基本描述

别名	硫化锑(III)
英文别名	EC 215-713-4 \| HSDB 1604 \| NSC 96581 \| Stibnite \| Antimony sulphide black \| Antimony(III) sulfide, 99.995% trace metals basis \| C.I. 77060 \| UNII-F79059A38U \| Black antimony \| DTXSID6030732 \| MFCD00011217 \| FT-0622437 \| Antimony trisulfide colloid \| Antimony trisulfide,black \| BAA34
规格或纯度	≥99.9% metals basis
英文名称	Amtimony sulfide
应用	橡胶硫化剂。焰火、玻璃、炸药、油漆颜料的制造。
运输条件	常规运输
产品介绍	露置空气中逐渐氧化。亦溶于不挥发氢氧化碱溶液中，溶于浓盐酸并放出硫化氢，不溶于水。纯三硫化二锑为黄红色无定形粉末，不溶于水和醋酸，溶于浓盐酸、醇、硫化铵和硫化钾溶液。烟花爆竹行业所用硫化锑为辉锑矿矿石粉加工而成，为黑色或灰黑色粉末，有金属光泽，不溶于水，具强还原性。有毒，最小致死量(大鼠，腹腔)1000mg/kg。橡胶硫化剂。焰火、玻璃、炸药、油漆颜料的制造。
纯度	≥99.9% metals basis

名称和识别符

PubChem SID	488199406
EC号	215-713-4
IIUPAC Name	sulfanylidene(sulfanylidenestibanylsulfanyl)stibane
INCHI	1S/3S.2Sb
InChi Key	IHBMMJGTJFPEQY-UHFFFAOYSA-N
Smiles	S=[Sb]S[Sb]=S
Isomeric SMILES	S=[Sb]S[Sb]=S
PubChem CID	16685273
UN Number	1549
Packing Group	III
分子量	339.72

化学和物理性质

密度	4.562
折光率	3.194
熔点	550°C
分子量	339.700 g/mol
XLogP3
氢键供体数Hydrogen Bond Donor Count	0
氢键受体数Hydrogen Bond Acceptor Count	3
可旋转键计数Rotatable Bond Count	0
精确质量Exact Mass	339.724 Da
单同位素质量Monoisotopic Mass	337.724 Da
拓扑极表面积Topological Polar Surface Area	89.500 Å²
重原子数Heavy Atom Count	5
形式电荷Formal Charge	0
复杂度Complexity	34.200
同位素原子数Isotope Atom Count	0
定义的原子立体中心计数Defined Atom Stereocenter Count	0
未定义的原子立体中心计数Undefined Atom Stereocenter Count	0
定义的键立体中心计数Defined Bond Stereocenter Count	0
未定义的键立体中心计数Undefined Bond Stereocenter Count	0
所有立体化学键的总数The total count of all stereochemical bonds	0
共价键合单元计数Covalently-Bonded Unit Count	1

安全和危险性（GHS）

一般危化品	一般危化品
象形图	GHS07, GHS09
信号词	警告
危险声明	H319: 引起严重眼睛刺激 H351: 怀疑引起遗传缺陷 H372: 通过长时间或反复暴露对器官造成损害 H411: 对水生生物有毒并具有长期持续影响
预防措施声明	P201: 使用前获取特殊说明 P202: 在阅读并理解所有安全预防措施之前，不要进行操作。 P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P264: 处理后要彻底洗手。 P270: 使用本产品时，请勿进食、饮水或吸烟。 P273: 避免释放到环境中。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P391: 收集溢出物 P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。 P308+P313: 如接触到或有疑虑：求医/就诊。 P337+P313: 如仍觉眼刺激：求医/就诊。 P405: 密闭存放 P501: 将内容物/容器处理到。。。
WGK Germany	2
Class	6.1
个人防护装备	dust mask type N95 (US), Eyeshields, Gloves

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批号(Lot Number)	证书类型	货号
J2517268	分析证书	A119485
I2512156	分析证书	A119485
I2512157	分析证书	A119485
H2515207	分析证书	A119485
H2515204	分析证书	A119485
G2510158	分析证书	A119485
G2510160	分析证书	A119485
I2320081	分析证书	A119485
D2511031	分析证书	A119485
I2320083	分析证书	A119485
I2320085	分析证书	A119485
I2320089	分析证书	A119485
C2301561	分析证书	A119485
C2301562	分析证书	A119485
L2220049	分析证书	A119485
K2230961	分析证书	A119485
I1821058	分析证书	A119485
B1913075	分析证书	A119485
F2223086	分析证书	A119485

