PdBx catalyst with optimized B-doping for efficient dehydrogenation of formic acid

Developing formic acid (FA) as a promising hydrogen (H 2 ) carrier relies on the exploration of efficient dehydrogenation catalyst. In this work, well-dispersed Pd-B x nanoparticles on XC-72 carbon were synthesized and investigated for FA dehydrogenation, wherein the B doping content can be varied by changing solvothermal temperature, B source concentration, and reaction time. With sodium formate as the additive, the optimized Pd–B 0.2 /C exhibits a low apparent activation energy of 27.6 kJ mol −1 for FA dehydrogenation, enabling the CO-free H 2 production with a high initial turnover frequency of 1146 h −1 and a H 2 generation rate of 315.79 L h −1 g Pd −1 at 343 K. System investigations suggest that the strain and electronic effects induced by B doping collaboratively contribute to the superior catalytic activity by promoting the dissociation of the O–H bond in FA molecule and weakening the possible CO adsorption.