基本描述

别名	甲基-β-CD \| MβCD
英文别名	MEBCD \| Methyl-β-CD \| Methyl-beta-cyclodextrin
规格或纯度	average Mn 1310
英文名称	Methyl-β-cyclodextrin（MβCD）
储存温度	室温
运输条件	常规运输
产品介绍	甲基-β-环糊精(MβCD)是一种大环化合物，可以与许多客体分子形成包合物。与母体β-环糊精相比，它在水溶液中呈现更高的溶解度以及更强的增溶和络合能力。MβCD可用于增强有机溶剂中的酶活性和枯草酶的对映选择性。应用: 甲基-β-环糊精可以用作：缓冲剂添加剂，通改良胶束电动毛细管色谱法（MEKC）结合激光诱导荧光检测有效分离氨基磷脂。流动相添加剂，用于常规和纳米液相色谱法（nano-LC）分析商业片剂制剂中的R,S-萘普生混合物。高效液相色谱法(HPLC)测定生物样品中分析物的分析标准品。毛细管电泳法分离药物制剂中瑞格列奈对映异构体的手性选择剂。甲基-β-环糊精是一种除胆固醇剂[7] 主要用于破坏脂筏结构。由于其对常用于膜蛋白化学的表面活性剂的高溶解度和亲和力，它还可以用于从蛋白质-脂质-表面活性剂三元混合物中去除表面活性剂以产生2D膜蛋白晶体。 Methyl-β-cyclodextrin (MβCD) is a macrocyclic compound that can form inclusion complexes with a number of guest molecules. It shows higher solubility in aqueous solutions and greater solubilizing and complexing power compared to the parent β-cyclodextrin. MβCD can be used to enhance the enzyme activity and enantioselectivity of subtilizing enzyme in organic solvents. Application: Methyl-β-cyclodextrin is a cholesterol-removing agent mainly used for lipid raft disruption.[4] It may also be used for detergent removal from protein-lipid-detergent ternary mixture to produce 2D membrane protein crystals due to its high solubility and affinity for detergents generally used in membrane protein chemistry. Methyl-β-cyclodextrin may be used as: A buffer additive for the effective separation of aminophospholipids by modified micellar electrokinetic capillary chromatography (MEKC) coupled with laser-induced fluorescence detection. A mobile phase additive for the analysis of R,S-naproxen mixtures in commercial tablet formulations by conventional and nano-liquid chromatography (nano-LC). An analytical standard for the determination of the analyte in biological samples by high performance liquid chromatography (HPLC). A chiral selector for the resolution of repaglinide enantiomers in pharmaceutical formulations by capillary electrophoresis.

名称和识别符

PubChem SID	488201479
分子类型	未知
Isomeric SMILES	CO[C@H]1[C@@H]([C@H]2[C@H](O[C@@H]1O[C@@H]3[C@H](O[C@@H]([C@H]([C@@H]3OC)OC)O[C@@H]4[C@H](O[C@@H]([C@H]([C@@H]4OC)OC)O[C@@H]5[C@H](O[C@@H]([C@H]([C@@H]5OC)OC)O[C@@H]6[C@H](O[C@@H]([C@H]([C@@H]6OC)OC)O[C@@H]7[C@H](O[C@@H]([C@H]([C@@H]7OC)OC)O[C@@H]8[C@H](O[C@H](O2)[C@H]([C@@H]8O)OC)CO)CO)CO)CO)CO)CO)CO)O
PubChem CID	51051622

化学和物理性质

溶解性	Soluble in water
密度	1.4
比旋光度	[α]25/D +159°, c = 1 in H2O
闪点(℉)	368.6 °F
闪点(℃)	63℃
熔点	180-182 °C
分子量	1303.300 g/mol
XLogP3	-8.600
氢键供体数Hydrogen Bond Donor Count	9
氢键受体数Hydrogen Bond Acceptor Count	35
可旋转键计数Rotatable Bond Count	19
精确质量Exact Mass	1302.56 Da
单同位素质量Monoisotopic Mass	1302.56 Da
拓扑极表面积Topological Polar Surface Area	422.000 Å²
重原子数Heavy Atom Count	89
形式电荷Formal Charge	0
复杂度Complexity	2050.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	35
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

