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9-蒽醇

11篇引用文献 COA COA
    级别和纯度:
  • ≥98%
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货号 (SKU) 包装规格 是否现货 价格 数量
A101362-5g
 5g 现货 Stock Image
A101362-10g
 10g 现货 Stock Image
A101362-25g
 25g 现货 Stock Image
A101362-50g
 50g 现货 Stock Image
A101362-100g
 100g 现货 Stock Image
A101362-250g
 250g 现货 Stock Image
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基本描述

别名 9-蒽甲醇 | 9-(羟甲基)蒽
英文别名 anthracen-9-ylmethanol | Anthracene-9-carbinol | 9-anthracene methanol | 9-Hydroxymethylanthracene | NSC 241166 | 9-(Hydroxymethyl)anthracene
规格或纯度 ≥98%
英文名称 9-Anthracenemethanol
应用 9-Anthracenemethanol was used in the preparation of 9-anthracenylmethyl-1-piperazinecarboxylate
运输条件 常规运输
产品介绍

9-蒽甲醇参与由氧化铝烷催化的L-丙交酯的开环聚合反应。它与叔-丁醇钾发生质子交换反应，生成9-蒽甲醇。 9-蒽甲醇是蒽的衍生物，常用于Diels-Alder反应。

应用

9-蒽甲醇可用于：

作为制备9-蒽甲基-1-哌嗪羧酸酯的起始原料，充当HPLC测定异氰酸酯的试剂。

Diels-Alder 反应,与二甲基乙炔-二羧酸酯反应生成内酯衍生物。

作为δ-戊内酯开环聚合反应引发剂，合成聚（(δ-戊内酯)。

作为合成聚合物载体蒽的起始材料，在环加成反应中充当亲二烯体清除剂。

9-Anthracenemethanol participates in ring-opening polymerization of L-lactide catalyzed by alumoxane. It undergoes proton exchange reaction with potassium tert-butoxide to yield potassium 9-anthracenemethoxide. 9-Anthracenemethanol is a derivative of anthracene used in the Diels-Alder reactions.

纯度 ≥98%

名称和识别符

PubChem SID 488184818
EC号 215-998-5
分子类型 小分子
IIUPAC Name anthracen-9-ylmethanol
INCHI 1S/C15H12O/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9,16H,10H2
InChi Key JCJNNHDZTLRSGN-UHFFFAOYSA-N
Smiles C1=CC=C2C(=C1)C=C3C=CC=CC3=C2CO
Isomeric SMILES C1=CC=C2C(=C1)C=C3C=CC=CC3=C2CO
分子量 208.26
Beilstein号 1873402
Reaxy-Rn 1873402
Reaxys-RN link address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=1873402&ln=

化学和物理性质

溶解性 Soluble in hot methanol very faint turbidity.Insoluble in water
密度 1.214
熔点 158-164°C
分子量 208.250 g/mol
XLogP3 3.800
氢键供体数Hydrogen Bond Donor Count 1
氢键受体数Hydrogen Bond Acceptor Count 1
可旋转键计数Rotatable Bond Count 1
精确质量Exact Mass 208.089 Da
单同位素质量Monoisotopic Mass 208.089 Da
拓扑极表面积Topological Polar Surface Area 20.200 Ų
重原子数Heavy Atom Count 16
形式电荷Formal Charge 0
复杂度Complexity 216.000
同位素原子数Isotope Atom Count 0
定义的原子立体中心计数Defined Atom Stereocenter Count 0
未定义的原子立体中心计数Undefined Atom Stereocenter Count 0
定义的键立体中心计数Defined Bond Stereocenter Count 0
未定义的键立体中心计数Undefined Bond Stereocenter Count 0
所有立体化学键的总数The total count of all stereochemical bonds 0
共价键合单元计数Covalently-Bonded Unit Count 1

