基本描述

别名	六甲基二硅基胺钾 \| 六甲基二硅氮烷钾盐溶液
英文别名	KHMDS
规格或纯度	1 M in THF(约22%含量)
英文名称	Potassium bis(trimethylsilyl)amide
储存温度	2-8°C储存,充氩
运输条件	冰袋运输
产品介绍	易溶于芳香烃和醚。非亲核性强碱。六甲基二硅胺钾（三甲基硅烷基）溶液（1 M in THF）已被用作聚环氧乙烷（PEO）聚合的阴离子引发剂。应用六甲基二硅胺钾（三甲基硅烷基）溶液（1 M in THF）已被用作聚环氧乙烷（PEO）聚合的阴离子引发剂。 Potassium bis(trimethylsilyl)amide solution (1 M in THF) has been used as an anionic initiator in the polymerization of polyethylene oxide(PEO).

名称和识别符

分子类型	未知
Isomeric SMILES	C[Si](C)(C)[N-][Si](C)(C)C.[K+]
PubChem CID	3251421
UN Number	3263
分子量	199.48
Beilstein号	4006754

化学和物理性质

溶解性	Reacts readily with water to form potassium hydroxide and hexamethyldisilazane. Soluble in aromatic hydrocarbons, ether,terahydrofuran, benzene and toluene.
密度	0.915
敏感性	对湿度，空气，光线敏感
闪点(℉)	4℃
闪点(℃)	4℃
沸点	66°C

安全和危险性（GHS）

象形图	GHS02, GHS07, GHS08
信号词	危险
危险声明	H225: 高度易燃的液体和蒸气 H304: 吞咽并进入呼吸道可能致命 H314: 造成严重的皮肤灼伤和眼睛损伤 H336: 可能引起嗜睡或头晕 H361d: 怀疑损害胎儿 H373: 通过长时间或反复暴露对器官造成损害
预防措施声明	P201: 使用前获取特殊说明 P210: 远离热源，热表面，火花，明火和其他点火源。 - 禁止抽烟。 P202: 在阅读并理解所有安全预防措施之前，不要进行操作。 P233: 保持容器密闭。 P240: 地面/粘结容器和接收设备 P241: 使用防爆的[电气/通风/照明/.../]设备。 P242: 仅使用无火花的工具。 P243: 采取防静电措施 P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾 P264: 处理后要彻底洗手。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P271: 仅在室外或通风良好的地方使用。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P330: 漱口 P301+P312: 如误吞咽：如感觉不适，呼叫急救中心/医生。 P303+P361+P353: 如皮肤（或头发）沾染：立即脱掉所有沾染的衣服。用水清洗皮肤/淋浴。 P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P308+P313: 如接触到或有疑虑：求医/就诊。 P337+P313: 如仍觉眼刺激：求医/就诊。 P370+P378: 火灾时：使用干砂、干粉或抗醇泡沫灭火。 P405: 密闭存放 P403+P233: 存放在通风良好的地方。保持容器密闭。 P403+P235: 存放在通风良好的地方。保持低温。 P501: 将内容物/容器处理到。。。
WGK Germany	3
个人防护装备	Faceshields,full-face respirator (US),Gloves,Goggles,multi-purpose combination respirator cartridge (US),type ABEK (EN14387) respirator filter

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批号(Lot Number)	证书类型	货号
H2206212	分析证书	P109542
H2515502	分析证书	P109542
H2515503	分析证书	P109542
D2402409	分析证书	P109542
L2325009	分析证书	P109542
D2523232	分析证书	P109542
D2523225	分析证书	P109542
D2523283	分析证书	P109542
D2524057	分析证书	P109542
K2428575	分析证书	P109542
K2428576	分析证书	P109542
D2402408	分析证书	P109542
D2402407	分析证书	P109542
D2402514	分析证书	P109542
A2314240	分析证书	P109542
J2320426	分析证书	P109542
J2320427	分析证书	P109542
L2031227	分析证书	P109542
H2206216	分析证书	P109542
A2314242	分析证书	P109542
H2206214	分析证书	P109542
G2312097	分析证书	P109542
I2320026	分析证书	P109542
I2101362	分析证书	P109542
A2213600	分析证书	P109542
A2213602	分析证书	P109542
A2214119	分析证书	P109542

