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氟氢化钾

    级别和纯度:
  • AR
  • ≥99%
有货

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货号 (SKU) 包装规格 是否现货 价格 数量
P110483-500g
500g 现货 Stock Image
P110483-2.5kg
2.5kg 现货 Stock Image
P110483-10kg
10kg 现货 Stock Image

基本描述

别名 氟化氢钾 | 二氟氢化钾
英文别名 Potassium hydrofluoride | Potassium hydrogen difluoride
规格或纯度 AR, ≥99%
英文名称 Potassium hydrogen fluoride
应用 烷化苯的催化剂。蚀绘玻璃。制造氟。冶金助熔剂。制备 2-氟糖;无机磷酸盐的一氟化。
储存温度 充氩
运输条件 常规运输
产品介绍

略带酸臭味。在干燥空气中不失去氢氟酸,在潮湿空气中吸收水分并有氟化氢逸出,遇水分解成氟化钾和氢氟酸。易溶于醋酸钾,溶于稀乙醇,不溶于无水乙醇。水溶液呈酸性反应。有毒。有腐蚀性。 烷化苯的催化剂。蚀绘玻璃。制造氟。冶金助熔剂。制备 2-氟糖;无机磷酸盐的一氟化。


纯度 ≥99%

名称和识别符

EC号 232-156-2
UN Number 1811
Packing Group II
分子量 78.1

化学和物理性质

密度 1.136
敏感性 对湿度敏感
熔点 238.7°C

安全和危险性(GHS)

一般危化品 一般危化品
象形图 GHS05,   GHS06
信号词 危险
危险声明

H301: 吞咽会中毒

H314: 造成严重的皮肤灼伤和眼睛损伤

预防措施声明

P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。

P264: 处理后要彻底洗手。

P270: 使用本产品时,请勿进食、饮水或吸烟。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P363: 再次使用之前,请清洗受污染的衣物。

P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。

P303+P361+P353: 如皮肤(或头发)沾染:立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。

P405: 密闭存放

P501: 将内容物/容器处理到。。。

P301+P310+P330: 如果吞咽:漱口。立即致电中毒中心/医生。

WGK Germany 1
RTECS TS6650000
Class 8, 6.1
个人防护装备 Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

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批号(Lot Number) 证书类型 货号
L2117325 分析证书 P110483
L2117326 分析证书 P110483
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I2130037 分析证书 P110483
B2120228 分析证书 P110483
E23301144 分析证书 P110483
I2307618 分析证书 P110483
G2213267 分析证书 P110483
H2203498 分析证书 P110483
J2210660 分析证书 P110483
J2210666 分析证书 P110483
D2230005 分析证书 P110483
C2209360 分析证书 P110483
C2209365 分析证书 P110483
C2209386 分析证书 P110483
A2217054 分析证书 P110483