WGK Germany	3
个人防护装备	Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter

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引用文献

1. Xin Wang, Jinshuang Hu, Hua Wei, Zihan Li, Jian Liu, Jie Zhang, Shenghong Yang. (2023) Ultra-fast solvent-free protocol remodels the large-scale synthesis of carbon dots for nucleolus-targeting and white light-emitting diodes. Journal of Colloid And Interface Science , 649 (-): (785–794). [10.1016/j.jcis.2023.06.171]
2. Yulin Mo, Yanjun Yang, Jingqi Zeng, Weikun Ma, Yuxin Guan, Jingxi Guo, Xiaochun Wu, Dingkun Liu, Liang Feng, Xiaobin Jia, Bing Yang. (2023) Enhancing the Biopharmacological Characteristics of Asperosaponin VI: Unveiling Dynamic Self-Assembly Phase Transitions in the Gastrointestinal Environment. International Journal of Nanomedicine, [PMID:38084126] [10.2147/IJN.S436372]
3. Yuhang Zhang, Fengrui Li, Guanhua Guo, Yue Xiu, Honglei Yan, Lixia Zhao, Shuang Gao, Fei Ye, Ying Fu. (2024) Preparation and characterization of betulin/methyl-beta-cyclodextrin inclusion complex electrospun nanofiber: Improving the properties of betulin. INDUSTRIAL CROPS AND PRODUCTS, 209 (117974). [10.1016/j.indcrop.2023.117974]
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5. Tao Wanjun, Xie Pei, Huang Chengyuan, Wang Ying, Huang Yu, Yin Zongning. (2023) Construction of PLGA nanoparticles modified with RWrNM and DLPC and their application in acute rhinosinusitis. Drug Delivery and Translational Research, (1-14). [PMID:37966678] [10.1007/s13346-023-01450-4]
6. Dan Yuan, Qi Li, Qibo Zhang, Feibai Zhou, Qiangzhong Zhao, Mouming Zhao. (2024) Enhanced curcumin transportation across epithelial barrier by mucus-permeable soy protein nanoparticles-mediated dual transcytosis pathways. FOOD CHEMISTRY, 437 (137771). [PMID:37897825] [10.1016/j.foodchem.2023.137771]
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8. Zhanlin Zhang, Hui Yan, Wenxiong Cao, Shuang Xie, Pan Ran, Kun Wei, Xiaohong Li. (2023) Ultrasound-Chargeable Persistent Luminescence Nanoparticles to Generate Self-Propelled Motion and Photothermal/NO Therapy for Synergistic Tumor Treatment. ACS Nano, [PMID:37515593] [10.1021/acsnano.3c04906]
9. Zhicheng Le, Qi Pan, Zepeng He, Hong Liu, Yi Shi, Lixin Liu, Zhijia Liu, Yuan Ping, Yongming Chen. (2023) Direct Cytosolic Delivery of Proteins and CRISPR-Cas9 Genome Editing by Gemini Amphiphiles via Non-Endocytic Translocation Pathways. ACS Central Science, [PMID:37521791] [10.1021/acscentsci.3c00207]
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12. Shengnan Huang, Chengzhi Song, Jinxin Miao, Xiali Zhu, Yongyan Jia, Yafei Liu, Dongjun Fu, Benyi Li, Mingsan Miao, Shaofeng Duan, Zhenzhong Zhang, Yurong Hu. (2023) Red blood cell membrane-coated functionalized Au nanocage as a biomimetic platform for improved MicroRNA delivery in hepatocellular carcinoma. INTERNATIONAL JOURNAL OF PHARMACEUTICS, 642 (123044). [PMID:37178790] [10.1016/j.ijpharm.2023.123044]
13. Xuan Nie, Wei You, Ze Zhang, Fan Gao, Xiao-Hong Zhou, Hai-Li Wang, Long-Hai Wang, Guang Chen, Chang-Hui Wang, Chun-Yan Hong, Qi Shao, Fei Wang, Lei Xia, Yang Li, Ye-Zi You. (2023) DPA-Zinc around Polyplexes Acts Like PEG to Reduce Protein Binding While Targeting Cancer Cells. Advanced Healthcare Materials, 12 (21): (2203252). [PMID:37154112] [10.1002/adhm.202203252]
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19. Wen-Juan Shen, Duo-Mei Tian, Le Fu, Biao Jin, Yu Liu, Yun-Sheng Xu, Yong-Bin Ye, Xiao-Bo Wang, Xiao-Jun Xu, Chun Tang, Fang-Ping Li, Chun-Fei Wang, Gang Wu, Le-Ping Yan. (2023) Elastin-Derived VGVAPG Fragment Decorated Cell-Penetrating Peptide with Improved Gene Delivery Efficacy. Pharmaceutics, 15 (2): (670). [PMID:36839992] [10.3390/pharmaceutics15020670]
20. Nini Xin, Dong Gao, Borui Su, Ting Zhou, Yuda Zhu, Chengheng Wu, Dan Wei, Jing Sun, Hongsong Fan. (2023) Orange-Emissive Carbon Dots with High Photostability for Mitochondrial Dynamics Tracking in Living Cells. ACS Sensors, 8 (3): (1161–1172). [PMID:36795996] [10.1021/acssensors.2c02451]
21. Zhiwei Shi, Weiping Li, Azhu Wang, Yuzhe Wang, Huishi Pi, Huicong Liu, Haining Chen, Pei Li, Xiaoyu Jiang. (2023) Inclusion Complexes of Photosensitizers with Cyclodextrins for Enhancing the Fabrication of Volume Grating. ACS Applied Materials & Interfaces, 15 (8): (11076–11083). [PMID:36790868] [10.1021/acsami.2c21905]
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23. Lei Kang, Lanjie Shi, Longfei Song, Xingpeng Guo. (2023) Facile fabrication of superhydrophobic porous materials using the water-based aza-Michael reaction for high-efficiency oil-water separation. SEPARATION AND PURIFICATION TECHNOLOGY, 308 (122880). [10.1016/j.seppur.2022.122880]
24. Li Fangyuan, Sun Heng, Ren Jiafeng, Zhang Bo, Hu Xi, Fang Chunyan, Lee Jiyoung, Gu Hongzhou, Ling Daishun. (2022) A nuclease-mimetic platinum nanozyme induces concurrent DNA platination and oxidative cleavage to overcome cancer drug resistance. Nature Communications, 13 (1): (1-16). [PMID:36450764] [10.1038/s41467-022-35022-w]
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41. Qiu-Ping Feng, Yu-Ting Zhu, Yi-Zhen Yuan, Wen-Jie Li, Hao-Han Yu, Meng-Yuan Hu, Su-Yun Xiang, Shu-Qin Yu. (2021) Oral administration co-delivery nanoparticles of docetaxel and bevacizumab for improving intestinal absorption and enhancing anticancer activity. Materials Science & Engineering C-Materials for Biological Applications, 124 (112039). [PMID:33947539] [10.1016/j.msec.2021.112039]
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