4-丙烯酰吗啉

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COA

级别和纯度:

≥98%(GC)
含稳定剂MEHQ

CAS编号: 5117-12-4
分子式: C₇H₁₁NO₂
分子量: 141.17
MDL号: MFCD00047413
PubChem编号: 98723
PubChem SID: 488187143

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货号 (SKU)	包装规格	是否现货
A151729-5ml	5ml	现货
A151729-25ml	25ml	现货
A151729-100ml	100ml	现货
A151729-500ml	500ml	现货
A151729-2.5L	2.5L	现货

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六元杂环化合物 (1701) 吗啉类 (213)

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基本描述

别名	4-甲氧基苯酚稳定剂 \| 1-吗啉代丙-2-烯-1-酮 \| 4-(1-氧代-2-丙烯基)吗啉 \| 1-(吗啉-4-基)丙烯酮 \| 4-丙烯酰基吗啉
英文别名	NCGC00256280-01 \| NSC162221 \| NSC-162221 \| acryloylmorpholine \| K0Y58P61JA \| 4-Acryloylmorpholine (stabilized with MEHQ) \| 4-Acryloylmorpholine, 97%, contains 1,000 ppm monomethyl ether hydroquinone as inhibitor \| Tox21_301658 \| ACRYLOYL MORPHOLINE \| N-Ac
规格或纯度	≥98%(GC), 含稳定剂MEHQ
英文名称	4-Acryloylmorpholine
储存温度	2-8°C储存
运输条件	冰袋运输
产品介绍	4-丙烯酰吗啉是一种丙烯酸酯单体，在聚合物工业中广泛用作交联剂。它用于形成三维聚合物网络，增强材料的机械强度、稳定性和耐久性。丙烯酰吗啉中的吗啉部分使分子具有亲水性，促进其在粘合剂、生物相容性涂层和药物输送系统领域的应用。它还用作反应性单体，合成用于药物输送的水凝胶、用于3D生物打印和显示设备的光固化材料和显示装置。用途 4-丙烯酰吗啉可在以下反应过程中用作单体： RAFT聚合法合成多嵌段共聚物。这些功能性嵌段共聚物在医学、能源和纳米技术领域都有应用。光聚合和交联法制备有机凝胶电极框架。聚合和交联催化剂。这可用于制造具有出色透明度、可拉伸性和界面粘附性的摩擦纳米发电机。用于打印热塑性3D组织支架。ACMO可溶于水，粘度极低，且具有表面氧阻聚作用，在高速露天打印过程中可促进液体快速流动。 4-Acryloylmorpholine is an acrylate monomer widely used as a crosslinking agent in the polymer industry. It is used to form three-dimensional polymer networks to enhance the mechanical strength, stability, and durability of materials. The morpholine moiety in acryloylmorpholine imparts hydrophilicity to the molecule facilitating its applications in the field of adhesives, biocompatible coatings, and drug delivery systems. It is also used as a reactive monomer to synthesize hydrogels for drug delivery, photocurable materials for 3D bioprinting and display devices. Purpose 4-Acryloylmorpholine can be used as a monomer: To synthesize multiblock copolymers via RAFT polymerization. These functional block copolymers find application in the fields of medicine, energy, and nanotechnology. To prepare organogel electrode frame via photopolymerization and cross-linking. This can be used to fabricate triboelectric nanogenerators with excellent transparency, stretchability, and interface adhesion. For printing thermoplastic 3D tissue scaffolds. ACMO′s water solubility,and remarkably low viscosity, combined with surface oxygen inhibition, promoteswift liquid flow during high-speed open-air printing.
纯度	≥98%(GC)

名称和识别符

PubChem SID	488187143
分子类型	小分子
IIUPAC Name	1-morpholin-4-ylprop-2-en-1-one
INCHI	1S/C7H11NO2/c1-2-7(9)8-3-5-10-6-4-8/h2H,1,3-6H2
InChi Key	XLPJNCYCZORXHG-UHFFFAOYSA-N
Smiles	C=CC(=O)N1CCOCC1
Isomeric SMILES	C=CC(=O)N1CCOCC1
分子量	141.17
Reaxy-Rn	119302
Reaxys-RN link address	https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=119302&ln=

