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Metribuzin in Methanol - 100μg/mL in Methanol, high purity , CAS No.21087-64-9

    Grade & Purity:
  • 100μg/mL in Methanol
In stock
Item Number
M283759
Grouped product items
SKU Size
Availability
Price Qty
M283759-1.2ml
1.2ml
Available within 4-8 weeks(?)
Items will be manufactured post-order and can take 4-8 weeks. Thank you for your patience!
$49.90
View related series
Cell Cycle (2830)

Basic Description

Synonyms METRIBUZIN | 21087-64-9 | Sencor | Lexone | Metribuzine | Zenkor | Sencorex | Senkor | 4-Amino-6-tert-butyl-3-methylsulfanyl-4H-[1,2,4]triazin-5-one | Lexone DF | Sencor DF | Lexone 4L | Sencor 4F | Sencoral | Bay 94337 | Bayer 6159H | Bayer 6443H | Bayer 94337 | BAY dic 1468 | DIC 1468 | 4-ami
Specifications & Purity 100μg/mL in Methanol
Storage Temp Store at 2-8°C,Protected from light
Shipped In
Wet ice
This product requires cold chain shipping. Ground and other economy services are not available.
Product Description

Application
This standard substance is mainly used for measuring instrument calibration, analytical method evaluation and quality control, and the determination of corresponding components and residue detection in the fields of food, sanitation, environment and agriculture.


Sample Preparation

This standard substance is prepared by using the purity standard substance Metribuzin as the solute, methanol as the solvent, and the weight-volume method in a clean laboratory at room temperature of 20±3°C.


Characteristic value and expanded uncertainty

ComponentStandard valueExpanded uncertainty (k=2)Matrix
Metribuzin
100μg/mL
3%methanol

It is mainly synthesized by the uncertainty of raw material purity, weighing, constant volume, uniformity, and long-term stability.


Packaging, storage and use

Packaging: This standard material is packaged, and the specification 1.2mL should be protected from shattering when carried or transported. Storage and use: Keep it under refrigerated airtight and protected from light. Before use, it should be balanced at room temperature (20±3℃) and shake well to ensure uniformity. Once the ampoule is opened, it should be used immediately. It cannot be used as a standard substance after being re-sealed. Strictly prevent contamination during use.

Taxonomic Classification

Taxonomy Tree

Kingdom Organic compounds
Superclass Organosulfur compounds
Class Thioethers
Subclass Aryl thioethers
Intermediate Tree Nodes Not available
Direct Parent Aryl thioethers
Alternative Parents Alkylarylthioethers  1,2,4-triazines  Heteroaromatic compounds  Lactams  Sulfenyl compounds  Azacyclic compounds  Organopnictogen compounds  Organooxygen compounds  Organonitrogen compounds  Organic oxides  Hydrocarbon derivatives  
Molecular Framework Aromatic heteromonocyclic compounds
Substituents Aryl thioether - Alkylarylthioether - Triazine - 1,2,4-triazine - Heteroaromatic compound - Lactam - Azacycle - Organoheterocyclic compound - Sulfenyl compound - Organic oxide - Hydrocarbon derivative - Organic nitrogen compound - Organooxygen compound - Organonitrogen compound - Organopnictogen compound - Organic oxygen compound - Aromatic heteromonocyclic compound
Description This compound belongs to the class of organic compounds known as aryl thioethers. These are organosulfur compounds containing a thioether group that is substituted by an aryl group.
External Descriptors Triazine herbicides - Triazinone herbicides

Associated Targets(Human)

RXRA Tclin Retinoid X receptor alpha (3637 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID

Associated Targets(non-human)

Avena fatua (609 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Triticum aestivum (1582 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Radish (446 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Allium cepa (293 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Alopecurus myosuroides (149 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Chenopodium album (769 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Bromus tectorum (40 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Stellaria media (151 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Malva sylvestris (32 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Matricaria chamomilla (44 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Phalaris minor (20 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Cyperus rotundus (46 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID
Chenopodiastrum murale (32 Activities)
Activity Type Relation Activity value Units Action Type Journal PubMed Id doi Assay Aladdin ID

