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Graphenic materials prepared from magnesium ions doping cellulose and its application in electrochemical detection of adenine and guanine

MICROCHEMICAL JOURNAL [2024]
Mingwei Yang, Qian Liu, Yulin Wang, Chengzhen Gu, Haibin Wang, Jianghua Ye, Xinyu Zheng
ABSTRACT

Graphenic materials of high quality are in high-demand. In this study, a method is proposed for the synthesis of graphenic materials by the pyrolysis of cellulose materials. Cellulose materials were oxidized and doped with magnesium prior to pyrolysis, which improved the graphitization efficiency significantly. The obtained graphenic materials, exhibiting a well-developed porous structure, high specific surface area, were employed for the fabrication of a composite electrode. The composite electrode was employed for the simultaneously detection of adenine (AE) and guanine (GA) with excellent performance in the electrocatalytic oxidation response. Various electrochemical tests were carried out to optimized the detection of AE and GA. Under the optimized conditions, the simultaneous quantification of GA and AE is achieved from 1 – 100 μM with detection limits from 0.4 – 0.6 μM. This study offers a promising alternative for the synthesis of graphenic materials of high quality.

MATERIALS

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