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MXene/Cellulose Hydrogel Composites: Preparation and Adsorption Properties of Pb2+

Polymers [2024]
Qiang Yang, Jia Zhang, Hairong Yin, Junkang Guo, Shenghua Lv, Yaofeng Li
ABSTRACT

In this work, acrylic cellulose hydrogel, a typical natural polymer adsorbent, was modified using MXene through in situ polymerization to create a synthetic inorganic–polymer composite known as MXene/cellulose hydrogel. FTIR, XRD, SEM, and thermogravimetric analyses were applied to characterize the chemical structure and micromorphology. The MXene/cellulose hydrogel was utilized for the removal of Pb2+from wastewater. Under optimal experimental conditions (initial Pb2+concentration of 0.04 mol/L, adsorption time of 150 min, pH = 5.5, and MXene doping content of 50% at 30 °C), a maximum adsorption capacity of 410.57 mg/g was achieved. The MXene/cellulose hydrogel corresponded with the pseudo-second-order kinetic equation model and exhibited a better fit with the Freundlich isotherm model.

MATERIALS

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