化学和物理性质

溶解性	Soluble in chloroform, toluene, Acetone, alcohol, benzene
密度	1.122
敏感性	对光敏感
折光率	1.512
闪点(℉)	260°F
闪点(℃)	127°C
沸点	165°C/16mmHg
熔点	-35 °C
分子量	141.170 g/mol
XLogP3	-0.100
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	2
可旋转键计数Rotatable Bond Count	1
精确质量Exact Mass	141.079 Da
单同位素质量Monoisotopic Mass	141.079 Da
拓扑极表面积Topological Polar Surface Area	29.500 Å²
重原子数Heavy Atom Count	10
形式电荷Formal Charge	0
复杂度Complexity	139.000
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

象形图	GHS05, GHS07, GHS08
信号词	危险

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F2512114	分析证书	A151729
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F2512134	分析证书	A151729
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E2421481	分析证书	A151729
K2303093	分析证书	A151729
K2303094	分析证书	A151729
K2303102	分析证书	A151729
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C2426032	分析证书	A151729
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G2308469	分析证书	A151729
D2325312	分析证书	A151729
D2325313	分析证书	A151729
D2325316	分析证书	A151729
A1914062	分析证书	A151729
K2222323	分析证书	A151729
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引用文献

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2. Dalong Sun, Yang Yang, Wenjing Ma, Shuangxiang Ye, Hao Zhang, Jiang Zhang, Bin Yang. (2023) Heat-Resistant Hydrogel for Temporary Plugging in High-Temperature and High-Pressure Fractured Reservoirs. ACS Applied Polymer Materials, 5 (10): (7746–7754). [10.1021/acsapm.3c00901]
3. Yujie Yang, Xin Xu, Zhiqiang Li, Xinle Yao, Dongqing Kang, Yaozhong Lu, Yanbin Wang, Yuxiong Guo, Xiaolong Wang. (2023) Synthesis and properties of vat photopolymerization 3D-printing benzoxazine. MATERIALS LETTERS, 345 (134448). [10.1016/j.matlet.2023.134448]
4. Qian Zhou, Tengjiao Wang, Kunpeng Li, Shanyu Zhang, Kun Wang, Weilin Hong, Rongjun Liu, Peng Li. (2023) Biofilm microenvironment-responsive polymeric CO releasing micelles for enhanced amikacin efficacy. JOURNAL OF CONTROLLED RELEASE, 357 (561). [PMID:37076015] [10.1016/j.jconrel.2023.04.025]
5. Baimei Dai, Peng Xu, Mingbiao Xu, Qisheng Jiang, Qinglin Liu, Siwei Wang. (2023) Synthesis and plugging effect of inverse emulsion polymerization microspheres (OPME) for oil-based drilling fluids. Arabian Journal of Chemistry, 16 (104577). [10.1016/j.arabjc.2023.104577]
6. Titao Jing, Shuchang Wang, Haiyuan Yuan, Yujue Yang, Ming Xue, Bingang Xu. (2023) Interfacial Roughness Enhanced Gel/Elastomer Interfacial Bonding Enables Robust and Stretchable Triboelectric Nanogenerator for Reliable Energy Harvesting. Small, 19 (12): (2206528). [PMID:36587974] [10.1002/smll.202206528]
7. Shenglong Shi, Jinsheng Sun, Kaihe Lv, Qingzhi Wen, Yingrui Bai, Jingping Liu, Xianbin Huang, Jintang Wang, Jiafeng Jin, Jian Li. (2023) Preparation and Performance Evaluation of a Variable Viscosity Friction Reducer Suspension with High Salt Tolerance and Low Damage. ENERGY & FUELS, 37 (2): (993–1005). [10.1021/acs.energyfuels.2c03494]
