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Nanosecond pulsed discharge plasma modified porous polymer adsorbent materials for efficient removal of low-concentration bisphenol A in liquid

Plasma Processes and Polymers [2024]
Chao-Jun Chen, Yi-Nong Li, Hong-Li Wang, Ke Lu, Zhi Zheng, Hao Yuan, Jian-Ping Liang, Wen-Chun Wang, Li-Ping Han, De-Zheng Yang
ABSTRACT

The efficient removal of low-concentration endocrine disruptors is crucial for the protection of the aquatic environment. In this study, porous polymer adsorbent materials were modified by nanosecond pulsed discharge plasma to achieve efficient adsorption of low-concentration bisphenol A (BPA). The removal efficiency of BPA reached 99% after 10 min of plasma modification at a pulse peak voltage of 28 kV, which increased by 25.8% compared to the raw materials. This enhancement was attributed to the increase of active sites and oxygen-containing functional groups. The adsorption behaviors of the porous polymer materials were primarily dominated by monolayer chemisorption. Subsequently, comparative experiments further verified the high-efficiency adsorption performance of porous polymer materials after plasma treatment.

MATERIALS

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