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Tag Chemical synthesis

Articles by tag "Chemical synthesis"

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  1. DIBAL-H, Diisobutylaluminium hydride DIBAL-H, Diisobutylaluminium hydride
  2. Diethylsilane Diethylsilane
  3. 1,3-Dimethylimidazol-2-ylidene borane (diMe-Imd-BH3) NHC-trihydroboranes are white solids that are stable to air, water, and even chromatography. However, 1,3-dimethylimidazol-2-ylidene borane is a surprisingly good hydride donor that is comparable to anionic reagents such as NaCNBH3. The reagent can be used for reductive amination procedures and ...
  4. 108 SadPhos, Find Your Own Chiral Phosphine Ligands/Catalysts Professor Zhang Junliang's research group from Fudan University has developed 12 series of chiral tert-butylsulfinamide phosphine ligands/catalysts (Sulfinamide Phosphine, collectively referred to as SadPhos) based on the design concept of non-C2 symmetry, combining rigidity and flexibility, as ...
  5. Hypophosphorous acid and hypophosphite salts Hypophosphorous acid and hypophosphite salts
  6. sec-Butanol, 2-Butanol Butan-2-ol, or sec-butanol, is an organic compound with formula CH3CH(OH)CH2CH3. Its structural isomers are 1-butanol, isobutanol, and tert-butanol. 2-Butanol is chiral and thus can be obtained as either of two stereoisomers designated as (R)-(−)-butan-2-ol and (S)-(+)-butan-2-ol. It is ...
  7. N-Fluoro-2,4,6-trimethylpyridinium triflate N-Fluoro-2,4,6-trimethylpyridinium triflate
  8. 1,4-Cyclohexadiene, CHD 1,4-Cyclohexadiene can act as hydrogen atom donor due to aromatization as driving force.
  9. N-tert-butylbenzenesulfinimidoyl chloride A range of unsymmetrical ketones has been prepared in good yields from aldehydes in one simple synthetic operation by addition of organolithium compounds followed by an oxidation using N-tert-butylphenylsulfinimidoyl chloride.
  10. tert-Butyl hydroperoxide, TBHP Various aromatic, aliphatic and conjugated alcohols were transformed into the corresponding carboxylic acids and ketones in good yields with aq 70% t-BuOOH in the presence of catalytic amounts of bismuth(III) oxide. This method possesses does not involve cumbersome work-up, exhibits ...
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