Articles by tag "Conjugate Reduction"

1. PMHS, Polymethylhydrosiloxane
   posted this at Jun 9, 2025

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   Polymethylhydrosiloxane (PMHS), a byproduct generated within the silicone manufacturing sector, serves as an economical, user-friendly, and eco-conscious reducing agent. Notably, PMHS exhibits superior stability in the presence of air and moisture compared to alternative silanes, enabling ...
2. Diethoxymethylsilane, DEMS
   posted this at Jun 9, 2025

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   Chiral rhodium-bis(oxazolinyl)phenyl complexes catalyze the conjugate hydrosilylation of 3,3-diarylacrylate derivatives to prepare optically active 3,3-diarylpropanoate derivatives in high yields and high enantioselectivities.