Humic acid-based polyphenol-functionalized collagen fiber for efficient recognition capture of iodine vapor

Effective capture of radioactive iodine vapor is a crucial part of the spent fuel reprocessing process. In this study, humic acid (HA), which has excellent recognition capture of iodine vapor, is introduced as the active site construction center, functionalizing and modifying alkali-activated collagen fiber (ACF), to prepare the biomass composite functional materials (HA@ACF). The results demonstrate that HA@ACF exhibits exceptional recognition ability and a strong affinity for iodine vapor, with an adsorption capacity of 2811.8 mg/g (ACF is only 1068.6 mg/g). Simultaneously, under relative humidity of 27 % and strong acid conditions, the iodine vapor capture capacity of HA@ACF only decreased by 17.2 %, indicating that the material exhibits excellent iodine capture performance under complex conditions. The excellent adsorption performance is attributed to the synergistic effect of abundant −NHR, C = O, and phenolic hydroxyl active sites in HA@ACF, which recognize and induce iodine vapor, resulting in the capture of iodine molecules as I 3 - . Meanwhile, DFT calculations reveal the excellent adsorption energy (−0.51 eV) of iodine vapor on the phenolic hydroxyl groups on HA . Therefore, the HA@ACF biomass composite functional material can be an ideal candidate adsorbent for the efficient recognition capture of radioactive iodine vapor in airborne effluent.