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SnO2/Fe2O3/Cu2O composites as catalysts for photoelectrocatalytic degradation of benzotriazoles

OPTICAL MATERIALS [2024]
Jianhong Han, Xinyuan Teng, Wenhui Jia, Pai Liu, Yumei Li, Weida Wang
ABSTRACT

Benzotriazole (BTA) is a kind of nitrogen-containing organic matter with great impact on the environment and biology. In order to further improve the degradation effect of BTA, SnO 2 /Fe 2 O 3 /Cu 2 O (SFC) photocatalytic materials have been successfully prepared by one-pot hydrothermal method . According to the material characterization and experimental results, SFC has a uniform distribution of active sites, which is conducive to the efficient degradation of BTA in water. When the pH is 6.68, the dosage is 0.09 g/L, and the time is 40 min, the degradation effect is the best. The removal rate of BTA by SFC reached 99.89 %. The repeatability test showed that the removal rate of SFC can reach more than 99.27 % after five cycles of experiments.Through PL , UV–Vis and i-t curve analysis, it proved the main mechanism of degradation of BTA by PEC enhanced by SFC. Finally, the possible degradation pathways of BTA were speculated, which provided a new technical support and theoretical basis for the effective treatment of wastewater containing BTA.

MATERIALS

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