基本描述

别名	聚甲基氢硅氧烷 \| 甲基氢硅氧烷聚合物
英文别名	SCHEMBL20166 \| 2-Methyl-1,2-oxasilinanato \| DTXSID20733323
规格或纯度	粘度：15 - 40 mPa.s(20°C)
英文名称	Poly(methylhydrosiloxane)
运输条件	常规运输
产品介绍	不溶于水。溶于大多数常见有机溶剂，可能会发生反应。不能用做卤烃溶媒，因为可能在催化或加热时发生卤化氢交换反应还原剂作为硼氢化物的替代物，用于还原胺化合成绿色胺。取代胺和异吲哚酮的合成：用大量可用的AlCl3/PMHS催化还原胺化使用聚甲基羟基硅氧烷和[RuCl2（芳烃）]2催化剂，温和催化亚胺的氢化硅烷化，最终合成胺 We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an environmentally benign reducing agent and has been enhanced for catalytic efficiency. Click here for more information. Harnessing the reactivity of poly(methylhydrosiloxane) for the reduction and cyclization of biomass to high-value products We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product is an environmentally benign reducing agent and has been enhanced for catalytic efficiency. Click here for more information. Harnessing the reactivity of poly(methylhydrosiloxane) for the reduction and cyclization of biomass to high-value products Reducing agent. Used in greener amine synthesis by reductive amination as an alternative to borohydrides. Synthesis of substituted amines and isoindolinones: catalytic reductive amination using abundantly available AlCl3/PMHS Amine Synthesis through Mild Catalytic Hydrosilylation of Imines using Polymethylhydroxysiloxane and [RuCl2(arene)]2 Catalysts

名称和识别符

PubChem SID	504767131
INCHI	1S/C5H11OSi/c1-7-5-3-2-4-6-7/h2-5H2,1H3
InChi Key	TXYXVOOPRILIHR-UHFFFAOYSA-N
Smiles	C[Si]1CCCCO1
Isomeric SMILES	C[Si]1CCCCO1
关联CAS	63148-57-2
PubChem CID	12487658

化学和物理性质

溶解性	Not miscible or difficult to mix in water
密度	1.006
闪点(℉)	399.2°F
闪点(℃)	204°C
分子量	115.230 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	1
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	115.058 Da
单同位素质量Monoisotopic Mass	115.058 Da
拓扑极表面积Topological Polar Surface Area	9.200 Å²
重原子数Heavy Atom Count	7
形式电荷Formal Charge	0
复杂度Complexity	56.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	1
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

质检证书（CoA,COO,BSE/TSE 和分析图谱)

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找到13个结果

批号(Lot Number)	证书类型	货号
L2311288	分析证书	P107083
I2509124	分析证书	P107083
C2307888	分析证书	P107083
C2307890	分析证书	P107083
D2417030	分析证书	P107083
F2511060	分析证书	P107083
A2515039	分析证书	P107083
C2201477	分析证书	P107083
C2201481	分析证书	P107083
C2201533	分析证书	P107083
F2122181	分析证书	P107083
F2122182	分析证书	P107083
F2122183	分析证书	P107083

