Photoresponsive Janus microfibers array film with tunable electrical anisotropy

A new kind of photoresponsive film is produced by integrating photoconductive material into the type-II anisotropic conductive film. This film consists of orderly arranged Janus microfibers, with each Janus microfiber is comprised of a conductive region and an insulating region. Copper phthalocyanine, as the photoconductive material, is introduced into the conductive regions of these Janus microfibers, and thus the electrical conduction of the conductive regions can be enhanced by applying appropriate external light irradiation, while the insulating regions are basically unaffected. Based on this property, the electrical conduction along with the length direction of the Janus microfibers in the film is adjustable by light, the perpendicular direction along the film surface remains constantly insulating, and thus the electrical anisotropy of the resulting Janus microfibers array film can be tuned under light irradiation. The products have potential applications in flexible electronic devices and control systems.