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Flexible bifunctional wood-derived water filtration/photo-Fenton membrane for efficient purification of mixed organic wastewater

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS [2024]
Haohang Fang, Qianqian Yu, Di Xie, Yiyan Cai, Jianping Sun, Boxi Chen, Houkai Huang, Xin Li, Siyang Dai, Shaohong Shi, Yiqiang Wu, Fangchao Cheng
ABSTRACT

Membrane filtration technology demonstrates excellent continuous processing capability in organic wastewater treated processes, which is usually applied in continuous industrial processes. However, it still faces a contradiction between membrane flux and treatment efficiency. In this study, a flexible wood-based photocatalytic membrane with high membrane flux and exceptional photofenton performance was developed via partial fragment wood components and uniform loading of multi-metal oxide nanocatalysts, which breaks mentioned contradiction. The homogeneous and efficient wood-based dual-function water filtration/photofenton system was established by leveraging the directional porous structure of wood in conjunction with the nanocatalysts while adjusting their ratios, enabling effective purification of highly concentrated mixed organic wastewater. Under one solar intensity and negative pressure filtration (0.03 MPa), the system treated a mixed solution containing Rhodamine B, phenol , and tetracycline at a concentration of 280 mg L −1 with the removal efficiencies of 100 %, 93.4 %, and 90.2 %, respectively, and the membrane flux could up to 315.3 Lm −2 h −1 within one hour. The membrane showed a good recycling performance, and the decay rates were all below 5 % after five cycles. This wood-based dual-function water filtration/photo-Fenton system provides a new approach for the continuous dynamic treatment of high-concentration organic wastewater on an industrial scale.

MATERIALS

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