| 货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
|---|---|---|---|---|
| C294176-1g |
1g |
期货  |
|
| 英文别名 | [(IPr)AgCl] |
|---|---|
| 规格或纯度 | 99.95% metals basis |
| 英文名称 | Chloro[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]silver |
| 储存温度 | 室温 |
| 运输条件 | 常规运输 |
| 产品介绍 |
Product class M-C, Homogeneous Catalysts, N-Heterocyclic Carbene Ligands Reaction type Alkynylation, Allylic Alkylation, Cyclopropanation Chemical properties Chemical formula C27H36N2ClAg Empirical formula [(IPr)AgCl] Molecular weight 531.92 Metal Ag Theoretical metal content 20 Physical state powder Color Metal purity white 99.95 Applications & references Silver catalyzed alkene cyclopropanation.
Reference: Tetrah. 2009, 65, 1790 (DOI: 10.1016/j.tet.2008.10.114) Alkynylation of isatins with phenylacteylene in water.
Reference: Green Chem. 2011, 13, 549 (DOI: 10.1039/C0GC00807A) Allylic alkylation using in situ formed Pd(NHC)(phosphine) complexes.
Reference: J. Organomet. Chem. 2007, 692, 5754 (DOI:10.1016/j.jorganchem.2007.10.012) |
| 纯度 | ≥99.95% metals basis |
| INCHI | 1S/C27H36N2.Ag.ClH/c1-18(2)22-11-9-12-23(19(3)4)26(22)28-15-16-29(17-28)27-24(20(5)6)13-10-14-25(27)21(7)8;;/h9-16,18-21H,1-8H3;;1H/q;+1;/p-1 |
|---|---|
| InChi Key | GNVDTUAJUVJOFQ-UHFFFAOYSA-M |
| Smiles | CC(C)c1cccc(C(C)C)c1N2C=CN(\C2=Ag/Cl)c3c(cccc3C(C)C)C(C)C |
| Isomeric SMILES | CC(C)C1=C(C(=CC=C1)C(C)C)N2C=CN([C]2)C3=C(C=CC=C3C(C)C)C(C)C.Cl[Ag] |
| PubChem CID | 49788523 |
| 分子量 | 531.92 |
| 熔点 | 265-270 °C |
|---|
| WGK Germany | 3 |
|---|
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