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此产品的引用文献

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引用文献

1. Zhihui Ma, Jie Shi, Di Wu, Dishuang Chen, Shuai Shang, Xuanhui Qu, Ping Li. (2023) Sn-doped thioantimonate superionic conductors with high air stability and enhanced Li-ion conduction for all-solid-state lithium batteries. Journal of Materials Chemistry A, 11 (43): (23342-23353). [10.1039/D3TA04730J]
2. Hui Deng, Zekun Chen, Weihao Xie, Muhammad Ishaq, Kefei Wu, Xinxin Feng, Yubin Kang, Weihuang Wang, Shuying Cheng. (2023) Bulk Defect Passivation for Full-Inorganic Sb2S3 Solar Cells by Sulfur-Atmosphere Recrystallization Process. Solar RRL, 7 (19): (2300482). [10.1002/solr.202300482]
3. Jinzhao Zou, Shizhuan Xu, Jian Chen, Peng Wang, Chao Yan, Changqing Cao, Yan You, Junqiang Lu, Libing Zhu, Zhiyong Zhu, Jun Lin. (2023) Effects of spark plasma sintering parameters on the microstructure of U3Si2 pellets. JOURNAL OF NUCLEAR MATERIALS, 585 (154649). [10.1016/j.jnucmat.2023.154649]
4. Ying Chu, Peng Wang, Yihong Ding, Jie Lin, Xinxin Zhu, Shiqiang Zhao, Huile Jin, Tianbiao Zeng. (2023) High-Capacity Sb/Fe2S3 Sodium-Ion Battery Anodes Fabricated by a One-Step Redox Reaction, Followed by Ball Milling with Graphite. ACS Applied Materials & Interfaces, 15 (20): (24354–24365). [PMID:37167087] [10.1021/acsami.3c01223]
5. Huaxiao Xie, Pan Deng, Zhentao Zhou, Heng Xiong, Xiumin Chen, Bin Yang, Baoqiang Xu. (2023) Exploring the vacuum distillation mechanism of PbS and Sb2S3 from ab initio and experiments perspective. JOURNAL OF MOLECULAR STRUCTURE, 1287 (135686). [10.1016/j.molstruc.2023.135686]
6. Zhaowang Dong, Hanning Liu, Xueyi Guo, Heng Xiong, Bin Yang, Baoqiang Xu. (2023) Volatilization kinetics and thermodynamic stability of antimony sulfide under vacuum conditions. VACUUM, 213 (112119). [10.1016/j.vacuum.2023.112119]
7. Peng Wang, Yihong Ding, Ying Chu, Xinxin Zhu, Jie Lin, Lixiong Shao, Tianbiao Zeng. (2023) Nano FeSb2S4 Anchored on Exfoliated Graphite for Sodium-Ion Battery Anode via a Two-Step Fabrication. ENERGY & FUELS, 37 (7): (5577–5585). [10.1021/acs.energyfuels.3c00106]
8. Huaxiao Xie, Zhentao Zhou, Heng Xiong, Xiumin Chen, Pan Deng, Yizhao Wang, Huan Yang, Chaosong Meng. (2023) Theoretical calculation and experimental study on the separation mechanism of PbS-Sb2S3. JOURNAL OF MOLECULAR STRUCTURE, 1273 (134327). [10.1016/j.molstruc.2022.134327]
9. Xiao Lin, Hui Deng, Yi Jia, Zhixu Wu, Yong Xia, Xingjian Wang, Siwei Chen, Yingshun Cheng, Qiao Zheng, Yunfeng Lai, Shuying Cheng. (2022) Self-Powered Sb2S3 Thin-Film Photodetectors with High Detectivity for Weak Light Signal Detection. ACS Applied Materials & Interfaces, 14 (10): (12385–12394). [PMID:35234027] [10.1021/acsami.1c25256]
10. Zhu Qiang, Yang Jianguang, Tang Chaobo, Nan Tianxiang, Ding Ruize, Liu Jiang. (2022) Electroreduction of Antimony Sulfide Enhanced by Nitrogen Bottom Blowing in Molten NaCl-KCl-Na2S. JOM, 74 (5): (1889-1899). [10.1007/s11837-021-05148-1]
11. Hui Deng, Siwei Chen, Muhammad Ishaq, Yingshun Cheng, Quanzhen Sun, Xiao Lin, Qiao Zheng, Caixia Zhang, Shuying Cheng. (2022) Efficient All-Inorganic Sb2S3 Solar Cells with Matched Energy Levels Using Sb2Se3 as Hole Transport Layers. Solar RRL, 6 (4): (2101017). [10.1002/solr.202101017]
12. Yi Jia, Hui Deng, Xiao Lin, Shenzhong Chen, Yong Xia, Zhixu Wu, Jinling Yu, Shuying Cheng, Yunfeng Lai. (2021) Depleted Sb2S3 Thin Film Photoconductive Detectors with Fast Response Speed and High Polarization Sensitivity. Advanced Materials Interfaces, 9 (2): (2101504). [10.1002/admi.202101504]