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此产品的引用文献

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引用文献

1. Jing Wang, Zhehao Wang, Zhonglin Chen, Pengwei Yan, Jimin Shen, Jing Kang. (2023) Preparation of Molecularly Imprinted Magnetic Stir Bar for Bisphenol A and Its Analysis on Trace Bisphenol A in Actual Water Samples. Water, 15 (19): (3361). [10.3390/w15193361]
2. Shuai-Yin Ma, Yuan-Sen Zhi, Hong-Shuang Zhang, Xiao-Zhi He, Bao-Yan Zhang, Fan-Bao Meng, Zhi-Na Ji. (2023) Fluorescent cholesteric liquid crystal polymers with dual properties: design, synthesis and characterisation. LIQUID CRYSTALS, [10.1080/02678292.2023.2206376]
3. Xiang-Yu Ma, Qiu-Cheng Li, Cheng-Han Song, Hong-Shuang Zhang, Yuan-Sen Zhi, Xiao-Zhi He. (2022) The effect of different photoluminescent side-chain length on the phase behaviour of chiral liquid crystal polymer. LIQUID CRYSTALS, [10.1080/02678292.2022.2044527]
4. Zhongshao Li, Shuwen Zhao, Zewei Shao, Hanxiang Jia, Aibin Huang, Ping Jin, Xun Cao. (2022) Deterioration mechanism of vanadium dioxide smart coatings during natural aging: Uncovering the role of water. CHEMICAL ENGINEERING JOURNAL, 447 (137556). [10.1016/j.cej.2022.137556]
5. Anhang Li, Sifan Chen, Zhidong Ma, Min Sun, Guiyu Zhu, Yue Zhang, Wei Wang. (2021) Corrosion protection properties of polyvinyl butyral/polyaniline-graphene oxide/poly (methylhydrosiloxane) composite coating for AA2024 aluminum alloy. DIAMOND AND RELATED MATERIALS, 116 (108397). [10.1016/j.diamond.2021.108397]
6. Panlei Liu, Na Sun, Yuanyuan Mi, Xiaohang Luo, Xiaoxiao Dong, Jiaye Cai, Xilai Jia, Melvin A. Ramos, Travis Shihao Hu, Quan Xu. (2021) Ultra-low CNTs filled high-performance fast self-healing triboelectric nanogenerators for wearable electronics. COMPOSITES SCIENCE AND TECHNOLOGY, 208 (108733). [10.1016/j.compscitech.2021.108733]
7. Yao Jianmei, Zhang Lingxue, Ran Jinfeng, Wang Shasha, Dong Nan. (2020) Specific recognition of cationic paraquat in environmental water and vegetable samples by molecularly imprinted stir-bar sorptive extraction based on monohydroxylcucurbit[7]uril–paraquat inclusion complex. MICROCHIMICA ACTA, 187 (10): (1-10). [PMID:32975594] [10.1007/s00604-020-04491-5]
8. Anhang Li, Min Sun, Zhidong Ma, Sifan Chen, Guiyu Zhu, Yue Zhang, Wei Wang. (2020) Anticorrosion performance of polyvinyl butyral composite coatings improved by polyaniline-multiwalled carbon nanotubes/poly (methylhydrosiloxane). THIN SOLID FILMS, 712 (138347). [10.1016/j.tsf.2020.138347]
9. Shang Gao, Ze-ping Liu, Yue-hua Cong, Xiao-zhi He, Bao-yan Zhang, Fan-bao Meng, Ying-gang Jia. (2020) Cholesteric fluorescent liquid crystal polysiloxanes with different liquid crystal side chain lengths—Synthesis and properties. DYES AND PIGMENTS, 181 (108520). [10.1016/j.dyepig.2020.108520]
10. Dong Nan, Zhang Lingxue, Yao Jianmei, Ma Peijian, He Jing, Li Tao, Wang Yuan. (2019) Monohydroxycucurbit[7]uril-coated stir-bar sorptive extraction coupled with high-performance liquid chromatography for the determination of apolar and polar organic compounds. MICROCHIMICA ACTA, 186 (12): (1-10). [PMID:31776838] [10.1007/s00604-019-3910-y]
11. Jun Zhang, Kaijun Dong, Weimin Luo. (2019) PdCl2-catalyzed hydrodeoxygenation of 5-hydroxymethylfurfural into 2,5-dimethylfuran at room-temperature using polymethylhydrosiloxane as the hydrogen donor. CHEMICAL ENGINEERING SCIENCE, 201 (467). [10.1016/j.ces.2019.03.011]
