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硫化镍

    级别和纯度:
  • ≥99.7% metals basis
  • >150目
有货

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库存信息

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货号 (SKU) 包装规格 是否现货 价格 数量
N475047-5g
5g 现货 Stock Image
N475047-25g
25g 现货 Stock Image
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硫化物盐 (5) 镍化合物 (14)

基本描述

别名 碱式硫化镍
英文别名 (sulfanylidene-lambda4-sulfanylidene)nickel | CCRIS 432 | alpha-Nickel sulfide (3:2) crystalline | Nickel subsulphide | UNII-ZK2A2WV92Z | alpha nickel subsulfide | EINECS 234-829-6 | EC 234-829-6 | HSDB 2965 | Nickel(III) sulfide | nickel
规格或纯度 ≥99.7% metals basis, >150目
英文名称 Nickel sulfide
产品介绍


Major phase is Ni3S2. Product may also include a small amount of sulfur-rich phase. Nickel Sulfide (Ni3S2) exists as a heazlewoodite mineral in nature. The structure of Ni3S2 is hombohedral. Raman spectral analysis of Ni3S2 has been reported.

纯度 ≥99.7% metals basis

名称和识别符

EC号 234-829-6
分子类型 未知
IIUPAC Name nickel;(sulfanylidene-λ4-sulfanylidene)nickel
INCHI 1S/3Ni.S2/c;;;1-2
InChi Key UPSUSTJZZWSTPN-UHFFFAOYSA-N
Smiles S=S=[Ni].[Ni].[Ni]
Isomeric SMILES S=S=[Ni].[Ni].[Ni]
PubChem CID 22833473
UN Number 3077
Packing Group III
分子量 240.21

化学和物理性质

溶解性 Soluble in water(0,00735 g/L at 20°C).
密度 5.8g/mL at 25°C (lit.)
熔点 >360° C

安全和危险性(GHS)

象形图 GHS06,   GHS07,   GHS08,   GHS09
信号词 危险
危险声明

H317: 可能引起皮肤过敏反应

H331: 吸入会中毒

H332: 吸入有害

H341: 怀疑引起遗传缺陷

H350: 可能导致癌症

H350i: 吸入可能致癌

H372: 通过长时间或反复暴露对器官造成损害

H400: 对水生生物有剧毒

H410: 对水生生物有剧毒并具有长期持续影响

预防措施声明

P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P264: 处理后要彻底洗手。

P270: 使用本产品时,请勿进食、饮水或吸烟。

P271: 仅在室外或通风良好的地方使用。

P272: 被污染的工作服不允许离开工作场所

P273: 避免释放到环境中。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P281: 根据需要使用个人防护设备。

P321: 特殊处理(请参阅此标签上的...)。

P391: 收集溢出物

P302+P352: 如皮肤沾染:用水充分清洗。

P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。

P333+P313: 如发生皮肤刺激或皮疹:求医/就诊。

P362+P364: 脱掉沾污的衣服,清洗后方可重新使用。

P405: 密闭存放

P403+P233: 存放在通风良好的地方。保持容器密闭。

P501: 将内容物/容器处理到。。。

P203: 使用前,获取、阅读并遵守所有安全说明。

P318: 如果暴露或担心,请就医。

P317: 寻求紧急医疗救助。

P316: 立即寻求紧急医疗救助。

P319: 如果你感到不适,请寻求医疗帮助。

WGK Germany 2
RTECS QR9800000
Class 9

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找到6个结果

批号(Lot Number) 证书类型 货号
D2515685 分析证书 N475047
K2422608 分析证书 N475047
K2422607 分析证书 N475047
I2418054 分析证书 N475047
C2413243 分析证书 N475047
C2413244 分析证书 N475047

