Rhamnofolane and daphnane diterpenoids

Description:

Diterpenoids with a structure based on one the rhamnofolane or daphnane skeleton. The rhamnofolane and daphnane skeletons are closely related, being formally derived from casbane by two cyclizations (6,10 and 5,14) followed by cleavage of the 1,15 (daphnane) or 2,15 (rhamnofolane) cyclopropane bonds.

Ancestors:

Organic compounds ⮕ Lipids and lipid-like molecules ⮕ Prenol lipids ⮕ Diterpenoids ⮕ Rhamnofolane and daphnane diterpenoids

resiniferatoxin
- ≥98%
Cas Number: 57444-62-9 EC Number: 637-354-6

Formula: C₃₇H₄₀O₉ Molecular Weight: 628.71

IUPAC Name: [(1R,2R,6R,10S,11R,13S,15R,17R)-13-benzyl-6-hydroxy-4,17-dimethyl-5-oxo-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadeca-show more

SMILES: CC1CC2(C3C4C1(C5C=C(C(=O)C5(CC(=C4)COC(=O)CC6=CC(=C(C=C6)O)OC)O)C)OC(O3)(O2)CC7=CC=CC=C7)C(=C)C

InChIKey: DSDNAKHZNJAGHN-MXTYGGKSSA-N

InChI: InChI=1S/C37H40O9/c1-21(2)35-17-23(4)37-27(33(35)44-36(45-35,46-37)19-24-9-7-6-8-10-24)14-26(18-34(41)30(37)13-22(3)32(34)40)20-43-31(39)16-25-11-12-2show more

Synonyms: Resiniferatoxin|57444-62-9|Lopain|RTX|(+)-resiniferatoxin|Resiniferatoxin [USAN]|Mtx-071|A5O6P1UL4I|MTX-71|Recinifera...
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5'-iodoresiniferatoxin
Cas Number: 535974-91-5

Formula: C₃₇H₃₉IO₉ Molecular Weight: 754.61

IUPAC Name: [(1R,2R,6R,10S,11R,15R,17R)-13-benzyl-6-hydroxy-4,17-dimethyl-5-oxo-15-prop-1-en-2-yl-12,14,18-trioxapentacyclo[11.4.1.01,10.02,6.011,15]octadeca-3,8-show more

SMILES: CC1CC2(C3C4C1(C5C=C(C(=O)C5(CC(=C4)COC(=O)CC6=CC(=C(C(=C6)I)O)OC)O)C)OC(O3)(O2)CC7=CC=CC=C7)C(=C)C

InChIKey: TZUJORCXGLGWDV-RYACRXIZSA-N

InChI: InChI=1S/C37H39IO9/c1-20(2)35-16-22(4)37-26(33(35)45-36(46-35,47-37)18-23-9-7-6-8-10-23)12-25(17-34(42)29(37)11-21(3)32(34)41)19-44-30(39)15-24-13-27(show more

Synonyms: I-RTX
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