12. Tiemei Li, Yuefei Song, Jingjie Xu, Jing Fan. (2019) A hydrophobic deep eutectic solvent mediated sol-gel coating of solid phase microextraction fiber for determination of toluene, ethylbenzene and o-xylene in water coupled with GC-FID. TALANTA, 195 (298). [PMID:30625546] [10.1016/j.talanta.2018.11.085]
13. Hu Li, Wenfeng Zhao, Zhen Fang. (2017) Hydrophobic Pd nanocatalysts for one-pot and high-yield production of liquid furanic biofuels at low temperatures. APPLIED CATALYSIS B-ENVIRONMENTAL, 215 (18). [10.1016/j.apcatb.2017.05.039]
14. Nan Dong, Tao Li, Yujie Luo, Lin Shao, Zhu Tao, Chun Zhu. (2016) A solid-phase microextraction coating of sol–gel-derived perhydroxy cucurbit[6]uril and its application on to the determination of polycyclic aromatic hydrocarbon. JOURNAL OF CHROMATOGRAPHY A, 1470 (9). [PMID:27702617] [10.1016/j.chroma.2016.09.066]
15. Miaomiao Tian, Rongmin Cheng, Juanjuan Ye, Xiaoting Liu, Qiong Jia. (2014) Preparation and evaluation of ionic liquid-calixarene solid-phase microextraction fibres for the determination of triazines in fruit and vegetable samples. FOOD CHEMISTRY, 145 (28). [PMID:24128445] [10.1016/j.foodchem.2013.08.029]
16. Na Sheng, Fangdi Wei, Wen Zhan, Zheng Cai, Shuhu Du, Xuemin Zhou, Fei Li, Qin Hu. (2012) Dummy molecularly imprinted polymers as the coating of stir bar for sorptive extraction of bisphenol A in tap water. JOURNAL OF SEPARATION SCIENCE, 35 (5-6): (707-712). [PMID:22331819] [10.1002/jssc.201100883]
17. Jingrui Li, Xiaobo Xu, Xiaozhen Ma, Minghui Cui, Xiaolin Wang, Jing Chen, Jin Zhu, Jing Chen. (2024) Antimicrobial Nonisocyanate Polyurethane Foam Derived from Lignin for Wound Healing. ACS Applied Bio Materials, 7 (2): (1301-1310). [PMID:38305746] [10.1021/acsabm.3c01257]
18. Yiran Bian, Yi Zhang, Taosuo Wang, Chuang Yang, Zhiming Feng, Kheng-Lim Goh, Yibin Zhou, Mingming Zheng. (2024) Insights into the enzymatic synthesis of alcoholic flavor esters with molecular docking analysis. LWT-FOOD SCIENCE AND TECHNOLOGY, 200 (116206). [10.1016/j.lwt.2024.116206]
19. Cailang Lu, Qian Jia, Linlin Yu, Bin Zhang, Ruoyu Chen. (2024) Mechanistic Insight into the Synthesis and Morphological Evolution of Superhydrophobic Silica Nanotubes. INORGANIC CHEMISTRY, 63 (28): (13039-13047). [PMID:38941071] [10.1021/acs.inorgchem.4c01856]

溶液计算器

摩尔浓度计算器

计算溶液所需的质量、体积或浓度。

质量

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浓度

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体积

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分子量

g/mol

稀释计算器

计算配制储备溶液所需的稀释度。

浓度1（C1）

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体积 1 (V1)

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浓度 2 (C2)

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复溶计算器

复溶计算器允许您快速计算试剂的体积，以复溶小瓶。只需输入试剂的质量和目标浓度，计算器将确定其余部分。

体积（添加到小瓶中）

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质量（小瓶）

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所需的复溶浓度

货号 (SKU)	包装规格	是否现货
P107083-25g	25g	现货
P107083-50g	50g	现货
P107083-250g	250g	现货
P107083-1kg	1kg	现货

聚（甲基氢硅氧烷）

库存信息

库存信息

库存信息

库存信息

基本描述

名称和识别符

化学和物理性质

安全和危险性（GHS）

质检证书（CoA,COO,BSE/TSE 和分析图谱)

显示更多⌵

此产品的引用文献

引用文献

溶液计算器

摩尔浓度计算器

稀释计算器

复溶计算器