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此产品的引用文献

引用文献

1. M Okamoto.  (1997-08-01)  Simultaneous demonstration of lens regeneration from dorsal iris and tumour production from ventral iris in the same newt eye after carcinogen administration..  Differentiation; research in biological diversity,  61  ((5)): (285-292).  [PMID:9342839]
2. C Ikai,M Okamoto.  (1998-05-06)  Reduced macrophage phagocytic activity in Wolffian lens regeneration of the newt after nickel subsulfide administration..  Comparative biochemistry and physiology. Part C, Pharmacology, toxicology & endocrinology,  119  ((1)): (81-88).  [PMID:9568377]
3. C Mayer,R G Klein,H Wesch,P Schmezer.  (1998-12-05)  Nickel subsulfide is genotoxic in vitro but shows no mutagenic potential in respiratory tract tissues of BigBlue rats and Muta Mouse mice in vivo after inhalation..  Mutation research,  420  ((1-3)): (85-98).  [PMID:9838057]
4. S Hamdan,B Morse,D Reinhold.  (1999-05-20)  Nickel subsulfide is similar to potassium dichromate in protecting normal human fibroblasts from the mutagenic effects of benzo[a]pyrene diolepoxide..  Environmental and molecular mutagenesis,  33  ((3)): (211-218).  [PMID:10334623]
5. S K Chakrabarti,C Bai,K S Subramanian.  (2001-02-13)  DNA-protein crosslinks induced by nickel compounds in isolated rat lymphocytes: role of reactive oxygen species and specific amino acids..  Toxicology and applied pharmacology,  170  ((3)): (153-165).  [PMID:11162780]
6. Joseph R Landolph,Anuradha Verma,Jamuna Ramnath,Farrah Clemens.  (2002-11-12)  Molecular biology of deregulated gene expression in transformed C3H/10T1/2 mouse embryo cell lines induced by specific insoluble carcinogenic nickel compounds..  Environmental health perspectives,  110 Suppl 5  (845-850).  [PMID:12426144]
7. Michael P Waalkes,Jie Liu,Kazimierz S Kasprzak,Bhalchandra A Diwan.  (2005-08-30)  Metallothionein-I/II double knockout mice are no more sensitive to the carcinogenic effects of nickel subsulfide than wild-type mice..  International journal of toxicology,  24  ((4)): (215-220).  [PMID:16126615]
8. Weiming Ouyang,Jingxia Li,Xianglin Shi,Max Costa,Chuanshu Huang.  (2005-11-12)  Essential role of PI-3K, ERKs and calcium signal pathways in nickel-induced VEGF expression..  Molecular and cellular biochemistry,  279  ((1-2)): (35-43).  [PMID:16283513]
9. Huaibo Ma,Jeffrey L Petersen,Victor G Young,Gordon T Yee,Michael P Jensen.  (2011-03-29)  Solid-state spin crossover of Ni(II) in a bioinspired N3S2 ligand field..  Journal of the American Chemical Society,  133  ((15)): (5644-5647).  [PMID:21438640]
10. Jun Zhang,Jing Zhang,MengJie Li,YouJun Wu,YingYing Fan,Yang Zhou,LiLi Tan,ZhiHua Shao,HongJun Shi.  (2011-05-14)  Methylation of RAR-β2, RASSF1A, and CDKN2A genes induced by nickel subsulfide and nickel-carcinogenesis in rats..  Biomedical and environmental sciences : BES,  24  ((2)): (163-171).  [PMID:21565688]
11. Frank E Huggins,Kevin C Galbreath,Kurt E Eylands,Lisa L Van Loon,Jeremy A Olson,Edward J Zillioux,Stephen G Ward,Paul A Lynch,Paul Chu.  (2011-06-30)  Determination of nickel species in stack emissions from eight residual oil-fired utility steam-generating units..  Environmental science & technology,  45  ((14)): (6188-6195).  [PMID:21711052]