13. Wei Weng, Gaozhan Liu, Lin Shen, Xiayin Yao. (2021) High ionic conductivity and stable phase Na11.5Sn2Sb0.5Ti0.5S12 for all-solid-state sodium batteries. JOURNAL OF POWER SOURCES, 512 (230485). [10.1016/j.jpowsour.2021.230485]
14. Chenhui Liu, Pengfei Zhao, Xiongjin Zhu, C. Srinivasakannan, Minghong Chen, Mengping Zhang. (2021) A novel production method of antimony trioxide from stibnite concentrate and the dielectric properties of antimony sulfide with different desulfurizer. MINERALS ENGINEERING, 171 (107097). [10.1016/j.mineng.2021.107097]
15. Muge Shele, Xinyu Tian, Menghe Baiyin. (2021) Solvothermal synthesis and properties of three antimony chalcogenides containing transition metal zinc. JOURNAL OF SOLID STATE CHEMISTRY, 302 (122401). [10.1016/j.jssc.2021.122401]
16. Yun Li, Haotian Xue, Pekka Taskinen, Ari Jokilaakso, Chaobo Tang, Wei Jin, Minna Rämä, Yongming Chen, Shenghai Yang. (2021) Clean antimony production from stibnite concentrate with goethite residue co-treatment for zinc, iron, sulfur conservation. Journal of Cleaner Production, 313 (127847). [10.1016/j.jclepro.2021.127847]
17. Li Xiang, Chaoyang Liu, Deng Liu, Liyuan Ma, Xuan Qiu, Hongmei Wang, Xiaolu Lu. (2022) Antimony transformation and mobilization from stibnite by an antimonite oxidizing bacterium Bosea sp. AS-1. Journal of Environmental Sciences, 111 (273). [PMID:34949357] [10.1016/j.jes.2021.03.042]
18. Muhammad Ishaq, Shuo Chen, Umar Farooq, Muhammad Azam, Hui Deng, Zheng-Hua Su, Zhuang-Hao Zheng, Ping Fan, Hai-Sheng Song, Guang-Xing Liang. (2020) High Open-Circuit Voltage in Full-Inorganic Sb2S3 Solar Cell via Modified Zn-Doped TiO2 Electron Transport Layer. Solar RRL, 4 (12): (2000551). [10.1002/solr.202000551]
19. Yun Li, Haotian Xue, Pekka Taskinen, Shenghai Yang, Chaobo Tang, Wei Jin, Yongming Chen, Ari Jokilaakso. (2020) Sustainable phase-conversion method for antimony extraction and sulfur conservation and waste treatment at low temperature. Journal of Cleaner Production, 268 (121950). [10.1016/j.jclepro.2020.121950]
20. Prakash C. Loni, Mengxiaojun Wu, Weiqi Wang, Hongmei Wang, Liyuan Ma, Chaoyang Liu, Yuyang Song, Olli H Tuovinen. (2020) Mechanism of microbial dissolution and oxidation of antimony in stibnite under ambient conditions. JOURNAL OF HAZARDOUS MATERIALS, 385 (121561). [PMID:31740307] [10.1016/j.jhazmat.2019.121561]
21. Muhammad Ishaq, Hui Deng, Umar Farooq, Huan Zhang, Xiaokun Yang, Usman Ali Shah, Haisheng Song. (2019) Efficient Copper-Doped Antimony Sulfide Thin-Film Solar Cells via Coevaporation Method. Solar RRL, 3 (12): (1900305). [10.1002/solr.201900305]
22. Hui Deng, Yiyu Zeng, Muhammad Ishaq, Shengjie Yuan, Huan Zhang, Xiaokun Yang, Mingming Hou, Umar Farooq, Jialiang Huang, Kaiwen Sun, Richard Webster, Hao Wu, Zhenhua Chen, Fei Yi, Haisheng Song, Xiaojing Hao, Jiang Tang. (2019) Quasiepitaxy Strategy for Efficient Full-Inorganic Sb2S3 Solar Cells. ADVANCED FUNCTIONAL MATERIALS, 29 (31): (1901720). [10.1002/adfm.201901720]
23. Yuxuan Liu, Zhongchen Lu, Jie Cui, Hui Liu, Jun Liu, Renzong Hu, Min Zhu. (2019) Plasma milling modified Sb2S3-graphite nanocomposite as a highly reversible alloying-conversion anode material for lithium storage. ELECTROCHIMICA ACTA, 310 (26). [10.1016/j.electacta.2019.04.104]
