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无水醋酸铜

    级别和纯度:
  • ≥98%
有货

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货号 (SKU) 包装规格 是否现货 价格 数量
C106650-25g
25g 现货 Stock Image
C106650-100g
100g 现货 Stock Image
C106650-500g
500g 现货 Stock Image
C106650-2.5kg
2.5kg 现货 Stock Image

基本描述

别名 乙酸铜
英文别名 Acetic acid, cupric salt | Acetic acid, copper salt | Crystals of venus | Cu(OAc)2 | diacetoxycopper | EC 205-553-3 | EINECS 205-553-3 | EINECS 257-974-7 | NSC 75796 | Cuprum aceticum 4 Special Order | copper (II)acetate | SY001104 | Crystallized verdigri
规格或纯度 ≥98%
英文名称 Cupric Acetate Anhydrous
储存温度 充氩
运输条件 常规运输
产品介绍

Copper(II) acetate is used in biochemical applications such as DNA extraction. Copper(II) complexes have been evaluated for anticancer, antibacterial and antifungal activities. Cu(II) complexes are known to cleave DNA; however, increased efficiency is seen in the presence of an oxidizer (often H2O2). Copper acetate exists in a dimeric structure in the solid state as well as in non-aqueous solution. Has been shown to bind the ribose hydroxyls of both purine and pyrimidine nucleosides. Popular methods for DNA extraction may be hindered by endogenous levels of polysaccharides, phenolics and other organic molecules; copper(II) acetate treatment has been shown to fix and remove tannins in samples from Pyrus (Pear) yielding high quality DNA.Used in biochemical applications such as DNA extraction

Copper(II) acetate is used in biochemical applications such as DNA extraction. Copper(II) complexes have been evaluated for anticancer, antibacterial and antifungal activities. Cu(II) complexes are known to cleave DNA; however, increased efficiency is seen in the presence of an oxidizer (often H2O2). Copper acetate exists in a dimeric structure in the solid state as well as in non-aqueous solution. Has been shown to bind the ribose hydroxyls of both purine and pyrimidine nucleosides. Popular methods for DNA extraction may be hindered by endogenous levels of polysaccharides, phenolics and other organic molecules; copper(II) acetate treatment has been shown to fix and remove tannins in samples from Pyrus (Pear) yielding high quality DNA.
Used in biochemical applications such as DNA extraction

纯度 ≥98%

名称和识别符

EC号 205-553-3
IIUPAC Name copper;diacetate
INCHI 1S/2C2H4O2.Cu/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
InChi Key OPQARKPSCNTWTJ-UHFFFAOYSA-L
Smiles CC(=O)[O-].CC(=O)[O-].[Cu+2]
Isomeric SMILES CC(=O)[O-].CC(=O)[O-].[Cu+2]
UN Number 3077
Packing Group III
分子量 181.63
Beilstein号 3595638
Reaxy-Rn 3595638
Reaxys-RN link address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=3595638&ln=

化学和物理性质

密度 1.068
敏感性 对湿度敏感
熔点 115°C
分子量 181.630 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count 0
氢键受体数Hydrogen Bond Acceptor Count 4
可旋转键计数Rotatable Bond Count 0
精确质量Exact Mass 180.956 Da
单同位素质量Monoisotopic Mass 180.956 Da
拓扑极表面积Topological Polar Surface Area 80.300 Ų
重原子数Heavy Atom Count 9
形式电荷Formal Charge 0
复杂度Complexity 25.500
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 3

安全和危险性(GHS)

象形图 GHS05,   GHS07,   GHS09
信号词 警告
危险声明

H302: 吞食有害

H314: 造成严重的皮肤灼伤和眼睛损伤

H400: 对水生生物有剧毒

H411: 对水生生物有毒并具有长期持续影响

预防措施声明

P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P264: 处理后要彻底洗手。

P270: 使用本产品时,请勿进食、饮水或吸烟。

P271: 仅在室外或通风良好的地方使用。

P273: 避免释放到环境中。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P321: 特殊处理(请参阅此标签上的...)。

