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Synthesis of Sb2Se3@PPy nanorod composite as cathode material for aluminum batteries

APPLIED SURFACE SCIENCE [2024]
Jian Li, Wenbin Luo, JinFeng Ou, Yi Yu, Zhen Zhang, Zisheng Chao, JinCheng Fan, WenJun Yi, Yadong Wang
ABSTRACT

Aluminum batteries (ABs) are a promising alternative to lithium-ion batteries (LIBs) in the future. The development of aluminum batteries   (ABs) is closely related to their cathode material. In this paper, we successfully designed and prepared a nanorod structure Sb 2 Se 3 @PPy as cathode material for ABs. It exhibits a high reversible capacity of 302 mAh/g at 0.2 A/g, and the capacity is maintained at about 210 mAh/g after 50 cycles. In addition, the electrochemical reaction mechanism and kinetic process of Sb 2 Se 3 @PPy were studied. The results showed that the PPy coating layer reduced the volume change of Sb 2 Se 3 , prevented irreversible deformation, enhanced the structural stability and electronic conductivity.

MATERIALS

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