24. Guoxing Pan, Dongxiao Wang, Shoushuai Gao, Peng Gao, Qiang Sun, Xingjiang Liu, Zhiqiang Zhou, Yun Sun, Yi Zhang. (2019) Substrate structured Sb2S3 thin film solar cells fabricated by rapid thermal evaporation method. SOLAR ENERGY, 182 (64). [10.1016/j.solener.2019.02.014]
25. Yi Huang, Xiaowen Wu, Sadeh Beysen. (2019) Investigation on two new antimony-based quaternary chalcogenides: Na6CdSb4S10 and Na3CdSbSe4. NEW JOURNAL OF CHEMISTRY, 43 (8): (3350-3356). [10.1039/C8NJ04072A]
26. Huiyun Guo, Wenlong Hou, Jingkai Yang, Lan Yu, Bo Liang, Haiquan Zhang. (2017) A Novel Chemical Sensor Based on Sb2S3 Film for Highly Sensitive Detection of Hydrazine. ELECTROANALYSIS, 29 (12): (2737-2743). [10.1002/elan.201700452]
27. Guo Huiyun, Hou Wenlong, Liang Bo, Zhang Haiquan. (2017) Fabrication and Photocatalytic Performance of Sb2S3 Film/ITO Combination. CATALYSIS LETTERS, 147 (10): (2592-2599). [10.1007/s10562-017-2154-x]
28. Shengjie Yuan, Hui Deng, Dongdong Dong, Xiaokun Yang, Keke Qiao, Chao Hu, Huaibing Song, Haisheng Song, Zhubing He, Jiang Tang. (2016) Efficient planar antimony sulfide thin film photovoltaics with large grain and preferential growth. SOLAR ENERGY MATERIALS AND SOLAR CELLS, 157 (887). [10.1016/j.solmat.2016.07.050]
29. Chang Liu, Peipei Hou, Wenxiang Chai, Jiawei Tian, Xuerong Zheng, Yaying Shen, Mingjia Zhi, Chunmei Zhou, Yi Liu. (2016) Hydrazine-hydrothermal syntheses, characterizations and photoelectrochemical properties of two quaternary chalcogenidoantimonates(III) BaCuSbQ3 (Q = S, Se). JOURNAL OF ALLOYS AND COMPOUNDS, 679 (420). [10.1016/j.jallcom.2016.04.096]
30. Yaying Shen, Chang Liu, Peipei Hou, Mingjia Zhi, Chunmei Zhou, Wenxiang Chai, Qichun Zhang, Yi Liu. (2016) Facile surfactant-thermal syntheses and characterization of quaternary copper thioantimonates(III) ACu2SbS3 (A = K, Rb, Cs). JOURNAL OF ALLOYS AND COMPOUNDS, 660 (171). [10.1016/j.jallcom.2015.11.075]
31. Qin Wen-qing, Luo Hong-lin, Liu Wei, Zheng Yong-xing, Yang Kang, Han Jun-wei. (2015) Mechanism of stibnite volatilization at high temperature. Journal of Central South University, 22 (3): (868-873). [10.1007/s11771-015-2595-6]
32. Kaite Peng, Xiaoyan Wang, Zhiyong Wang, Xianbo Jin. (2025) Achieving solid-like liquid antimony sulfide cathodes for high performance thermal batteries. Journal of Energy Storage, 109 (115233). [10.1016/j.est.2024.115233]
33. Zhi-Ping Huang, Hui-Li, Wei-Ze Wang, Hu Li, Li-Mei Lin, Zhi-Gao Huang, Shui-Yuan Chen, Gui-Lin Chen. (2025) Enhancing the efficiency of Sb2(S,Se)3 thin-film solar cells via Li doping in close-spaced sublimation. SOLAR ENERGY, 285 (113117). [10.1016/j.solener.2024.113117]
34. Hui Li, Rui Da, Li-Quan Yao, Hu Li, Peng Tang, Jin-Rui Cai, Li-Mei Lin, Shui-Yuan Chen, Dong Wei, Li-Ping Cai, Gui-Lin Chen. (2024) Fabrication of homogenous Sb2(S,Se)3 solar cells by close space sublimation using a single alloyed powder source. JOURNAL OF ALLOYS AND COMPOUNDS, 991 (174492). [10.1016/j.jallcom.2024.174492]
35. Min Li, Weiqi Wang, Mengxiaojun Wu, Jingwen Lei, Xiaolu Lu, Hongmei Wang. (2024) Stibnite dissolution and Sb oxidation by Paraccocus versutus XT0.6 via direct and indirect contact. JOURNAL OF HAZARDOUS MATERIALS, 467 (133731). [PMID:38340562] [10.1016/j.jhazmat.2024.133731]

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货号 (SKU)	包装规格	是否现货
A119485-10g	10g	现货
A119485-50g	50g	现货
A119485-250g	250g	现货

硫化锑

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基本描述

名称和识别符

化学和物理性质

安全和危险性（GHS）

质检证书（CoA,COO,BSE/TSE 和分析图谱)

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