P330: 漱口

P363: 再次使用之前,请清洗受污染的衣物。

P391: 收集溢出物

P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。

P302+P352: 如皮肤沾染:用水充分清洗。

P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。

P361+P364: 立即脱掉所有沾染的衣服,清洗后方可重新使用。

P405: 密闭存放

P403+P233: 存放在通风良好的地方。保持容器密闭。

P501: 将内容物/容器处理到。。。

P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。

P301+P316: 如果吞咽:立即寻求紧急医疗救助。

P301+P317: 如果被吞咽:请寻求医疗帮助。

P305+P354+P338: 如果进入眼睛:立即用水冲洗几分钟。取下隐形眼镜(如果有的话),并且操作简单。继续冲洗。

P317: 寻求紧急医疗救助。

P302+P361+P354: 如果接触皮肤:立即脱掉所有被污染的衣服。立即用水冲洗几分钟。

P316: 立即寻求紧急医疗救助。

P319: 如果你感到不适,请寻求医疗帮助。

WGK Germany 3
RTECS AG3480000
Class 9
个人防护装备 dust mask type N95 (US),Eyeshields,Gloves

质检证书(CoA,COO,BSE/TSE 和分析图谱)

C of A & Other Certificates(BSE/TSE, COO):
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找到25个结果

批号(Lot Number) 证书类型 货号
I2523072 分析证书 C106650
J2414653 分析证书 C106650
J2414654 分析证书 C106650
F2415150 分析证书 C106650
F2415157 分析证书 C106650
F2415205 分析证书 C106650
H2322171 分析证书 C106650
H2322172 分析证书 C106650
H2322173 分析证书 C106650
H2322174 分析证书 C106650
I2510074 分析证书 C106650
G2303444 分析证书 C106650
G2303445 分析证书 C106650
G2303448 分析证书 C106650
G2303457 分析证书 C106650
E2421083 分析证书 C106650
D23141236 分析证书 C106650
D23141237 分析证书 C106650
F2213493 分析证书 C106650
F2213486 分析证书 C106650
C2203096 分析证书 C106650
C2203097 分析证书 C106650
C2203099 分析证书 C106650
C2203279 分析证书 C106650
F2301050 分析证书 C106650

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技术文档和文章

点击化学
Click Chemistry
新药研发中的点击化学
铜(I)催化的叠氮化物-炔烃环加成(CuAAC)
Copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC)
点击化学中的应变烯烃反应
Reactions of strained alkenes in click chemistry
环张力促进的炔烃-硝酮环加成反应(SPANC)
点击化学的潜在应用
Potential Applications in Click Chemistry
Copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC)
Reactions of strained alkenes in click chemistry
Potential Applications in Click Chemistry
Click Chemistry
Click Chemistry in Drug Discovery
点击化学在化学连接和肽修饰中的应用
The application of click chemistry in chemical ligation and peptide modification
Click Chemistry in Drug Discovery
Reactions of strained alkenes in click chemistry
Copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC)
过硫酸铵
过氧化氢叔丁醇(TBHP)
tert-Butyl hydroperoxide, TBHP
tert-Butyl hydroperoxide, TBHP
tert-Butyl hydroperoxide, TBHP
tert-Butyl hydroperoxide, TBHP
tert-Butyl hydroperoxide, TBHP
tert-Butyl hydroperoxide, TBHP
tert-Butyl hydroperoxide, TBHP
tert-Butyl hydroperoxide, TBHP
tert-Butyl hydroperoxide, TBHP
tert-Butyl hydroperoxide, TBHP
tert-Butyl hydroperoxide, TBHP
tert-Butyl hydroperoxide, TBHP
甲基二乙氧基硅烷(DEMS)
Diethoxymethylsilane, DEMS
Diethoxymethylsilane, DEMS
Diethoxymethylsilane, DEMS
Diethoxymethylsilane, DEMS
Diethoxymethylsilane, DEMS
二甲氧基甲基硅烷(DMMS)
过氧化二叔丁基(DTBP)

