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| 货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
|---|---|---|---|---|
| A117233-1g |
1g |
现货 ![]() |
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| A117233-5g |
5g |
现货 ![]() |
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| A117233-25g |
25g |
现货 ![]() |
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| A117233-50g |
50g |
现货 ![]() |
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| A117233-100g |
100g |
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| 别名 | 金刚烷酰氯 | 金刚烷-1-甲酰氯 |
|---|---|
| 英文别名 | 1-AdamantanecarbonylChloride | Adamantane-1-carbonyl chloride | Adamantanecarbonyl chloride | 1-Adamantoyl chloride | 1-Adamantanecarbonyl chloride | |
| 规格或纯度 | ≥97% |
| 英文名称 | 1-Adamantanecarbonyl chloride |
| 储存温度 | 2-8°C储存,充氩 |
| 运输条件 | 冰袋运输 |
| 产品介绍 |
1-Adamantanecarbonyl chloride on reaction with triethylammonium isopropylphosphite forms mixed anhydride, an efficient capping reagent for the hydrogen-phosphonate DNA synthesis. It is a good substrate for Friedel-Crafts acylation of anisole in the presence of indium metal.1-Adamantanecarbonyl chloride was used in the preparation of efficient amine-modified oligodeoxynucleotides for fabrication of DNA microarrays. 1-Adamantanecarbonyl chloride on reaction with triethylammonium isopropylphosphite forms mixed anhydride, an efficient capping reagent for the hydrogen-phosphonate DNA synthesis. It is a good substrate for Friedel-Crafts acylation of anisole in the presence of indium metal. |
| 纯度 | ≥97% |
| EC号 | 218-252-7 |
|---|---|
| IIUPAC Name | adamantane-1-carbonyl chloride |
| INCHI | 1S/C11H15ClO/c12-10(13)11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2 |
| InChi Key | MIBQYWIOHFTKHD-UHFFFAOYSA-N |
| Smiles | C1C2CC3CC1CC(C2)(C3)C(=O)Cl |
| Isomeric SMILES | C1C2CC3CC1CC(C2)(C3)C(=O)Cl |
| UN Number | 3261 |
| 分子量 | 198.69 |
| Beilstein号 | 389960 |
| Reaxy-Rn | 389960 |
| Reaxys-RN link address | https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=389960&ln= |
| 溶解性 | Solubility in Toluene almost transparency |
|---|---|
| 密度 | 1.239 |
| 敏感性 | 对湿度敏感 |
| 沸点 | 135-136°C |
| 熔点 | 49-51°C |
| 分子量 | 198.690 g/mol |
| XLogP3 | 3.600 |
| 氢键供体数Hydrogen Bond Donor Count | 0 |
| 氢键受体数Hydrogen Bond Acceptor Count | 1 |
| 可旋转键计数Rotatable Bond Count | 1 |
| 精确质量Exact Mass | 198.081 Da |
| 单同位素质量Monoisotopic Mass | 198.081 Da |
| 拓扑极表面积Topological Polar Surface Area | 17.100 Ų |
| 重原子数Heavy Atom Count | 13 |
| 形式电荷Formal Charge | 0 |
| 复杂度Complexity | 218.000 |
| 同位素原子数Isotope Atom Count | 0 |
| 定义的原子立体中心计数Defined Atom Stereocenter Count | 0 |
| 未定义的原子立体中心计数Undefined Atom Stereocenter Count | 0 |
| 定义的键立体中心计数Defined Bond Stereocenter Count | 0 |
| 未定义的键立体中心计数Undefined Bond Stereocenter Count | 0 |
| 所有立体化学键的总数The total count of all stereochemical bonds | 0 |
| 共价键合单元计数Covalently-Bonded Unit Count | 1 |
| 象形图 | GHS05 |
|---|---|
| 信号词 | 危险 |
| 危险声明 |
H314: 造成严重的皮肤灼伤和眼睛损伤 |
| 预防措施声明 |
P260: 不要吸入灰尘/烟雾/气体/雾/蒸汽/喷雾。 P264: 处理后要彻底洗手。 P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。 P321: 特殊处理(请参阅此标签上的...)。 P363: 再次使用之前,请清洗受污染的衣物。 P301+P330+P331: 如误吞咽:漱口。不要诱导呕吐。 P304+P340: 如误吸入:将人转移到空气新鲜处,保持呼吸舒适体位。 P405: 密闭存放 P501: 将内容物/容器处理到。。。 P305+P354+P338: 如果进入眼睛:立即用水冲洗几分钟。取下隐形眼镜(如果有的话),并且操作简单。继续冲洗。 P302+P361+P354: 如果接触皮肤:立即脱掉所有被污染的衣服。立即用水冲洗几分钟。 P316: 立即寻求紧急医疗救助。 |
| WGK Germany | 3 |
| 个人防护装备 | Eyeshields,Faceshields,full-face particle respirator type N100 (US),Gloves,respirator cartridge type N100 (US),type P1 (EN143) respirator filter,type P3 (EN 143) respirator cartridges |
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| 批号(Lot Number) | 证书类型 | 货号 |
|---|---|---|
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 | |
| 分析证书 | A117233 |
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| 1. Nagendra Kumar Kamisetty,Seung Pil Pack,Mitsuru Nonogawa,Kamakshaiah Charyulu Devarayapalli,Seiya Watanabe,Tsutomu Kodaki,Keisuke Makino. (2007-01-24) Efficient preparation of amine-modified oligodeoxynucleotide using modified H-phosphonate chemistry for DNA microarray fabrication.. Analytical and bioanalytical chemistry, 387 ((6)): (2027-2035). [PMID:17237920] |
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| 6. Yuan-Fu Ding, Xun Xu, Junyan Li, Ziyi Wang, Jingwei Luo, Greta S.P. Mok, Shengke Li, Ruibing Wang. (2023) Hyaluronic acid-based supramolecular nanomedicine with optimized ratio of oxaliplatin/chlorin e6 for combined chemotherapy and O2-economized photodynamic therapy. Acta Biomaterialia, 164 (397). [PMID:37004784] [10.1016/j.actbio.2023.03.039] |
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| 12. Wenlong Huang, Anan Wang, Wenchen Wang, Lihong Lin, Jianyu Rong, Jia Tian, Weian Zhang. (2025) A Bacteria-Targeting Supramolecular Nanophotosensitizer for Combating Multidrug Resistant Bacteria. ACS Biomaterials Science & Engineering, 11 (3): (1741-1750). [PMID:39961745] [10.1021/acsbiomaterials.4c02047] |
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