Mechanisms of Action

Mechanism of Action Action Type target ID Target Name Target Type Target Organism Binding Site Name References

Names and Identifiers

IUPAC Name 4-amino-6-tert-butyl-3-methylsulfanyl-1,2,4-triazin-5-one
INCHI InChI=1S/C8H14N4OS/c1-8(2,3)5-6(13)12(9)7(14-4)11-10-5/h9H2,1-4H3
InChIKey FOXFZRUHNHCZPX-UHFFFAOYSA-N
Smiles CC(C)(C)C1=NN=C(N(C1=O)N)SC
Isomeric SMILES CC(C)(C)C1=NN=C(N(C1=O)N)SC
WGK Germany 3
RTECS XZ2990000
UN Number 3077
Packing Group III
Molecular Weight 214.29
Beilstein 746650
Reaxy-Rn 746650
Reaxys-RN_link_address https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=746650&ln=

Certificates(CoA,COO,BSE/TSE and Analysis Chart)

C of A & Other Certificates(BSE/TSE, COO):
Analytical Chart:

Chemical and Physical Properties

Melt Point(°C) 125-126.5°C
Molecular Weight 214.290 g/mol
XLogP3 1.700
Hydrogen Bond Donor Count 1
Hydrogen Bond Acceptor Count 5
Rotatable Bond Count 2
Exact Mass 214.089 Da
Monoisotopic Mass 214.089 Da
Topological Polar Surface Area 96.400 Ų
Heavy Atom Count 14
Formal Charge 0
Complexity 316.000
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
The total count of all stereochemical bonds 0
Covalently-Bonded Unit Count 1