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此产品的引用文献

引用文献

1. Matthew J Hesse,Craig P Butts,Christine L Willis,Varinder K Aggarwal.  (2012-11-07)  Diastereodivergent synthesis of trisubstituted alkenes through protodeboronation of allylic boronic esters: application to the synthesis of the Californian red scale beetle pheromone..  Angewandte Chemie (International ed. in English),  51  ((50)): (12444-12448).  [PMID:23129403]
2. Y Kobayashi,N Taneichi,T Tsuchiya,K Koga.  (1992-05-22)  Reaction of 2-deoxy-6-O-[2,3-dideoxy-4,6-O-isopropylidene-2,3- (N-tosylepimino)-alpha-D-mannopyranosyl]-4,5-O-isopropylidene-1,3-di-N- tosylstreptamine with potassium hydrogenfluoride..  Carbohydrate research,  229  ((2)): (363-368).  [PMID:1394293]
3. Gary A Molander,Noel M Ellis.  (2008-08-07)  Highly stereoselective synthesis of cis-alkenyl pinacolboronates and potassium cis-alkenyltrifluoroborates via a hydroboration/protodeboronation approach..  The Journal of organic chemistry,  73  ((17)): (6841-6844).  [PMID:18681402]
4. Wenrui Zhang, Zhaowu Wang, Shiyu Jia, Yayun Zhou, Haipeng Ji.  (2023)  Millimeter-Sized K2MnF6:Si4+, NH4+ Red-Luminescent Crystals with High Absorption Efficiency (AEmax of 93.5%) and External Quantum Efficiency (EQEmax of 68.9%) Grown by Cooling-Induced Crystallization.  INORGANIC CHEMISTRY,  [PMID:38115192] [10.1021/acs.inorgchem.3c03844]
5. Yi Qin, Lingxiang Chu, Tao Yang, Jing Wan, Qiang Zhou, Yanqing Ye, Huaijun Tang, Zhengliang Wang.  (2024)  Spectroscopic properties and thermal stability of a Mn4+-doped polyfluoride phosphor for application in solid-state lighting.  JOURNAL OF LUMINESCENCE,  267  (120388).  [10.1016/j.jlumin.2023.120388]
6. Sisi Liang, Liping Song, Wendong Nie, Zihao Wang, Dejian Chen, Fulin Lin, Haomiao Zhu.  (2023)  Utilizing the Unique Redox Reaction Between Transition Metal Ions to Improve Mn4+ Doping Concentration and Achieve a High-Performance Red-Emitting Cs2NbF6: Mn4+ Phosphor.  Advanced Optical Materials,  (2301502).  [10.1002/adom.202301502]
7. Qiao Qu, Konglan Chen, Yayun Zhou, Jinsheng Li, Haipeng Ji.  (2023)  A Na2MoO2F4:Mn4+ phosphor with red luminescence peaking at 625 nm and a ZPL/v6 intensity ratio of 243%.  Journal of Materials Chemistry C,  11  (37): (12658-12666).  [10.1039/D3TC02609D]
8. Menglin Ye, Chen Yang, Aolin Wang, Gengli Chen, Dongming Yuan, Wenli Zhou.  (2023)  Advancing Red-Emitting Fluoride Phosphors for Highly Stable White Light-Emitting Diodes: Crystal Reconstruction and Covalence Enhancement Strategy.  INORGANIC CHEMISTRY,  62  (30): (12130–12137).  [PMID:37459403] [10.1021/acs.inorgchem.3c01709]
9. Pingping Wan, Chen Yang, Aolin Wang, Liping Yu, Shixun Lian, Wenli Zhou.  (2023)  Surface lattice enhancement of red-emitting fluorides enabled by embedding small cations.  Inorganic Chemistry Frontiers,  10  (17): (5089-5097).  [10.1039/D3QI01088K]
10. Yuhan Gao, Lei Feng, Linglin Wang, Jun Zheng, Feiyao Ren, Siyu Liu, Zhanglei Ning, Ting Zhou, Xiaochun Wu, Xin Lai, Daojiang Gao.  (2023)  Novel Mn4+-Activated K2Nb1−xMoxF7 (0 ≤ x ≤ 0.15) Solid Solution Red Phosphors with Superior Moisture Resistance and Good Thermal Stability.  MOLECULES,  28  (11): (4566).  [PMID:37299041] [10.3390/molecules28114566]
11. Xixiang Pan, Di Wu, Songbin Liu, Qiang Zhou, Biqing Song, Lu Wen, Li Luo, Jie Wang, Xinyu Ye.  (2023)  A novel thiourea loading strategy for improving the moisture resistance of K2SiF6: Mn4+ red phosphors.  MATERIALS RESEARCH BULLETIN,  163  (112215).  [10.1016/j.materresbull.2023.112215]
