Strong, tough and environment-tolerant organohydrogels for flaw-insensitive strain sensing

Conductive organohydrogels are promising for strain sensing, while their weak mechanical properties, poor crack propagation resistance and unstable sensing signals during the long-term use have seriously limit their applications as high-performance strain sensors. Here, we propose a facile method, i.e., solvent exchange assisted hot-pressing, to prepare strong yet tough, transparent and anti-fatigue ionically conductive organohydrogels (ICOHs). The densified polymeric network and improved crystallinity endow ICOHs with excellent mechanical properties. The tensile strength, toughness, fracture energy and fatigue threshold of ICOHs can reach 36.12 ± 4.15 MPa, 54.57 ± 2.89 MJ/m3, 43.44 ± 8.54 KJ/m2 and 1212.86 ± 57.20 J/m2, respectively, with a satisfactory fracture strain of 266 ± 33%. In addition, the ICOH strain sensors with freezing and drying resistance exhibit excellent cyclic stability (10,000 cycles). More importantly, the fatigue resistance allows the notched strain sensor to work normally with no crack propagation and output stable and reliable sensing signals. Overall, the unique flaw-insensitive strain sensing makes ICOHs promising in the field of wearable and durable electronics.