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Porous carbon derived from a by-product of traditional Chinese medicine for high-performance aqueous zinc-ion hybrid supercapacitors

DIAMOND AND RELATED MATERIALS [2024]
Bingjing Song, Qifan Liu, Fangfang Shi, Tao Xue, Chao Yang, Limin Zang
ABSTRACT

The rational utilization of biomass waste for the production of usable energy holds immense significance. The present study proposes the effective utilization of a byproduct derived from traditional Chinese medicine, specifically momordica grosvenori shell, as a precursor for fabricating high-performance porous carbon electrodes in rechargeable aqueous zinc ion supercapacitors . The MGC x -T electrodes are prepared by KOH activation and carbonization with MG (momordica grosvenori shell). The influence of KOH addition amount and carbonization temperature on the properties of the prepared materials were studied. Resulting that MGC 3 –800 has good electrical conductivity , high specific surface area (1141 m 2  g −1 ) and abundant pore structure . The maximum specific capacity reaches 228.7 mAh g −1 at 0.2 A g −1 in 2 M ZnSO 4 electrolyte. In the gelatin/ZnSO 4 electrolyte, the specific capacity reaches a maximum of 186.1 mAh g −1 . Additionally, it exhibits an energy density of 167.5 Wh kg −1 and a power density of 6300 W kg −1 . Furthermore, exceptional cycling stability is observed with a capacity retention rate of 92.6 % after 10,000 cycles. Hence, the realization of an industry-effective strategy that not only utilizes biomass waste, but also produces high-performance zinc-ion hybrid supercapacitor electrodes has been achieved.

MATERIALS

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