| 货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
|---|---|---|---|---|
| P466781-100ml |
100ml |
期货  |
|
| 英文别名 | DTXSID4060789 | EINECS 210-856-9 | PROPARGYL CHLORIDE [MI] | 3-Chloropropyne | 3-Chloroprop-1-yne (Propargyl chloride) | Propargyl chloride | P0810 | 1-Propyne, 3-chloro- | 3-CHLORO-1-PROPYNE | EN300-119441 | Q420202 | A833787 | 3-chloranylprop-1-yne | CH |
|---|---|
| 规格或纯度 | 70wt. % in toluene |
| 英文名称 | Propargyl chloride solution |
| 储存温度 | 2-8°C储存 |
| 运输条件 | 冰袋运输 |
| 产品介绍 |
Description Product is the 70wt.% solution of propargyl chloride in toluene. Propargyl chloride is a propargyl halide. Its trimethylsilylation reaction has been reported. Liquid-phase Raman spectra, and vapor-phase and solution-phase infrared spectra of propargyl chloride has been studied at 100-3400cm-1and 300-3800cm-1, respectively. It participates in the addition reaction with acyclic 1,3-dienes (at -78°C) in the presence of zinc chloride.Propargyl chloride solution may be used for the enantioselective synthesis of enantiomerically enriched homopropargyl alcohols.Propargyl chloride may be used as propargylating agent in the preparation of arabinogalactan propargyl ethers with degree of substitution up to 1.8. It may be used for thein situpreparation of propargyltrichlorosilane and allenyltrichlorosilane, required for the synthesis of optically active allenic and homopropargylic alcohols. |
| EC号 | 210-856-9 |
|---|---|
| IIUPAC Name | 3-chloroprop-1-yne |
| INCHI | 1S/C3H3Cl/c1-2-3-4/h1H,3H2 |
| Smiles | C#CCCl |
| Isomeric SMILES | C#CCCl |
| 分子量 | 74.51 |
| Beilstein号 | 506005 |
| Reaxy-Rn | 506005 |
| Reaxys-RN link address | https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=506005&ln= |
| 密度 | 0.963g/mL at 25°C |
|---|---|
| 折光率 | 1.44 |
| 闪点(℉) | 66.2 °F |
| 闪点(℃) | 19 °C |
| 沸点 | 57 °C |
| 熔点 | -78 °C |
| 分子量 | 74.510 g/mol |
| XLogP3 | 0.900 |
| 氢键供体数Hydrogen Bond Donor Count | 0 |
| 氢键受体数Hydrogen Bond Acceptor Count | 0 |
| 可旋转键计数Rotatable Bond Count | 0 |
| 精确质量Exact Mass | 73.9923 Da |
| 单同位素质量Monoisotopic Mass | 73.9923 Da |
| 拓扑极表面积Topological Polar Surface Area | 0.000 Ų |
| 重原子数Heavy Atom Count | 4 |
| 形式电荷Formal Charge | 0 |
| 复杂度Complexity | 38.500 |
| 同位素原子数Isotope Atom Count | 0 |
| 定义的原子立体中心计数Defined Atom Stereocenter Count | 0 |
| 未定义的原子立体中心计数Undefined Atom Stereocenter Count | 0 |
| 定义的键立体中心计数Defined Bond Stereocenter Count | 0 |
| 未定义的键立体中心计数Undefined Bond Stereocenter Count | 0 |
| 所有立体化学键的总数The total count of all stereochemical bonds | 0 |
| 共价键合单元计数Covalently-Bonded Unit Count | 1 |
| 象形图 | GHS02, GHS05, GHS06, GHS07 |
|---|---|
| 信号词 | 危险 |
| 危险声明 |
H225: 高度易燃的液体和蒸气 H304: 吞咽并进入呼吸道可能致命 H314: 造成严重的皮肤灼伤和眼睛损伤 H336: 可能引起嗜睡或头晕 H361d: 怀疑损害胎儿 H373: 通过长时间或反复暴露对器官造成损害 H412: 对水生生物有害并具有长期持续影响 H301+H311+H331: 吞咽、皮肤接触或吸入中毒。 |
| 预防措施声明 |