12. Xi Zhang, Song Qing, Yi Qin, Qiang Zhou, Jing Wan, Huaijun Tang, Zhenglian Wang.  (2023)  Luminescent properties of a double-perovskite Rb2KScF6:Mn4+ red-emitting phosphor for white light-emitting diodes.  JOURNAL OF LUMINESCENCE,  254  (119531).  [10.1016/j.jlumin.2022.119531]
13. Meng Gao, Weibing Zhang, Binchang Wu, Yining Dai, Chengdong Peng, Yuexiao Pan.  (2022)  Acetate-triggered morphology evolution and improved photoluminescence performance of K2NaInF6:Mn4+ crystals for wide applications.  JOURNAL OF LUMINESCENCE,  249  (119011).  [10.1016/j.jlumin.2022.119011]
14. Yong Liu, Anqi Huang, Shengchun Yang, Zhenjuan Duan, Zhengui Li, Zongtao Li, Hai Lan, Anzhong Peng, Xiaodong Wen, Zhengliang Wang.  (2022)  Synthesis and optical properties of a new double-perovskite Rb2KInF6:Mn4+ red phosphor used for blue LED pumped white lighting.  OPTICAL MATERIALS,  127  (112307).  [10.1016/j.optmat.2022.112307]
15. Hong Ming, Yifei Zhao, Yayun Zhou, Maxim S. Molokeev, Yuanjing Wang, Shuai Zhang, Enhai Song, Shi Ye, Zhiguo Xia, Qinyuan Zhang.  (2022)  Shining Mn4+ in 0D Organometallic Fluoride Hosts towards Highly Efficient Photoluminescence.  Advanced Optical Materials,  10  (7): (2102141).  [10.1002/adom.202102141]
16. Peilan Luo, Menglin Ye, Wenli Zhou, Pingping Wan, Zhongyun Ma, Zhongxian Qiu, Jilin Zhang, Ru-Shi Liu, Shixun Lian.  (2022)  Simultaneous construction of impermeable dual-shell stabilizing fluoride phosphors for white light-emitting diodes.  CHEMICAL ENGINEERING JOURNAL,  435  (134951).  [10.1016/j.cej.2022.134951]
17. Jing Yang, Peilan Luo, Pingping Wan, Menglin Ye, Zhongxian Qiu, Jilin Zhang, Shixun Lian, Chengzhi Li, Wenli Zhou.  (2022)  Surface engineered environment-stable red-emitting fluorides for white light emitting diodes.  CERAMICS INTERNATIONAL,  48  (5009).  [10.1016/j.ceramint.2021.11.038]
18. Yajun Jia, Chengdong Peng, Meng Gao, Keqin Yang, Aiying Wang, Yuexiao Pan.  (2022)  Optimization of the luminescence efficiency and moisture stability of a red phosphor KRb3Ge2F12:Mn4+ for indoor plant growth LED applications.  CERAMICS INTERNATIONAL,  48  (4208).  [10.1016/j.ceramint.2021.10.212]
19. Pingping Wan, Zijuan Liang, Peilan Luo, Shixun Lian, Wenli Zhou, Ru-Shi Liu.  (2021)  Reconstruction of Mn4+-free shell achieving highly stable red-emitting fluoride phosphors for light-emitting diodes.  CHEMICAL ENGINEERING JOURNAL,  426  (131350).  [10.1016/j.cej.2021.131350]
20. Xiaoling Xie, Jing Wan, Haiqi Pu, Xi Zhang, Song Qing, Qiang Zhou, Lingxiang Chu, Tao Yang, Yayun Zhou, Zhengliang Wang.  (2021)  Structure and luminescence behaviour of a novel red-emitting fluoroperovskite for display backlight application.  DALTON TRANSACTIONS,  50  (32): (11221-11227).  [PMID:34338702] [10.1039/D1DT02049H]
21. Di Peng, Shengan He, Yuyan Zhang, Liqin Yao, Wendong Nie, Zhijian Liao, Wenting Cai, Xinyu Ye.  (2022)  Blue light-induced rare-earth free phosphors for the highly sensitive and selective imaging of latent fingerprints based on enhanced hydrophobic interaction.  Journal of Materiomics,  (229).  [10.1016/j.jmat.2021.03.005]
22. Hong Ming, Yifei Zhao, Yayun Zhou, Shuai Zhang, Yuanjing Wang, Enhai Song, Zhiguo Xia, Qinyuan Zhang.  (2020)  A Guanidinium-Based Mn4+-Doped Red-Emitting Hybrid Phosphor with High Stability.  ACS Applied Electronic Materials,  (12): (4134–4145).  [10.1021/acsaelm.0c00916]
23. Dongxin Shi, Xiaoling Xie, Haiqi Pu, Xi Zhang, Qiang Zhou, Zhengliang Wang, Yanqing Ye, Minghong Chen.  (2020)  Communication—Luminescence Properties of a Novel l Rb2KGaF6:Mn4+ Red-Emitting Phosphor for Solid-State Lighting.  ECS Journal of Solid State Science and Technology,  (12): (126001).  [10.1149/2162-8777/abc835]
