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| Synonyms | EINECS 223-725-6 | A825085 | Lithiobis(trimethylsilyl)amide; Lithiohexamethyldisilazane; Lithium bis(trimethylsilyl)amide; Lithium bis(trimethylsilyl)amide(1-) | lithium bis (trimethylsilyl)amide | lithium bis trimethylsilyl amide | BCP21718 | Lithium hex |
|---|---|
| Specifications & Purity | 1.5 M in THF |
| Storage Temp | Argon charged |
| Shipped In | Normal |
| Product Description |
Application Strong base for kinetically controlled deprotonations. |
Taxonomy Tree
| Kingdom | Organic compounds |
|---|---|
| Superclass | Organometallic compounds |
| Class | Organometalloid compounds |
| Subclass | Organosilicon compounds |
| Intermediate Tree Nodes | Organoheterosilanes |
| Direct Parent | Trialkylheterosilanes |
| Alternative Parents | Organic metalloid salts Organic lithium salts N-silyl compounds Organic nitrogen compounds Hydrocarbon derivatives |
| Molecular Framework | Aliphatic acyclic compounds |
| Substituents | Trialkylheterosilane - N-silyl compound - Organic lithium salt - Organic alkali metal salt - Organic metalloid salt - Organic nitrogen compound - Hydrocarbon derivative - Organic salt - Aliphatic acyclic compound |
| Description | This compound belongs to the class of organic compounds known as trialkylheterosilanes. These are organoheterosilanes, bearing a silicon atom linked to three alkyl groups and one heteroatom. |
| External Descriptors | Not available |
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| IUPAC Name | lithium;bis(trimethylsilyl)azanide |
|---|---|
| INCHI | InChI=1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1 |
| InChIKey | YNESATAKKCNGOF-UHFFFAOYSA-N |
| Smiles | [Li+].C[Si](C)(C)[N-][Si](C)(C)C |
| Isomeric SMILES | [Li+].C[Si](C)(C)[N-][Si](C)(C)C |
| WGK Germany | 3 |
| Molecular Weight | 167.32 |
| Beilstein | 3567910 |
| Reaxy-Rn | 8136861 |
| Reaxys-RN_link_address | https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=8136861&ln= |
Find and download the COA for your product by matching the lot number on the packaging.
| Lot Number | Certificate Type | Date | Item |
|---|---|---|---|
| Certificate of Analysis | Nov 13, 2023 | L432695 | |
| Certificate of Analysis | Nov 13, 2023 | L432695 | |
| Certificate of Analysis | Nov 13, 2023 | L432695 | |
| Certificate of Analysis | Nov 13, 2023 | L432695 | |
| Certificate of Analysis | Nov 13, 2023 | L432695 |
| Sensitivity | Air sensitive;Moisture sensitive |
|---|---|
| Flash Point(°F) | 1.4℉ |
| Flash Point(°C) | -17℃ |
| Molecular Weight | 167.400 g/mol |
| XLogP3 | |
| Hydrogen Bond Donor Count | 0 |
| Hydrogen Bond Acceptor Count | 1 |
| Rotatable Bond Count | 2 |
| Exact Mass | 167.114 Da |
| Monoisotopic Mass | 167.114 Da |
| Topological Polar Surface Area | 1.000 Ų |
| Heavy Atom Count | 10 |
| Formal Charge | 0 |
| Complexity | 80.900 |
| Isotope Atom Count | 0 |
| Defined Atom Stereocenter Count | 0 |
| Undefined Atom Stereocenter Count | 0 |
| Defined Bond Stereocenter Count | 0 |
| Undefined Bond Stereocenter Count | 0 |
| The total count of all stereochemical bonds | 0 |
| Covalently-Bonded Unit Count | 2 |
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| 1. Chi Zhang, Jiang-An You, Xue Wang, Rui Hou, Xiaofeng Li, Yuxuan Sun, Guorui Qin, Shenghai Li, Suobo Zhang. (2024) Design of Precursor Polymers Assists the Processing of Poly(ether ether ketone) Membranes in Solvents. MACROMOLECULES, 57 (5): (2446-2457). |
| 2. Huicheng Hu, Jing Liu, Jing Liu, Mohan Yuan, Haifei Ma, Binbin Wang, Ya Wang, Hang Xia, Junrui Yang, Liang Gao, Jianbing Zhang, Jiang Tang, Xinzheng Lan. (2025) Double-Heterojunction-Based HgTe Colloidal Quantum Dot Imagers. ACS Nano, 19 (9): (8974-8984). |