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引用文献

1. Hua Lu,Jianjun Cheng. (2007-10-30) Hexamethyldisilazane-mediated controlled polymerization of alpha-amino acid N-carboxyanhydrides.. Journal of the American Chemical Society, 129 ((46)): (14114-14115). [PMID:17963385]
2. H B Lazrek,D Ouzebla,L Baddi,J J Vasseur. (2007-12-07) Glycosylation reaction via a mild and efficient one-pot reaction using doped natural phosphate with iodine as catalyst.. Nucleosides, nucleotides & nucleic acids, 26 ((8-9)): (1095-1098). [PMID:18058543]
3. Tong Zhang,Ibrahim Khadra,Melvin R Euerby,Graham G Skellern,David G Watson,Justice N A Tettey. (2008-01-24) Simultaneous analysis of basic, acidic and neutral compounds on an endcapped octadecylsilane silica-based monolith by pressure-assisted capillary electrochromatography.. Electrophoresis, 29 ((4)): (944-951). [PMID:18213596]
4. Daniele Fabbri,Leszek Marynowski,Monika J Fabiańska,Michał Zatoń,Bernd R T Simoneit. (2008-05-24) Levoglucosan and other cellulose markers in pyrolysates of Miocene lignites: geochemical and environmental implications.. Environmental science & technology, 42 ((8)): (2957-2963). [PMID:18497150]
5. Takashi Nagase,Yoshihiro Sasazaki,Toshiyuki Kikuchi,Masafumi Machida. (2008-10-03) Rapid 3-dimensional imaging of embryonic craniofacial morphology using microscopic computed tomography.. Journal of computer assisted tomography, 32 ((5)): (816-821). [PMID:18830118]
6. A Sebok,K Sezer,A Vasanits-Zsigrai,A Helenkár,Gy Záray,I Molnár-Perl. (2008-10-14) Gas chromatography-mass spectrometry of the trimethylsilyl (oxime) ether/ester derivatives of cholic acids: their presence in the aquatic environment.. Journal of chromatography. A, 1211 ((1-2)): (104-112). [PMID:18849033]
7. Nan Li,Chih-Ming Ho. (2008-11-22) Photolithographic patterning of organosilane monolayer for generating large area two-dimensional B lymphocyte arrays.. Lab on a chip, 8 ((12)): (2105-2112). [PMID:19023473]
8. Werner Mormann,Markus Wezstein. (2008-11-26) Trimethylsilylation of cellulose in ionic liquids.. Macromolecular bioscience, 9 ((4)): (369-375). [PMID:19031387]
9. Jerry Isaacson,Yoshihisa Kobayashi. (2009-01-29) An Ugi reaction in the total synthesis of (-)-dysibetaine.. Angewandte Chemie (International ed. in English), 48 ((10)): (1845-1848). [PMID:19173271]
10. Elsa Vennat,Christine Bogicevic,Jean-Marie Fleureau,Michel Degrange. (2009-01-29) Demineralized dentin 3D porosity and pore size distribution using mercury porosimetry.. Dental materials : official publication of the Academy of Dental Materials, 25 ((6)): (729-735). [PMID:19174308]
11. Hung-Che Chou,Tsong-Rong Yan,Ko-Shao Chen. (2009-06-24) Detecting cells on the surface of a silver electrode quartz crystal microbalance using plasma treatment and graft polymerization.. Colloids and surfaces. B, Biointerfaces, 73 ((2)): (244-249). [PMID:19545984]
12. Guanxia Shen,Yiqing Lu,Li Shen,Yi Zhang,Shouwu Guo. (2009-07-16) Nondestructively creating nanojunctions by combined-dynamic-mode dip-pen nanolithography.. Chemphyschem : a European journal of chemical physics and physical chemistry, 10 ((13)): (2226-2229). [PMID:19603447]
13. Tatsuya Nitabaru,Akihiro Nojiri,Makoto Kobayashi,Naoya Kumagai,Masakatsu Shibasaki. (2009-09-10) anti-Selective catalytic asymmetric nitroaldol reaction via a heterobimetallic heterogeneous catalyst.. Journal of the American Chemical Society, 131 ((38)): (13860-13869). [PMID:19736990]
14. Haoyu Tang,Donghui Zhang. (2010-05-15) General route toward side-chain-functionalized alpha-helical polypeptides.. Biomacromolecules, 11 ((6)): (1585-1592). [PMID:20465286]