P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P233: 保持容器密闭。 P240: 地面/粘结容器和接收设备 P241: 使用防爆的[电气/通风/照明/.../]设备。 P242: 仅使用无火花的工具。 P243: 采取防静电措施 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P264: 处理后要彻底洗手。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P271: 仅在室外或通风良好的地方使用。 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P284: 如果通风不良，请佩戴呼吸防护装置。 P320: 迫切需要特殊治疗（请参阅此标签上的...）。 P321: 特殊处理（请参阅此标签上的...）。 P330: 漱口 P363: 再次使用之前，请清洗受污染的衣物。 P301+P330+P331: 如误吞咽：漱口。不要诱导呕吐。 P302+P352: 如皮肤沾染：用水充分清洗。 P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P361+P364: 立即脱掉所有沾染的衣服，清洗后方可重新使用。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P405: 密闭存放 P403+P233: 存放在通风良好的地方。保持容器密闭。 P403+P235: 存放在通风良好的地方。保持低温。 P501: 将内容物/容器处理到。。。 P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。 P301+P316: 如果吞咽：立即寻求紧急医疗救助。 P305+P354+P338: 如果进入眼睛：立即用水冲洗几分钟。取下隐形眼镜（如果有的话），并且操作简单。继续冲洗。 P317: 寻求紧急医疗救助。 P302+P361+P354: 如果接触皮肤：立即脱掉所有被污染的衣服。立即用水冲洗几分钟。 P316: 立即寻求紧急医疗救助。 P319: 如果你感到不适，请寻求医疗帮助。 |
| WGK Germany | 2 |
| Merck Index | 7810 |
| 个人防护装备 | Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US) |
| 1. Lyudmila A Grischenko,Lidiya N Parshina,Lyudmila V Kanitskaya,Lyudmila I Larina,Lyubov N Novikova,Boris A Trofimov. (2013-06-04) Propargylation of arabinogalactan with propargyl halides--a facile route to new functionalized biopolymers.. Carbohydrate research, 376 (7-14). [PMID:23727702] |
| 2. Zixuan Xu, Ke Liu, He Huang, Yadong Zhang, Zhouyang Long, Minman Tong, Guojian Chen. (2022) Quaternization-induced catalyst-free synthesis of viologen-linked ionic polyacetylenes towards heterogeneous catalytic CO2 fixation. Journal of Materials Chemistry A, 10 (10): (5540-5549). [10.1039/D1TA10312A] |
| 3. Lingxiao Gu, Qingquan Xue, Shusen Peng, Gang Wang, Jin Han, Xuedong Wu. (2016) A novel and facile strategy to inhibit corrosion: thiol-click synthesis of polythiols and their skinning on a metal surface to form super thick protective films. Polymer Chemistry, 7 (3): (625-632). [10.1039/C5PY01517K] |
| 4. Yujing Zuo, Dengxu Wang, Jie Zhang, Shengyu Feng. (2014) Multifunctional alkoxysilanes prepared by thiol–yne “click” chemistry: their luminescence properties and modification on a silicon surface. RSC Advances, 4 (108): (62827-62834). [10.1039/C4RA13620A] |
| 5. Daoyi Jiang, Gang Wang, Feng Zheng, Jin Han, Xuedong Wu. (2014) Novel thermo-sensitive hydrogels containing polythioether dendrons: facile tuning of LCSTs, strong absorption of Ag ions, and embedment of smaller Ag nanocrystals. Polymer Chemistry, 6 (4): (625-632). [10.1039/C4PY01158A] |
| 6. Jin Han, Bo Zhao, Aijin Tang, Yanqin Gao, Chao Gao. (2012) Fast and scalable production of hyperbranched polythioether-ynes by a combination of thiol-halogen click-like coupling and thiol-yne click polymerization. Polymer Chemistry, 3 (7): (1918-1925). [10.1039/C1PY00367D] |
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