12. Kazimierz S Kasprzak,Bhalchandra A Diwan,Monika Z Kaczmarek,Daniel L Logsdon,Mathew J Fivash,Konstantin Salnikow.  (2011-09-01)  Effects of ascorbic acid on carcinogenicity and acute toxicity of nickel subsulfide, and on tumor transplants growth in gulonolactone oxidase knock-out mice and wild-type C57BL mice..  Toxicology and applied pharmacology,  257  ((1)): (32-37).  [PMID:21878346]
13. Chan Woo Lee,Seung-Deok Seo,Hoon Kee Park,Sangbaek Park,Hee Jo Song,Dong-Wan Kim,Kug Sun Hong.  (2015-01-15)  High-areal-capacity lithium storage of the Kirkendall effect-driven hollow hierarchical NiS(x) nanoarchitecture..  Nanoscale,  ((6)): (2790-2796).  [PMID:25585208]
14. S J Newsholme,D M Zimmerman.  (1997-11-05)  Immunohistochemical evaluation of chemically induced rhabdomyosarcomas in rats: diagnostic utility of MyoD1..  Toxicologic pathology,  25  ((5)): (470-474).  [PMID:9323836]
15. T Ohmori,K Okada,M Terada,R Tabei.  (1999-04-22)  Low susceptibility of specific inbred colonies of rats to nickel tumorigenesis in soft tissue..  Cancer letters,  136  ((1)): (53-58).  [PMID:10211939]
16. A Andrew,A Barchowsky.  (2000-09-23)  Nickel-induced plasminogen activator inhibitor-1 expression inhibits the fibrinolytic activity of human airway epithelial cells..  Toxicology and applied pharmacology,  168  ((1)): (50-57).  [PMID:11000099]
17. X Mao,T Kashii,R Hayashi,K Sassa,T Fujishita,M Maruyama,M Kobayashi,S Liu.  (2000-11-18)  Cloning of differentially expressed sequence tags from nickel-transformed human embryonic lung cells..  Cancer letters,  161  ((1)): (57-62).  [PMID:11078913]
18. A S Andrew,L R Klei,A Barchowsky.  (2001-08-16)  Nickel requires hypoxia-inducible factor-1 alpha, not redox signaling, to induce plasminogen activator inhibitor-1..  American journal of physiology. Lung cellular and molecular physiology,  281  ((3)): (L607-L615).  [PMID:11504687]
19. C Huang,J Li,M Costa,Z Zhang,S S Leonard,V Castranova,V Vallyathan,G Ju,X Shi.  (2001-11-24)  Hydrogen peroxide mediates activation of nuclear factor of activated T cells (NFAT) by nickel subsulfide..  Cancer research,  61  ((22)): (8051-8057).  [PMID:11719426]
20. Keisuke Ozaki,Joseph K Haseman,James R Hailey,Robert R Maronpot,Abraham Nyska.  (2002-04-13)  Association of adrenal pheochromocytoma and lung pathology in inhalation studies with particulate compounds in the male F344 rat--the National Toxicology Program experience..  Toxicologic pathology,  30  ((2)): (263-270).  [PMID:11950170]
21. Shosuke Kawanishi,Shinji Oikawa,Sumiko Inoue,Kohsuke Nishino.  (2002-11-12)  Distinct mechanisms of oxidative DNA damage induced by carcinogenic nickel subsulfide and nickel oxides..  Environmental health perspectives,  110 Suppl 5  (789-791).  [PMID:12426132]
22. Weiming Ouyang,Dongyun Zhang,Jingxia Li,Udit N Verma,Max Costa,Chuanshu Huang.  (2008-09-17)  Soluble and insoluble nickel compounds exert a differential inhibitory effect on cell growth through IKKalpha-dependent cyclin D1 down-regulation..  Journal of cellular physiology,  218  ((1)): (205-214).  [PMID:18792914]
23. Ke Li, Jun Xu, Chan Chen, Zhizhog Xie, Dan Liu, Deyu Qu, Haolin Tang, Qiang Wei, Qibo Deng, Junsheng Li, Ning Hu.  (2021)  Activating the hydrogen evolution activity of Pt electrode via synergistic interaction with NiS2.  JOURNAL OF COLLOID AND INTERFACE SCIENCE,  582  (591).  [PMID:32911407] [10.1016/j.jcis.2020.08.071]

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