15. D B Mahadik,A Venkateswara Rao,A Parvathy Rao,P B Wagh,S V Ingale,Satish C Gupta. (2011-02-01) Effect of concentration of trimethylchlorosilane (TMCS) and hexamethyldisilazane (HMDZ) silylating agents on surface free energy of silica aerogels.. Journal of colloid and interface science, 356 ((1)): (298-302). [PMID:21277584]
16. Xiaoguang Li,Jun Shen. (2011-08-30) A facile two-step dipping process based on two silica systems for a superhydrophobic surface.. Chemical communications (Cambridge, England), 47 ((38)): (10761-10763). [PMID:21874180]
17. Adrienne C Greene,Cody M Washburn,George D Bachand,Conrad D James. (2011-09-03) Combined chemical and topographical guidance cues for directing cytoarchitectural polarization in primary neurons.. Biomaterials, 32 ((34)): (8860-8869). [PMID:21885117]
18. Zhengtao Deng,Dongran Han,Yan Liu. (2011-09-15) Colloidal synthesis of metastable zinc-blende IV-VI SnS nanocrystals with tunable sizes.. Nanoscale, 3 ((10)): (4346-4351). [PMID:21915425]
19. S V Buravkov,V P Chernikov,L B Buravkova. (2012-03-28) Simple method of specimen preparation for scanning electron microscopy.. Bulletin of experimental biology and medicine, 151 ((3)): (378-382). [PMID:22451892]
20. Juliana Tsz Yan Lee,King Lau Chow. (2012-04-26) SEM sample preparation for cells on 3D scaffolds by freeze-drying and HMDS.. Scanning, 34 ((1)): (12-25). [PMID:22532079]
21. Nur Hazlin Hazrin-Chong,Mike Manefield. (2012-05-09) An alternative SEM drying method using hexamethyldisilazane (HMDS) for microbial cell attachment studies on sub-bituminous coal.. Journal of microbiological methods, 90 ((2)): (96-99). [PMID:22561094]
22. Marko Marinkovic,Dagmawi Belaineh,Veit Wagner,Dietmar Knipp. (2012-06-26) On the origin of contact resistances of organic thin film transistors.. Advanced materials (Deerfield Beach, Fla.), 24 ((29)): (4005-4009). [PMID:22730030]
23. Mario Janjetovic,Annika M Träff,Tobias Ankner,Jenny Wettergren,Göran Hilmersson. (2013-01-30) Solvent dependent reductive defluorination of aliphatic C-F bonds employing Sm(HMDS)2.. Chemical communications (Cambridge, England), 49 ((18)): (1826-1828). [PMID:23358653]
24. André M Bienfait,Christoph Schädle,Cäcilia Maichle-Mössmer,Karl W Törnroos,Reiner Anwander. (2014-10-17) Europium bis(dimethylsilyl)amides including mixed-valent Eu3[N(SiHMe2)2]6[μ-N(SiHMe2)2]2.. Dalton transactions (Cambridge, England : 2003), 43 ((46)): (17324-17332). [PMID:25318830]
25. Yulei Wu, Xiaohui Liu, Xiaodong Li, Wenjun Zhang, Hai-Qiao Wang, Junfeng Fang. (2016) High-Performance Polymer Solar Cells with Zinc Sulfide-Phenanthroline Derivatives as the Hybrid Cathode Interlayers. ACS Applied Materials & Interfaces, 8 (4): (2688–2693). [PMID:26757048] [10.1021/acsami.5b10798]

溶液计算器

摩尔浓度计算器

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分子量

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稀释计算器

计算配制储备溶液所需的稀释度。

浓度1（C1）

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体积 1 (V1)

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浓度 2 (C2)

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复溶计算器

复溶计算器允许您快速计算试剂的体积，以复溶小瓶。只需输入试剂的质量和目标浓度，计算器将确定其余部分。

体积（添加到小瓶中）

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质量（小瓶）

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所需的复溶浓度

货号 (SKU)	包装规格	是否现货
P109542-100ml	100ml	现货
P109542-500ml	500ml	现货
P109542-1L	1L	现货

双(三甲基硅烷基)氨基钾

库存信息

库存信息

库存信息

基本描述

名称和识别符

化学和物理性质

安全和危险性（GHS）

质检证书（CoA,COO,BSE/TSE 和分析图谱)

显示更多⌵

可替换产品

此产品的引用文献

引用文献

溶液计算器

摩尔浓度计算器

稀释计算器

复溶计算器