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9. Shenglong Shi, Jinsheng Sun, Kaihe Lv, Jingping Liu, Yingrui Bai, Jintang Wang, Xianbin Huang, Jiafeng Jin, Jian Li. (2022) Comparative Studies on Thickeners as Hydraulic Fracturing Fluids: Suspension versus Powder. Gels, 8 (11): (722). [PMID:36354629] [10.3390/gels8110722]
10. Wenpeng Zhao, Yuan Li, Jian Hu, Xianqi Feng, Hao Zhang, Jun Xu, Shouke Yan. (2023) Mechanically robust, instant self-healing polymers towards elastic entropy driven artificial muscles. CHEMICAL ENGINEERING JOURNAL, 454 (140100). [10.1016/j.cej.2022.140100]
11. Feifan Sheng, Bo Zhang, Yihan Zhang, Yanyan Li, Renwei Cheng, Chuanhui Wei, Chuan Ning, Kai Dong, Zhong Lin Wang. (2022) Ultrastretchable Organogel/Silicone Fiber-Helical Sensors for Self-Powered Implantable Ligament Strain Monitoring. ACS Nano, 16 (7): (10958–10967). [PMID:35775629] [10.1021/acsnano.2c03365]
12. Wenpeng Zhao, Zixiang Zhang, Jian Hu, Xianqi Feng, Jun Xu, Yumin Wu, Shouke Yan. (2022) Robust and ultra-fast self-healing elastomers with hierarchically anisotropic structures and used for wearable sensors. CHEMICAL ENGINEERING JOURNAL, 446 (137305). [10.1016/j.cej.2022.137305]
13. Xu Jun, Zhang Zixiang, Nie YongJia, Liu Yanxia, Fan Yue, Zhao Wenpeng, Feng Xianqi. (2022) Dual physical cross-linked self-healing elastomer for the triple shape memory. JOURNAL OF MATERIALS SCIENCE, 57 (24): (11430-11442). [10.1007/s10853-022-07243-3]
14. Zhuo Sun, Yahui Lu, Qian Zhao, Jingjun Wu. (2022) A new stereolithographic 3D printing strategy for hydrogels with a large mechanical tunability and self-weldability. Additive Manufacturing, 50 (102563). [10.1016/j.addma.2021.102563]
15. Lingyun Wang, Yu Wang, Su Yang, Xiaoming Tao, Yunlong Zi, Walid A. Daoud. (2022) Solvent-free adhesive ionic elastomer for multifunctional stretchable electronics. Nano Energy, 91 (106611). [10.1016/j.nanoen.2021.106611]
16. Jiazhou Jin, Shanshan Dai, Xiaojiang Li, Ya Liu, Hongsheng Lu. (2021) pH-Switchable Latexes Based on the Nonionic Amphiphilic Diblock Copolymer with a Chargeable End-Group on the Core-Forming Block. LANGMUIR, 37 (20): (6123–6131). [PMID:33989002] [10.1021/acs.langmuir.1c00095]
17. Wenpeng Zhao, Yaoyao Liu, Can Zhao, Xinyi Shi, Xianqi Feng, Jun Xu, Shouguo Wang, Yumin Wu, Shouke Yan. (2021) A fast self-healable and stretchable conductor based on hierarchical wrinkled structure for flexible electronics. COMPOSITES SCIENCE AND TECHNOLOGY, 211 (108834). [10.1016/j.compscitech.2021.108834]
18. Wenpeng Zhao, Yaoyao Liu, Zixiang Zhang, Xianqi Feng, Hong Xu, Jun Xu, Jian Hu, Shouguo Wang, Yumin Wu, Shouke Yan. (2020) High-Strength, Fast Self-Healing, Aging-Insensitive Elastomers with Shape Memory Effect. ACS Applied Materials & Interfaces, 12 (31): (35445–35452). [PMID:32643374] [10.1021/acsami.0c09045]
19. Ji Jingqi, Zhao Jianqing, Ke Yangchuan. (2020) In situ fabrication of graphene-scaffold poly(acrylamide-acrylic acid-4-acryloylmorpholine) microspheres as a novel plugging agent for profile control. JOURNAL OF MATERIALS SCIENCE, 55 (29): (14137-14152). [10.1007/s10853-020-05018-2]