24. Dong Li, Yuexiao Pan, Xunan Wei, Jun Lin.  (2021)  Significantly enhanced the humidity resistance of a novel red phosphor CsNaGe0.5Sn0.5F6:Mn4+ through surface modification.  CHEMICAL ENGINEERING JOURNAL,  420  (127673).  [10.1016/j.cej.2020.127673]
25. Yan-Li Zhu, Yan-Mei Lian, Ji-Kai Wang, Zeng-Ping Chen, Ru-Qin Yu.  (2021)  Ultrasensitive detection of protein biomarkers by MALDI-TOF mass spectrometry based on ZnFe2O4 nanoparticles and mass tagging signal amplification.  TALANTA,  224  (121848).  [PMID:33379064] [10.1016/j.talanta.2020.121848]
26. Lili Liu, Di Wu, Shengan He, Zejian Ouyang, Junfei Zhang, Fu Du, Jiaqing Peng, Fengli Yang, Xinyu Ye.  (2020)  A Reverse Strategy to Restore the Moisture-deteriorated Luminescence Properties and Improve the Humidity Resistance of Mn4+-doped Fluoride Phosphors.  Chemistry-An Asian Journal,  15  (20): (3326-3337).  [PMID:32776694] [10.1002/asia.202000863]
27. Yong Liu, Zhi Zhou, Lin Huang, Mikhail G. Brik, Shuaichen Si, Litian Lin, Tongtong Xuan, Hongbin Liang, Jianbei Qiu, Jing Wang.  (2019)  High-performance and moisture-resistant red-emitting Cs2SiF6:Mn4+ for high-brightness LED backlighting.  Journal of Materials Chemistry C,  (8): (2401-2407).  [10.1039/C8TC06083E]
28. Aihu Feng, Yang Yu, Le Mi, Yunzhen Cao, Yun Yu, Lixin Song.  (2019)  Synthesis and characterization of hierarchical Y zeolites using NH4HF2 as dealumination agent.  MICROPOROUS AND MESOPOROUS MATERIALS,  280  (211).  [10.1016/j.micromeso.2019.01.039]
29. Chunyan Jiang, Mikhail G. Brik, Alok M. Srivastava, Lihua Li, Mingying Peng.  (2019)  Significantly conquering moisture-induced luminescence quenching of red line-emitting phosphor Rb2SnF6:Mn4+ through H2C2O4 triggered particle surface reduction for blue converted warm white light-emitting diodes.  Journal of Materials Chemistry C,  (2): (247-255).  [10.1039/C8TC05207G]
30. Chunyan Jiang, Mingying Peng, Alok M. Srivastava, Lihua Li, Mikhail G. Brik.  (2018)  Mn4+-Doped Heterodialkaline Fluorogermanate Red Phosphor with High Quantum Yield and Spectral Luminous Efficacy for Warm-White-Light-Emitting Device Application.  INORGANIC CHEMISTRY,  57  (23): (14705–14714).  [PMID:30451499] [10.1021/acs.inorgchem.8b02488]
31. Lei Zhang, Luqing Xi, Yuexiao Pan, Yajun Jia, Mingmei Wu, Hongzhou Lian, Jun Lin.  (2018)  Synthesis and improved photoluminescence of hexagonal crystals of Li2ZrF6:Mn4+ for warm WLED application.  DALTON TRANSACTIONS,  47  (46): (16516-16523).  [PMID:30411760] [10.1039/C8DT03790F]
32. Mengmeng Zhu, Yuexiao Pan, Mingmei Wu, Hongzhou Lian, Jun Lin.  (2019)  Optimized photoluminescence properties of a novel red phosphor LiSrAlF6:Mn4+ synthesized at room-temperature.  JOURNAL OF ALLOYS AND COMPOUNDS,  774  (331).  [10.1016/j.jallcom.2018.09.172]
33. Ming Gu, Yue Tian, Cai’e Cui, Ping Huang, Lei Wang, Qiufeng Shi.  (2018)  Two-step synthesis of a novel red-emitting Ba2ZrF8:Mn4+ phosphor for warm white light-emitting diodes.  MATERIALS RESEARCH BULLETIN,  107  (242).  [10.1016/j.materresbull.2018.07.031]
34. Mengmeng Zhu, Yuexiao Pan, Luqing Xi, Hongzhou Lian, Jun Lin.  (2017)  Design, preparation, and optimized luminescence of a dodec-fluoride phosphor Li3Na3Al2F12:Mn4+ for warm WLED applications.  Journal of Materials Chemistry C,  (39): (10241-10250).  [10.1039/C7TC03805D]
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36. Aihu Feng, Yun Yu, Yong Wang, Feng Jiang, Yang Yu, Le Mi, Lixin Song.  (2017)  Two-dimensional MXene Ti3C2 produced by exfoliation of Ti3AlC2.  MATERIALS & DESIGN,  114  (161).  [10.1016/j.matdes.2016.10.053]
