lactate over Carbon-Supported Noble Metal Catalysts under Base-Free Conditions. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 60 (40): (14397–14409). [10.1021/acs.iecr.1c02410]
7. Menghan Wang, Zhen Wang, Shuqi Hu, Xinxin Zhu, Xu Lin, Xinyi Zhang, Pei Kang Shen. (2021) A facile strategy synthesized PtRhNi truncated triangle nanoflakes with PtRh-rich surface as highly active and stable bifunctional catalysts for direct methanol fuel cells. JOURNAL OF COLLOID AND INTERFACE SCIENCE, 604 (894). [PMID:34311264] [10.1016/j.jcis.2021.07.009]
8. Biao Sun, Long Huang, Shan Su, Sai Luo, Chunfeng Meng, Hafiz Muhammad Abdul Basit, Jiankun Xiao, Ting Bian, Shichuan Su. (2020) PtRhCu ternary alloy nanodendrites with enhanced catalytic activity and durability toward methanol electro-oxidation. MATERIALS CHEMISTRY AND PHYSICS, 252 (123234). [10.1016/j.matchemphys.2020.123234]
9. Tao Gan, Yifei Liu, Qian He, Hao Zhang, Xiaohui He, Hongbing Ji. (2020) Facile Synthesis of Kilogram-Scale Co-Alloyed Pt Single-Atom Catalysts via Ball Milling for Hydrodeoxygenation of 5-Hydroxymethylfurfural. ACS Sustainable Chemistry & Engineering, 8 (23): (8692–8699). [10.1021/acssuschemeng.0c02065]
10. Jinchang Fan, Xiaoqiang Cui, Shansheng Yu, Lin Gu, Qinghua Zhang, Fanqi Meng, Zhangquan Peng, Lipo Ma, Jing-Yuan Ma, Kun Qi, Qiaoliang Bao, Weitao Zheng. (2019) Interstitial Hydrogen Atom Modulation to Boost Hydrogen Evolution in Pd-Based Alloy Nanoparticles. ACS Nano, 13 (11): (12987–12995). [PMID:31618006] [10.1021/acsnano.9b05615]
11. Shuai Li, Zhe Chen, Xingchen Ling, Jingjiao Cao, Qian Wang, Yu Zhou, Jun Wang. (2019) Engineering polyoxometalate anions on porous ionic network towards highly catalytic active noble metal clusters. APPLIED SURFACE SCIENCE, 496 (143650). [10.1016/j.apsusc.2019.143650]
12. Zhounan Yu, Leilei Zhang, Yuanlong Tan, Rizheng Jing, Hongchen Cao, Caiyi Lou, Rile Ge, Junhu Wang, Aiqin Wang, Tao Zhang. (2024) PS-PPh2 tethered Pt single atoms promoted by SnCl2 as highly efficient and regio-selective catalysts for the hydroformylation of higher α-alkenes. CHINESE JOURNAL OF CATALYSIS, 60 (316). [10.1016/S1872-2067(24)60029-X]
13. Yafeng Wang, Xian Luo, Wenjie Lu, Bin Huang, Yanqing Yang. (2024) RhCo alloyed nanodendrites as an efficient electrocatalyst for boosting electro oxidation of ethylene glycol in alkaline media. CHEMICAL ENGINEERING JOURNAL, 499 (155924). [10.1016/j.cej.2024.155924]

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货号 (SKU)	包装规格	是否现货	价格	数量
R118540-250mg	250mg	现货
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三乙酰丙酮铑(III)

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