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TMS-BA - for GC derivatization, high purity , CAS No.10416-59-8
Basic Description
Synonyms
B0510 | DTXSID5051525 | D72517 | Trimethylsilyl N-(trimethylsilyl)ethanimidoate | TMS-BA | N-trimethylsilyl-acetylimidic acid trimethylsilyl ester | trimethylsilyl N-trimethylsilylacetimidate | BCP24460 | n,o-bis (trimethylsilyl)acetamide | (E)-trimethyls
Specifications & Purity
for GC derivatization
Storage Temp
Store at 2-8°C,Argon charged
Shipped In
Wet ice
This product requires cold chain shipping. Ground and other economy services are not available.
Grade
for GC derivatization
Taxonomic Classification
Kingdom
Organic compounds
Superclass
Organometallic compounds
Class
Organometalloid compounds
Subclass
Organosilicon compounds
Intermediate Tree Nodes
Organoheterosilanes
Direct Parent
Trialkylheterosilanes
Alternative Parents
Organic metalloid salts N-silyl compounds Organopnictogen compounds Organooxygen compounds Organonitrogen compounds Hydrocarbon derivatives
Molecular Framework
Aliphatic acyclic compounds
Substituents
Trialkylheterosilane - N-silyl compound - Organic metalloid salt - Organic nitrogen compound - Organic oxygen compound - Organopnictogen compound - Hydrocarbon derivative - Organic salt - Organooxygen compound - Organonitrogen compound - Aliphatic acyclic compound
Description
This compound belongs to the class of organic compounds known as trialkylheterosilanes. These are organoheterosilanes, bearing a silicon atom linked to three alkyl groups and one heteroatom.
External Descriptors
Not available
Data sources
1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.
Names and Identifiers
IUPAC Name
trimethylsilyl N-trimethylsilylethanimidate
INCHI
InChI=1S/C8H21NOSi2/c1-8(9-11(2,3)4)10-12(5,6)7/h1-7H3
InChIKey
SIOVKLKJSOKLIF-UHFFFAOYSA-N
Smiles
CC(=N[Si](C)(C)C)O[Si](C)(C)C
Isomeric SMILES
CC(=N[Si](C)(C)C)O[Si](C)(C)C
WGK Germany
3
RTECS
AK3000000
PubChem CID
25248
Molecular Weight
203.43
Beilstein
1306669
Reaxy-Rn
1306669
Certificates（CoA,COO,BSE/TSE and Analysis Chart)
Chemical and Physical Properties
Sensitivity
Moisture Sensitive
Refractive Index
1.417
Flash Point(°F)
42 °C
Flash Point(°C)
42°C
Boil Point(°C)
71-73°C
Melt Point(°C)
24°C
Molecular Weight
203.430 g/mol
XLogP3
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
2
Rotatable Bond Count
3
Exact Mass
203.116 Da
Monoisotopic Mass
203.116 Da
Topological Polar Surface Area
21.600 Ų
Heavy Atom Count
12
Formal Charge
0
Complexity
176.000
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
1
The total count of all stereochemical bonds
1
Covalently-Bonded Unit Count
1
Citations of This Product
1.
Hanxiao Zhou, Tianhui Li, Wenjing Liu, Zhihao Guo, Zihao Su, Jingjing Gao, Meizhen Qu, Gongchang Peng.
(2023)
A Bifunctional Fluorine-Free Electrolyte Additive for Realizing Dendrite-Free Lithium Anodes. ChemSusChem,
16
(10):
(e202300186).
2.
Xuerui Bai, Maiqian Nie, Zhenjun Diwu, Lei Wang, Hongyun Nie, Yan Wang, Qiuyue Yin, Bo Zhang.
(2021)
Extraction and purification of 2-hydroxymuconic semialdehyde accumulated in phenol degradation by Pseudomonas stutzeri N2. CHEMICAL ENGINEERING JOURNAL,
419
(129444).
3.
Chuan-Guo Ma, Man Zhao, Tian-Lei Si, Xiao-Wei Chen.
(2021)
Comparative study of adsorption polysaccharide on bioactive components and in vitro antioxidant activity of sea buckthorn (Hippophaë rhamnoides L.) pulp oil. LWT-FOOD SCIENCE AND TECHNOLOGY,
141
(110896).
4.
Yichun Yang, Pai Peng, Qing Yang, Dongmei Wang, Juane Dong.
(2020)
Fabrication of renewable gutta percha/silylated nanofibers membrane for highly effective oil-water emulsions separation. APPLIED SURFACE SCIENCE,
530
(147163).
5.
Haizhu Shi, Jie Yuan, Yi Zhang, Shun Feng, Jide Wang.
(2019)
Discovering significantly different metabolites between Han and Uygur two racial groups using urinary metabolomics in Xinjiang, China. JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS,
164
(481).
6.
Hongyun Nie, Maiqian Nie, Yongzhe Yang, Jing Zhao, Xinyi Zhang, Yutao Guo, Yi Wan, Jing Zi.
(2016)
Characterization of Phenol Metabolization by P. stutzeri N2. POLYCYCLIC AROMATIC COMPOUNDS,
7.
Zuolong Yu, Beizhen Hu, Yao Chen, Chaoqun Huang, Chao Han, Yan Shen.
(2024)
Determination of penicillic acid in cereals by solid-phase extraction and gas chromatography-tandem mass spectrometry. JOURNAL OF FOOD COMPOSITION AND ANALYSIS,
130
(106197).
8.
Fenghui Li, Hao Wu, Tianfu Zhao, Hong Wen, Wei Lin, Tianhao Wu, Fang Wang, Jie Zhou, Lianbang Wang.
(2025)
Insights into the selection of SiO bond containing electrolyte additives for Si-based lithium-ion batteries. Journal of Energy Storage,
114
(115943).
9.
Lingfang Ran, Yaohua Li, Long Chen, Tong Mo, Nian Liu, Shijia Xu, Yucheng Su, Chuannan Wang, Aimin Liang, Jianyan Zeng, Wanting Yu, Jie Kong, Yuehua Xiao.
(2025)
Specific expression of a fusion gene Lc-GhPAP1D results in colored cotton fibers with increased flavonoid and lignin synthesis, but impaired elongation and secondary cell wall deposition. Journal of Integrative Agriculture,
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9 Citations
K2327454