20. Yangyang Yan, Chen Gao, Jianjun Li, Tao Zhang, Guang Yang, Zhongkai Wang, Zan Hua. (2020) Modulating Morphologies and Surface Properties of Nanoparticles from Cellulose-Grafted Bottlebrush Copolymers Using Complementary Hydrogen-Bonding between Nucleobases. BIOMACROMOLECULES, 21 (2): (613–620). [PMID:31841316] [10.1021/acs.biomac.9b01345]
21. Jia Gao, Yilin Wu, Jiuyun Cui, Xiuling Wu, Minjia Meng, Chunxiang Li, Li Yan, Shi Zhou, Lili Yang, Yongsheng Yan. (2018) Bioinspired synthesis of multi-walled carbon nanotubes based enoxacin-imprinted nanocomposite membranes with excellent antifouling and selective separation properties. Journal of the Taiwan Institute of Chemical Engineers, 91 (468). [10.1016/j.jtice.2018.05.003]
22. Lingmei Jiang, Haoran Liu, Kuanyu Yuan, Guangsheng Zhang, Changhong Xiao, Chenghao Wang, Lishuai Zong, Jinyan Wang, Xigao Jian. (2024) Construction of fluorinated hyperbranched polyaryletherketone-based UV-cured films with low dielectric and enhanced mechanical properties. POLYMER, 299 (126902). [10.1016/j.polymer.2024.126902]
23. Quanyang Wang, Jing Cai, Jiannan Wang, Chenghua Zhou, Xinxin Wen, Jiang Zhang, Hui Mao. (2024) Development and Application of the Anti-High-Temperature Delayed Crosslinking Polymer as a Gel Plugging Additive for Drilling Fluid. Gels, 10 (1): (73). [PMID:38247795] [10.3390/gels10010073]
24. Xu Jun, Zhu Lei, Feng Xian-Qi, Sui Cong, Zhao Wen-Peng, Yan Shou-Ke. (2024) Effect of Phase Separation Size on the Properties of Self-healing Elastomer. CHINESE JOURNAL OF POLYMER SCIENCE, 42 (6): (798-804). [10.1007/s10118-024-3097-5]
25. Dong-Yin Wang, Chang-Feng Chen, Fei Ju, Yang-Chuan Ke. (2024) High-temperature resistant polymer nanocomposites with exfoliated organic-modified montmorillonite nanosheets strongly adsorbed on polymer chains. Petroleum Science, [10.1016/j.petsci.2024.07.006]
26. Yibo Xu, Shirong Wang, Hongli Liu, Xianggao Li. (2024) Microencapsulated Perovskite Crystals via In Situ Permeation Growth from Polymer Microencapsulation-Expansion-Contraction Strategy: Advancing a Record Long-Term Stability beyond 10 000 h for Perovskite Solar Cells. ADVANCED MATERIALS, (2313080). [PMID:38242543] [10.1002/adma.202313080]
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28. Enhui He, Chen Chen, Zheng Wang, Xuefeng Yan, Liangmin Yu. (2024) Novel post-functionalized polymer microspheres containing capsaicin as reversed-phase chromatography stationary phase separation for hydrophilic compounds. MICROCHEMICAL JOURNAL, 201 (110606). [10.1016/j.microc.2024.110606]
29. Chaoyu Liang, Jin Huang, Hongxiao Gong, Dongqiao Bai, Yunna Pu, Jianjun Wang, Pengbing Zhao. (2024) Research on material jetting fabrication and dielectric constant calculation of LTCC based on silica-borosilicate glass. Materials Today Communications, 40 (109741). [10.1016/j.mtcomm.2024.109741]
30. Yuting Tian, Weining Liu, Jun Hu, Zhiwei Li, Xiaoying Xin, Guodong Fu. (2024) Synthesis of highly transparent and fast-responding photochromic coating by template method with space-limited domains. CHEMICAL ENGINEERING JOURNAL, 500 (156961). [10.1016/j.cej.2024.156961]

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