37. J.S. Zhong, D.Q. Chen, X. Wang, L.F. Chen, H. Yu, Z.G. Ji, W.D. Xiang.  (2016)  Synthesis and optical performance of a new red-emitting ZnTiF6·6H2O:Mn4+ phosphor for warm white-light-emitting diodes.  JOURNAL OF ALLOYS AND COMPOUNDS,  662  (232).  [10.1016/j.jallcom.2015.12.075]
38. Li Gao, Tenghong Kong, Yanqing Ye, Peng Ren, Qiang Zhou, Huaijun Tang, Zhengliang Wang.  (2024)  High-efficiency RbASiF6:Mn4+ (A = K, Cs) phosphors obtained by one-step green synthesis method.  JOURNAL OF ALLOYS AND COMPOUNDS,  1008  (176529).  [10.1016/j.jallcom.2024.176529]
39. Wenrui Zhang, Yayun Zhou, Ce Shi, Jiajun Ren, Liying Zhang, Haipeng Ji.  (2024)  K2SiF6:Mn4+ red-luminescent crystals with high external quantum efficiency (EQEmax of 78%) and high thermal quenching temperature (T1/2 > 500 K) enabling high brightness warm white LEDs.  Journal of Materials Chemistry C,  [10.1039/D4TC04035J]
40. Wenyu Tang, Yuanjing Wang, Yayun Zhou, Chuang Zhang, Zhen Chen, Fanquan He, Enhai Song, Qinyuan Zhang.  (2024)  Li Substitution Strategy for Enhancing Quantum Efficiency and Improving Thermal Stability of Red-Light Mn4+-Activated Fluoride for Wide-Gamut Displays.  Advanced Optical Materials,  12  (19): (2400250).  [10.1002/adom.202400250]
41. Enbei Yang, Han Ma, Qiang Zhou, Mengyan Yang, Yurong Guo, Jing Wan, Huaijun Tang, Zhengliang Wang.  (2024)  Luminescence enhancement of near-infrared Cr3+ doped solid solution phosphor via Al3+ substitution for light-emitting diode applications.  CERAMICS INTERNATIONAL,  50  (54762).  [10.1016/j.ceramint.2024.10.335]
42. Lulu He, Mingxin Zhang, Xiaoliang Dong, Liying Zhang, Ce Shi, Haipeng Ji.  (2024)  Millimeter-scale Na2SiF6:Mn4+ red-emitting crystals with intense zero phonon line at 617 nm and enhanced hydrolysis resistance.  CERAMICS INTERNATIONAL,  [10.1016/j.ceramint.2024.12.239]
43. Jun Zheng, Linglin Wang, Lei Feng, Yuhan Gao, Feiyao Ren, Siyu Liu, Ting Zhou, Xiaochun Wu, Xin Lai, Daojiang Gao.  (2024)  Mn4+-activated (K1-xCsx)2NbF7 red phosphors with high color purity and excellent moisture resistance for WLEDs.  MATERIALS RESEARCH BULLETIN,  173  (112695).  [10.1016/j.materresbull.2024.112695]
44. Qiao Qu, Haiyan Zhang, Haipeng Ji.  (2024)  Non-equivalent Mn4+ doping in mixed-anion host of K3Na(MoO2F4)2·H2O achieving short fluorescence lifetime and intense zero phonon line.  Journal of Materials Chemistry C,  [10.1039/D4TC00218K]
45. Yitong Guo, Sen Jin, Libo Wang, Qixun Xia, Aiguo Zhou.  (2024)  Rapid preparation of Mo2CTx MXene by hydrothermal etching in ammonium hydrogen fluoride solution.  JOURNAL OF ALLOYS AND COMPOUNDS,  998  (175009).  [10.1016/j.jallcom.2024.175009]
46. Yufan Wei, Qianxing Huang, Shijie Yu, Qiyue Shao, Jianqing Jiang.  (2024)  Reconstructing the Surface of K2SiF6:Mn4+ Phosphors toward Enhanced Moisture Resistance for White LED Applications.  ACS Applied Materials & Interfaces,  16  (41): (55792-55801).  [PMID:39376150] [10.1021/acsami.4c12727]
47. Huaiyong Li, Lulu Xing, Shifang Wang, Mingzheng Sun, Yangbo Wang, Xufeng Zhou, Shanshan Du, Wanying Geng, Jigong Hao, Wei Li.  (2024)  Synthesis, crystal structure and photoluminescence properties of Mn4+ activated K2WO2F4·H2O.  JOURNAL OF LUMINESCENCE,  269  (120515).  [10.1016/j.jlumin.2024.120515]
48. Huiting Yu, Xi Sun, Zheng Liu, Heguo Han, Jianhang Qiu, Qifeng Zhang, Yuxuan Sun, Shenghai Li, Suobo Zhang.  (2024)  Utilizing N-cyclohexyl imine as a protecting group enables faster fabrication of solvent-resistant PEK membranes.  POLYMER,  315  (127812).  [10.1016/j.polymer.2024.127812]

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