安全和危险性（GHS）

象形图 GHS07,   GHS08
信号词 警告
危险声明

H315: 引起皮肤刺激

H319: 引起严重眼睛刺激

H335: 可能引起呼吸道刺激

H341: 怀疑引起遗传缺陷

H302+H312+H332: 吞咽，皮肤接触或吸入有害。
预防措施声明

P261: 避免吸入灰尘/烟雾/气体/雾/蒸汽/喷雾

P264: 处理后要彻底洗手。

P270: 使用本产品时，请勿进食、饮水或吸烟。

P271: 仅在室外或通风良好的地方使用。

P280: 戴防护手套/穿防护服/戴防护眼罩/戴防护面具。

P281: 根据需要使用个人防护设备。

P321: 特殊处理（请参阅此标签上的...）。

P330: 漱口

P302+P352: 如皮肤沾染：用水充分清洗。

P304+P340: 如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。

P305+P351+P338: 如进入眼睛：用水小心冲洗几分钟。如戴隐形眼镜并可方便地取出，取出隐形眼镜。继续冲洗。

P362+P364: 脱掉沾污的衣服，清洗后方可重新使用。

P405: 密闭存放

P403+P233: 存放在通风良好的地方。保持容器密闭。

P501: 将内容物/容器处理到。。。

P203: 使用前，获取、阅读并遵守所有安全说明。

P264+P265: 处理后彻底洗手[和…]。不要触摸眼睛。

P301+P317: 如果被吞咽：请寻求医疗帮助。

P318: 如果暴露或担心，请就医。

P317: 寻求紧急医疗救助。

P337+P317: 如果眼睛刺激持续：寻求医疗帮助。

P332+P317: 如果出现皮肤刺激：请寻求医疗帮助。

P319: 如果你感到不适，请寻求医疗帮助。
WGK Germany 3
个人防护装备 Eyeshields,Gloves,type N95 (US),type P1 (EN143) respirator filter

质检证书（CoA,COO,BSE/TSE 和分析图谱)

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找到23个结果

批号(Lot Number) 证书类型 货号
L2121081 分析证书 A101362
L2121083 分析证书 A101362
L2121085 分析证书 A101362
L2121086 分析证书 A101362
E2114074 分析证书 A101362
E2114075 分析证书 A101362
E2114076 分析证书 A101362
H2428253 分析证书 A101362
J1618003 分析证书 A101362
C2421098 分析证书 A101362
C2421099 分析证书 A101362
C2421100 分析证书 A101362
H2308471 分析证书 A101362
H2308472 分析证书 A101362
H2308476 分析证书 A101362
H2308477 分析证书 A101362
H2308478 分析证书 A101362
H2308481 分析证书 A101362
I2222643 分析证书 A101362
I2222633 分析证书 A101362
I2222636 分析证书 A101362
I2222634 分析证书 A101362
D2306026 分析证书 A101362

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引用文献

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10. Chen-Yu Li,Chen-Yen Tsai,Chia-Her Lin,Bao-Tsan Ko.  (2011-02-02)  Synthesis, structural characterization and reactivity of aluminium complexes supported by benzotriazole phenoxide ligands: air-stable alumoxane as an efficient catalyst for ring-opening polymerization of L-lactide..  Dalton transactions (Cambridge, England : 2003),  40  ((9)): (1880-1887).  [PMID:21283858]
11. Shanshan Kou,Hu Zhou,Guodong Tang,Rongqing Li,Yu Zhang,Jianying Zhao,Changmei Wei.  (2012-08-14)  Experimental and DFT studies on the vibrational and electronic spectra of 9-anthracenemethanol..  Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy,  96  (768-775).  [PMID:22885894]
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13. Patrick Morkus,Mehdi Zolfaghari,Salman Alizadeh Kordkandi,Jake Nease,Carlos D M Filipe,David R Latulippe.  (2019-12-04)  A Rapid Assay to Assess Nitrification Inhibition Using a Panel of Bacterial Strains and Partial Least Squares Modeling..  Environmental science & technology,  54  ((1)): (184-194).  [PMID:31790215]
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