此产品的引用文献

引用文献

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14. Yi-Chi Chien.  (2012-03-01)  Investigation of carbon tetrachloride destruction by copper acetate..  Journal of environmental quality,  41  ((2)): (449-453).  [PMID:22370408]
15. Qun Zhang,Xinyan Wang,Chuanjie Cheng,Rui Zhu,Nan Liu,Yuefei Hu.  (2012-03-06)  Copper(I) acetate-catalyzed azide-alkyne cycloaddition for highly efficient preparation of 1-(pyridin-2-yl)-1,2,3-triazoles..  Organic & biomolecular chemistry,  10  ((14)): (2847-2854).  [PMID:22388558]
16. Zhiyuan Chen,Liang Gao,Shengqing Ye,Qiuping Ding,Jie Wu.  (2012-03-17)  Silver triflate-copper(II) acetate cooperative catalysis in a cascade reaction for concise synthesis of 2-carbonyl H-pyrazolo[5,1-a]isoquinolines..  Chemical communications (Cambridge, England),  48  ((33)): (3975-3977).  [PMID:22421796]
17. Liang Li,Mi-Na Zhao,Zhi-Hui Ren,Jian-Li Li,Zheng-Hui Guan.  (2012-06-26)  Cu(OAc)2/TFA-promoted formal [3 + 3] cycloaddition/oxidation of enamines and enones for synthesis of multisubstituted aromatic amines..  Organic letters,  14  ((13)): (3506-3509).  [PMID:22724429]
18. John Mondal,Arindam Modak,Arghya Dutta,Sohini Basu,Shambhu Nath Jha,Dibyendu Bhattacharyya,Asim Bhaumik.  (2012-07-10)  One-pot thioetherification of aryl halides with thiourea and benzyl bromide in water catalyzed by Cu-grafted furfural imine-functionalized mesoporous SBA-15..  Chemical communications (Cambridge, England),  48  ((64)): (8000-8002).  [PMID:22772355]
19. Li Zhang,Yongliang Zhang,Xin Wang,Jingkang Shen.  (2013-01-08)  Efficient synthesis of a (Z)-3-methyleneisoindolin-1-one library using Cu(OAc)₂•H₂O/DBU under microwave irradiation..  Molecules (Basel, Switzerland),  18  ((1)): (654-665).  [PMID:23292328]
20. Dong Lei Wu,Wei Wang,Jing Hui Zhang,Hao Fu,Xiao Shu Lv,Xin Hua Xu.  (2013-01-30)  Preparation of mulberry branch biomass char and its usage in wastewater treatment..  Water environment research : a research publication of the Water Environment Federation,  84  ((11)): (2060-2069).  [PMID:23356022]
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23. Xinxia Wang,Jie Feng,Caihua Yu,Qingwu W Shen,Yizhen Wang.  (2015-04-01)  Alterations in oral [1-(14)C] 18:1n-9 distribution in lean wild-type and genetically obese (ob/ob) mice..  PloS one,  10  ((3)): (e0122028-e0122028).  [PMID:25826747]
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33. Lijia Yao, Bingquan Chen, Hailong Wu, Yuanjing Cui, Guodong Qian.  (2023)  Rational design of copper(I)-doped metal–organic frameworks as dual-functional nanocarriers for combined chemo–chemodynamic therapy.  Journal of Materials Chemistry B,  11  (44): (10632-10639).  [PMID:37910388] [10.1039/D3TB01869E]
