Lattice-Doped Ir Cooperating with Surface-Anchored IrOx for Acidic Oxygen Evolution Reaction with Ultralow Ir Loading

Reducing iridium (Ir) loading while maintaining efficiency and stability is crucial for the acidic oxygen evolution reaction (OER). In this study, we develop a synthetic method of sequential electrochemical deposition and high-temperature thermal shock to produce an IrOx/Ir-WO3 electrocatalyst with ∼1.75 nm IrOx nanoparticles anchoring on Ir-doped WO3 nanosheets. The IrOx/Ir-WO3 electrocatalyst with a low Ir loading of 0.035 mg cm–2 demonstrates a low overpotential of 239 mV to achieve a current density of 10 mA cm–2 and a mass activity of 6.6 × 104 A gIr–1 @1.75 V vs RHE in 0.5 M H2SO4. IrOx/Ir-WO3 on carbon paper as the anode and Pt/C as the cathode work stably for 40 h at 30 mA cm–2 in a proton exchange membrane water electrolyzer. It is found that the cooperation of lattice-doped Ir and surface-anchored IrOx enhances the activity and stability of IrOx/Ir-WO3 for acidic OER. Specifically, the doped Ir reduces the electron density of the anchored IrOx, thus optimizing the adsorption energy of oxygen-containing intermediates and the kinetic barrier of H2O dissociation, leading to an enhanced activity of IrOx/Ir-WO3. Also, the Ir-WO3 support provides electrons to retard the overoxidation and dissolution of Ir atoms from the anchored IrOx during acidic OER.