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Study on the adsorption performance of Eu(III) in nitric acid medium by TODGA-C resin

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY [2024]
Wang Xuebin, Mao Guoshu, Yu Shengjie, Fu Zhihai, Yue Yuanzhen, Zhang Shengdong, Ding Youqian, Huang Kun, Zhang Xian, Sun Xiaoyi
ABSTRACT

Responding to the need for radioactive waste disposal, the static and dynamic adsorption of Eu 3+ on TODGA-C resin in HNO 3 was investigated. The findings indicated that the adsorption of Eu 3+ on TODGA-C adheres to the quasi-second-order kinetic model. Additionally, the distribution coefficient for Eu 3+ adsorption on TODGA-C reaches 10 5  mL/g in 4 mol/L HNO 3 . Under the conditions of 3.5 mol/L HNO 3 , a flow rate of 3.6 mL/min, and an initial Eu 3+ concentration of 10 mg/L, the Thomas rate constant was found to be 1.2 mL/(mg·min), with a dynamic saturation capacity of 15 mg/mL.

MATERIALS

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