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The oxidation resistance of Ni nanoparticle incorporated SiOC coating for TiAl alloy

APPLIED SURFACE SCIENCE [2025]
Yun-Yang Li, Hao-Jie Yan, Ruo-Zhan Yin, Qing-Qing Sun, Lian-Kui Wu, Fa-He Cao
ABSTRACT

In this work, SiOC coatings incorporated with Ni nanoparticles were fabricated on γ-TiAl alloy by dip-coating. The microstructure and high temperature oxidation behavior of the SiOC-Ni coatings with different Ni contents were investigated. Results showed that the incorporation of Ni nanoparticles improved the oxidation resistance of the SiOC coating at 850 ℃. During thermal exposure to air, the incorporated Ni particles would react with both oxygen and the SiOC coating, forming NiO and Ni 2 Si, respectively, therefore changing the structure of the SiOC coating. The generation of NiO and Ni 2 Si is beneficial in reducing the oxygen partial pressure at the coating/substrate interface, thereby facilitating the formation of a protective aluminum oxide layer.

MATERIALS

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