34. Hui-Ping Yu, Xiao-Dong Bi, Yu-Jing He, Yuan-Yuan Cui, Cheng-Xiong Yang.  (2023)  Microporous Organic Network: Superhydrophobic Coating to Protect Metal–Organic Frameworks from Hydrolytic Degradation.  ACS Applied Materials & Interfaces,  15  (30): (36822–36830).  [PMID:37467423] [10.1021/acsami.3c08458]
35. Xue Zhang, Xue-Lei Tian, Yutian Qin, Jing Qiao, Fei Pan, Na Wu, Changxian Wang, Shanyu Zhao, Wei Liu, Jie Cui, Zhao Qian, Meiting Zhao, Jiurong Liu, Zhihui Zeng.  (2023)  Conductive Metal–Organic Frameworks with Tunable Dielectric Properties for Boosting Electromagnetic Wave Absorption.  ACS Nano,  17  (13): (12510–12518).  [PMID:37350557] [10.1021/acsnano.3c02170]
36. Renzhong Xue, Liuyang Zhao, Ziyang Chen, Binbin Cao, Chunyu Yuan, Yifan Xiao.  (2023)  Improved optical, dielectric, and nonlinear properties of CaCu3Ti4O12 thin films by chromium doping.  THIN SOLID FILMS,  779  (139940).  [10.1016/j.tsf.2023.139940]
37. Shaohui Zhang, Suying Liu, Jingwen Huang, Haikun Zhou, Xuanzhi Liu, Pengfei Tan, Haoyun Chen, Yili Liang, Jun Pan.  (2023)  Microbial synthesis of N, P co-doped carbon supported PtCu catalysts for oxygen reduction reaction.  Journal of Energy Chemistry,  84  (486).  [10.1016/j.jechem.2023.05.036]
38. Wenhao Bai, Tongtong Xuan, Haiyan Zhao, Haorui Dong, Xinru Cheng, Le Wang, Rong-Jun Xie.  (2023)  Perovskite Light-Emitting Diodes with an External Quantum Efficiency Exceeding 30%.  ADVANCED MATERIALS,  35  (39): (2302283).  [PMID:37246938] [10.1002/adma.202302283]
39. Wanying Gu, Yicheng Zeng, Yuan Deng, Pan Huang, Geyu Jin, Fangze Liu, Jing Wei, Hongbo Li.  (2023)  Colloidal Synthesis and Optical Properties of Cs2CuCl4 Nanocrystals.  Crystals,  13  (6): (864).  [10.3390/cryst13060864]
40. Sheng Li, Sidra Subhan, Liqin Zhou, Jing Li, Zhongxing Zhao, Zhenxia Zhao.  (2023)  High efficiency of toluene Ad-/Desorption on Thermal-conductive HKUST-1@BN nanosheets composite.  CHEMICAL ENGINEERING JOURNAL,  465  (142791).  [10.1016/j.cej.2023.142791]
41. Shaohui Zhang, Haikun Zhou, Xuanzhi Liu, Pengfei Tan, Hongwei Liu, Jun Pan.  (2023)  Highly stable PtCu3Auy nanowires-nanoparticles composite as efficient electrocatalysts towards oxygen reduction reaction.  JOURNAL OF POWER SOURCES,  567  (232924).  [10.1016/j.jpowsour.2023.232924]
42. Ziyuan Liu, Chunju He.  (2023)  Fabrication of amphiphilic self-healing coatings with high mechanical properties and their antifouling performance.  PROGRESS IN ORGANIC COATINGS,  175  (107371).  [10.1016/j.porgcoat.2022.107371]
43. Fuqiang Guo, Cheng Feng, Zheng Zhang, Lili Zhang, Chang Xu, Congting Zhang, Shuang Lin, Huanxing Wu, Baohua Zhang, Aersi Tabusi, Yineng Huang.  (2023)  A room-temperature NO2 sensor based on Ti3C2TX MXene modified with sphere-like CuO.  SENSORS AND ACTUATORS B-CHEMICAL,  375  (132885).  [10.1016/j.snb.2022.132885]
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