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Triphenylphosphine, polymer-bound - 100-200mesh, extent of labeling: ~3mmol/g triphenylphosphine loading, high purity , CAS No.39319-11-4

    Grade & Purity:
  • 100-200mesh, extent of labeling: ~3mmol/g triphenylphosphine loading
In stock
Item Number
T466296
Grouped product items
SKU Size
Availability
Price Qty
T466296-5g
5g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$329.90
T466296-25g
25g
Available within 8-12 weeks(?)
Production requires sourcing of materials. We appreciate your patience and understanding.
$963.90

Basic Description

Synonyms TRIPHENYLPHOSPHINE [INCI] | Triphenylphosphine, flakes | CCRIS 4889 | Triphenylphosphine, powder | Tox21_202114 | tripbenylphosphine | AT26025 | EC 210-036-0 | HSDB 4266 | NCGC00257211-01 | triphenyiphosphine | PP 360 | NCGC00091416-01 | triphenyl phosphi
Specifications & Purity 100-200mesh, extent of labeling: ~3mmol/g triphenylphosphine loading
Note Polymer-bound triphenylphosphine is used for preparing polymer-bound yields which are highly useful for Wittig reactions; removal of the polymer at the end of the reaction removes all the phosphine oxide.
Product Description

Description

Polymer-bound triphenylphosphine is a solid-supported reagent that can be used as a better alternative to triphenylphosphine in the Mitsunobu reaction.It can also be used:For the esterification of alkylphosphonic acids using primary alcohols in the presence of iodine and imidazole.To catalyze the conversion of 3-[3-(1,3-dioxolan-2-yl)-1-hydroxypropyl]pyridine to 3-[1-bromo-3-(1,3-dioxolan-2-yl)propyl]pyridine using carbon tetrabromide.To isomerize (Z)-nitro olefins to the (E)-isomers.To prepare polymer-bound ylides which are useful in Wittig reactions.To convert alcohols or carboxylic acids to the corresponding chlorides.In combination with carbon tetrachloride for the couplingN-alkoxycarbonyl α-amino acids and primary amines to form the corresponding amides.

Associated Targets(Human)

KCNH2 Tclin HERG (29587 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
CXCL8 Tchem Interleukin-8 (642 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
CYP3A4 Tclin Cytochrome P450 3A4 (53859 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
CCRF-CEM (65223 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Lymphoblastoid cell (5959 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
TDP1 Tchem Tyrosyl-DNA phosphodiesterase 1 (345557 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID

Mechanisms of Action

Mechanism of Action Action Type target ID Target Name Target Type Target Organism Binding Site Name References

Names and Identifiers

Smiles C1CCC(CC1)P(C1CCCCC1)C1CCCCC1
Isomeric SMILES C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3
WGK Germany 3
PubChem CID 11776
Molecular Weight 262.29

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Chemical and Physical Properties

Molecular Weight 262.300 g/mol
XLogP3 4.600
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 0
Rotatable Bond Count 3
Exact Mass 262.091 Da
Monoisotopic Mass 262.091 Da
Topological Polar Surface Area 0.000 Ų
Heavy Atom Count 19
Formal Charge 0
Complexity 202.000
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
The total count of all stereochemical bonds 0
Covalently-Bonded Unit Count 1

Citations of This Product

1. Wenhua Ji,Xiuli Ma,Hongkai Xie,Lingxiao Chen,Xiao Wang,Hengqiang Zhao,Luqi Huang.  (2014-12-03)  Molecularly imprinted polymers with synthetic dummy template for simultaneously selective removal and enrichment of ginkgolic acids from Ginkgo biloba L. leaves extracts..  Journal of chromatography. A,  1368  (44-51). 
2. Bing-Feng Zhang,Lei Xing,Peng-Fei Cui,Feng-Zhen Wang,Rong-Lin Xie,Jia-Liang Zhang,Mei Zhang,Yu-Jing He,Jin-Yuan Lyu,Jian-Bin Qiao,Bao-An Chen,Hu-Lin Jiang.  (2015-05-26)  Mitochondria apoptosis pathway synergistically activated by hierarchical targeted nanoparticles co-delivering siRNA and lonidamine..  Biomaterials,  61  (178-189). 
3. Nengchao Luo, Tingting Hou, Shiyang Liu, Bin Zeng, Jianmin Lu, Jian Zhang, Hongji Li, Feng Wang.  (2020)  Photocatalytic Coproduction of Deoxybenzoin and H2 through Tandem Redox Reactions.  ACS Catalysis,  10  (1): (762–769). 

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