Citations of This Product

1. Chen-Yan Hu, Dan-Dan Huang, Yi-Li Lin, Qiang-Bing Wang, Ling Xu, Zi-Yi Dong, Yi-Hui Wu, Sheng-Jie Ji.  (2023)  Degradation of metribuzin in the UV/chlorine process: kinetic model, degradation by-products and transformation pathways.  Environmental Science-Water Research & Technology,  (7): (1932-1943). 
2. Chun Wang, Qianqian Wang, Jintao Yu, Xinmeng Wang, Lijuan Wang, Bin Zhao, Lin Hao, Weihua Liu, Zhi Wang, Hao Chen, Qiuhua Wu.  (2023)  Converting waste expanded polystyrene into higher-value-added hyper-crosslinked porous polymer for rapid and high-efficient adsorption of aflatoxins.  Journal of Cleaner Production,  408  (137102). 
3. Xiang Dongmei, Zhu Lin, Yang Song, Hou Xiaomin.  (2023)  Scrutinizing the interaction between metribuzin with glutathione reductase 2 from Arabidopsis thaliana: insight into the molecular toxicity in agriculture.  ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH,  30  (5): (11936-11945). 
4. Qianqian Wang, Ranxiao Tang, Mingming Xu, Junmin Wang, Shuofeng Li, Weihua Liu, Lin Hao, Shuaihua Zhang, Junhong Zhou, Chun Wang, Qiuhua Wu, Zhi Wang.  (2022)  Sustainable synthesis of hydroxyl-functional porous organic framework as novel adsorbent for effective removal of organic micropollutants from water.  JOURNAL OF ENVIRONMENTAL MANAGEMENT,  321  (115952). 
5. Xicheng Xie, Lingyun Li, Lumei Wang, Chaoqiang Pan, Dongwei Zhang, Guoqing Shen, Xicheng Xie, Lingyun Li, Lumei Wang, Chaoqiang Pan, Dongwei Zhang, Guoqing Shen.  (2021)  Colourimetric Detection of Tebuconazole in Aqueous Solution Based on an Unmodified Aptamer and the Aggregation of Gold Nanoparticles.  AUSTRALIAN JOURNAL OF CHEMISTRY,  74  (12): (838-846). 
6. Wu Lijie, Li Zhanchao, Hu Mingzhu.  (2021)  Dynamic Microwave-Assisted Micelle Extraction Coupled with Cloud Point Preconcentration for the Determination of Triazine Herbicides in Soil.  JOURNAL OF CHROMATOGRAPHIC SCIENCE,  60  (5): (493-500). 
7. Qiuhua Wu, Yuhong Song, Qianqian Wang, Weihua Liu, Lin Hao, Zhi Wang, Chun Wang.  (2021)  Combination of magnetic solid-phase extraction and HPLC-UV for simultaneous determination of four phthalate esters in plastic bottled juice.  FOOD CHEMISTRY,  339  (127855). 
8. Qianqian Wang, Weihua Liu, Lin Hao, Chun Wang, Qiuhua Wu, Zhi Wang.  (2020)  Fabrication of magnetic porous organic framework for effective enrichment and assay of nitroimidazoles in chicken meat.  FOOD CHEMISTRY,  332  (127427). 
9. Wang Qianqian, Li Gaigai, Wang Chun, Wu Qiuhua, Wang Zhi.  (2020)  Layered porous organic frameworks as a novel adsorbent for the solid phase extraction of chlorophenols prior to their determination by HPLC-DAD.  MICROCHIMICA ACTA,  187  (4): (1-11). 
10. Yan Xu, Shumin Wu, Xianliang Li, Hao Meng, Xia Zhang, Zhuopeng Wang, Yide Han.  (2017)  Ag nanoparticle-functionalized ZnO micro-flowers for enhanced photodegradation of herbicide derivatives.  CHEMICAL PHYSICS LETTERS,  679  (119). 
11. Wang Chengke, Wang Chengen, Wang Qingqing, Chen Dan.  (2017)  Resonance light scattering method for detecting kanamycin in milk with enhanced sensitivity.  ANALYTICAL AND BIOANALYTICAL CHEMISTRY,  409  (11): (2839-2846). 
12. Wang Chengke, Chen Dan, Wang Qingqing, Wang Qiuxia.  (2016)  Aptamer-based Resonance Light Scattering for Sensitive Detection of Acetamiprid.  ANALYTICAL SCIENCES,  32  (7): (757-762). 
13. Donglin Jia, Lu Wang, Yudong Gao, Lina Zou, Baoxian Ye.  (2016)  Electrochemical behavior of metribuzin based on l-Norvaline modified electrode and its sensitive determination.  JOURNAL OF ELECTROANALYTICAL CHEMISTRY,  764  (56). 
14. Zihang Zeng, Bingni Jia, Xiaofeng Liu, Lixiang Chen, Peng Zhang, Taiping Qing, Bo Feng.  (2024)  Adsorption behavior of triazine pesticides on polystyrene microplastics aging with different processes in natural environment.  ENVIRONMENTAL POLLUTION,  356  (124319). 
15. Guijiao Zhao, Chenhuan Wang, Min Kang, Lin Hao, Weihua Liu, Zhi Wang, Xiaodong Shi, Qiuhua Wu.  (2024)  Construction of magnetic azo-linked porous polymer for highly-efficient enrichment and separation of phenolic endocrine disruptors from environmental water and fish.  FOOD CHEMISTRY,  445  (138698). 
16. Zichen Zhao, Ruiyang Ma, Juntao Wang, Qing Zhang, Miao Jing, Chun Wang, Qiuhua Wu, Zhi Wang.  (2025)  Preparation of boric acid functionalized hyper-crosslinked polymer for efficient extraction of phenylurea herbicides from lake water, green tea drink and tomato samples.  JOURNAL OF CHROMATOGRAPHY A,  1747  (465823). 
17. Linna Guo, Qianqian Wang, Qiuhua Wu, Chun Wang, Baojiang Chen.  (2025)  β-Cyclodextrin based magnetic hyper-crosslinked polymer: A recyclable adsorbent for effective preconcentration of triazine herbicides in complex sample matrices.  FOOD CHEMISTRY,  463  (141219). 

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